Organochromium Compounds is a three-chapter text that covers the major developments in the preparation, characterization, and reaction of the five main classes of organochromium compounds. These classes include the chromium p and solvated sodium and lithium poly(organo)chromate(III) and (II) complexes, carbenoid-chromium, solvated s-bonded organochromium(III) and (II), solvated sodium and lithium poly(organo)chromate(III) and (II) complexes, and unsolvated s-bonded tetra(organo)chromium(IV) compounds. This book will be of value to organic chemists and researchers who are interested in organotransition metal chemistry.
The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively
Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.
It is now some sixteen years since the author's first series of books on the analysis of organometallic compounds. Many developments in the subject have occurred since that time and a new book on the subject is now overdue. The present book aims to provide a comprehensive review of the subject. It covers not only all aspects of the analysis of organometallic compounds but also contains two additional chapters, dealing with environmental analysis and the use of chelates of metals in the determination of very low concentrations of organic metals. Whilst reviewing the literature for the present book, it was observed that whereas papers published prior to 1973 dealt almost exclusively with various forms of analysis, a high proportion of those published during the past ten years were concerned with the application of proven or newly developed methods to the determination of organometallic compounds in environmental samples such as water, air, soil, river and ocean sediments, fish life and biota samples. An increasing range of elements including mercury, lead, arsenic, tin, antimony, selenium and manganese are now being found in organically bound forms in the environment, some resulting from pollution, others formed in nature by bacterial processes. As many of these substances have appreciable implications to human and animal health and the ecosystem as a whole, it was considered that it would be timely to include a separate chapter in the book devoted entirely to this subject.
Metallurgical Coatings and Thin Films 1990 presents the Proceedings of the 17th International Conference on Metallurgical Coatings and 8th International Conference on Thin Films, held in San Diego, California on April 2-6, 1990. It contains 219 papers covering a wide range of topics related to metallurgical coatings and thin films, including high temperature coatings, hard coatings, diamond films, tribology, and ion beam modification. Organized into 99 chapters, this volume begins with a discussion of a thermochemical model for diamond growth from the vapor phase and an experiment in large area diamond coating using a combustion flame torch in its traversing mode. It then explores the properties of diamond films, preparation of diamond-like carbon films using various ion-beam-assisted techniques, deposition of diamond-like films by laser ablation, and coating of cubic BN films on different substrates. The book examines surface processes and rate-determining steps in plasma-induced chemical vapor deposition, and addition of rare earths to improve scale adherence on heat-resisting alloys and coatings. The reader is introduced to high temperature wear and clearance control coatings, thermal barrier coatings, and corrosion resistant coatings. The book also discusses modification of coatings/surfaces to reduce friction; the mechanics of the tribology of thin films systems; mechanochemical interactions in the tribological behavior of materials; analysis and micromechanical testing of tribological coatings; surface modification using directed ion beams; and industrial equipment and processes. This book is a valuable resource for students and researchers interested in metallurgical coatings and thin films.
