Metal Oxides and Related Solids for Electrocatalytic Water Splitting

Metal Oxides and Related Solids for Electrocatalytic Water Splitting

Author: Junlei Qi

Publisher: Elsevier

Published: 2022-05-05

Total Pages: 406

ISBN-13: 0323898068

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Metal Oxides and Related Solids for Electrocatalytic Water Splitting reviews the fundamentals and strategies needed to design and fabricate metal oxide-based electrocatalysts. After an introduction to the key properties of transition metal oxides, materials engineering methods to optimize the performance of metal-oxide based electrocatalysts are discussed. Strategies reviewed include defect engineering, interface engineering and doping engineering. Other sections cover important categories of metal-oxide (and related solids) based catalysts, including layered hydroxides, metal chalcogenides, metal phosphides, metal nitrides, metal borides, and more. Each chapter introduces important properties and material design strategies, including composite and morphology design. There is also an emphasis on cost-effective materials design and fabrication for optimized performance for electrocatalytic water splitting applications. Lastly, the book touches on recently developed in-situ characterization methods applied to observe and control the material synthesis process. - Introduces metal oxide-based materials for electrocatalytic water splitting applications, including their key properties, synthesis, design and fabrication strategies - Reviews the most relevant materials design strategies, including defect engineering, interface engineering, and doping engineering - Discusses the pros and cons of metal oxide-based materials for water splitting applications to aid in materials selection


Catalysis

Catalysis

Author: James Spivey

Publisher: Royal Society of Chemistry

Published: 2020-02-05

Total Pages: 246

ISBN-13: 1788017749

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Catalysts are required for a variety of applications and researchers are increasingly challenged to find cost effective and environmentally benign catalysts to use. This volume looks at modern approaches to catalysis and reviews the extensive literature. Chapters highlight reactions active under oxidative coupling of methane conditions and how they are interlinked, heterogeneous nickel catalysts and their use in laboratory and industry, the reaction mechanism of heterogeneous catalysis with the surface science probe, the concepts of electroless deposition (ED) methods for preparation of true bimetallic catalysts, the general subject of metal-support interactions occurring over ruthenium-based catalysts and benzene as the target volatile organic compound (VOC). Appealing broadly to researchers in academia and industry, these illustrative chapters bridge the gap from academic studies in the laboratory to practical applications in industry not only for catalysis field but also for environmental protection. The book will be of great benefit to any researcher wanting a succinct reference on developments in this area now and looking to the future.


Advances in Chemical Engineering II

Advances in Chemical Engineering II

Author: Zi Li Liu

Publisher: Trans Tech Publications Ltd

Published: 2012-07-26

Total Pages: 3489

ISBN-13: 303813869X

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Selected, peer reviewed papers from the 2nd International Conference on Chemical Engineering and Advanced Materials (CEAM 2012), July 13-15, 2012, Guangzhou, China


Metal Oxides/Chalcogenides and Composites

Metal Oxides/Chalcogenides and Composites

Author: Aneeya Kumar Samantara

Publisher: Springer

Published: 2019-08-09

Total Pages: 94

ISBN-13: 3030248615

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This book covers the recent development of metal oxides, hydroxides and their carbon composites for electrochemical oxidation of water in the production of hydrogen and oxygen as fuels. It includes a detailed discussion on synthesis methodologies for the metal oxides/hydroxides, structural/morphological characterizations, and the key parameters (Tafel plot, Turnover frequency, Faradic efficiency, overpotential, long cycle life etc.) needed to evaluate the electrocatalytic activity of the materials. Additionally, the mechanism behind the electro oxidation process is presented. Readers will find a comprehensive source on the close correlation between metal oxides, hydroxides, composites, and their properties and importance in the generation of hydrogen and oxygen from water. The depletion of fossil fuels from the earth’s crust, and related environmental issues such as climate change, demand that we search for alternative energy resources to achieve some form of sustainable future. In this regard, much scientific research has been devoted to technologies such as solar cells, wind turbines, fuel cells etc. Among them fuel cells attract much attention because of their versatility and efficiency. In fuel cells, different fuels such as hydrogen, CO2, alcohols, acids, methane, oxygen/air, etc. are used as the fuel, and catalysts are employed to produce a chemical reaction for generating electricity. Hence, it is very important to produce these fuels in an efficient, eco-friendly, and cost effective manner. The electrochemical splitting of water is an environmentally friendly process to produce hydrogen (the greener fuel used in fuel cells), but the efficiencies of these hydrogen evolution reactions (cathodic half reaction) are strongly dependent on the anodic half reaction (oxygen evolution reaction), i.e., the better the anodic half, the better will be the cathodic reaction. Further, this oxygen evolution reaction depends on the types of active electrocatalysts used. Though many more synthetic approaches have been explored and different electrocatalysts developed, oxide and hydroxide-based nanomaterials and composites (with graphene, carbon nanotubes etc.) show better performance. This may be due to the availability of more catalytic surface area and electro active centers to carry out the catalysis process.


Nanotechnology and the Generation of Sustainable Hydrogen

Nanotechnology and the Generation of Sustainable Hydrogen

Author: Sarah Farrukh

Publisher: Springer Nature

Published: 2020-10-29

Total Pages: 112

ISBN-13: 3030604020

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This book explains the aspiring vision of a sustainable hydrogen generating system which employs nanotechnology one way or the other and presents a detailed update on research activities, achievements and challenges. It explores how nanotechnology is reshaping science in general and how this can be applied to the generation and storage of hydrogen energy. This book begins by highlighting the importance of hydrogen a source of sustainable energy and its impact on the technical advances of fuel cells, internal combustion engines, batteries and power plants. The book depicts the role of nanotechnology in the development of sustainable hydrogen. Comprehensive studies on various nanotechnologies involved in hydrogen generation are discussed in separate chapters, representing a complete picture of hydrogen generation utilizing nanotechnology. This book serves as a useful research tool for academics and practitioners looking towards new ways to develop and consume energy, without conceding our environment. Providing the advantages and disadvantages of each technology discussed, this book shows the benefits of utilizing nanotechnology in this field.


Crystalline Metal Oxide Catalysts

Crystalline Metal Oxide Catalysts

Author: Wataru Ueda

Publisher: Springer Nature

Published: 2022-10-26

Total Pages: 398

ISBN-13: 981195013X

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This book introduces the innovatively advanced crystalline metal oxide catalysts that have multi-catalytic functions on the basis of spatially placed elements in crystal structure. With authors who are experts in their fields, the chapters of the book are organized according to catalytic function, on the basis of crystal structure. The book also covers the structure determination of micro–nano-sized metal oxide crystals that are now standard in most catalytic materials and new trends in catalyst development using materials informatics and catalytic informatics. The information contained here will guide researchers who are eager to carry out sustainable catalytic processes and ultimately to achieve a sustainable society in their quest for catalyst development.


Advances in Nanostructured Composites

Advances in Nanostructured Composites

Author: Mahmood Aliofkhazraei

Publisher: CRC Press

Published: 2019-07-25

Total Pages: 450

ISBN-13: 0429664311

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The first volume of this book covered Section I: Introduction to Nanocomposites Fabrication and Section II: CNT and Graphene Nanocomposites. The present second volume covers Section III: Recent Applications of Nanocomposites. The second volume aims to provide a guide for different applications of modern nanocomposites especially those fabricated by carbon nanotubes and graphene. The book makes a comparative study of fiber-reinforced composites which have been embedded into the matrix with nanocomposites containing nanotubes in place of fibers. The main topics of this volume are: Electrochemical Properties of Nanoporous Based Materials, Fabrication and Application of Graphene Oxide-based Metal and Metal Oxide Nanocomposites, Electrochemical Sensors/Biosensors Based on Carbon Aerogels/Xerogels, Advances in Nanobiocatalysis: Strategies for Lipase Immobilization and Stabilization, Metal Oxide Based Heterojunction Nanoscale Materials for Chemiresistive Gas Sensors, Recent Advances in Polymer Nanocomposite Coatings for Corrosion Protection, Recent Advances in the Design of Nanocomposite Materials via Laser Techniques for Biomedical Applications, Carbonaceous Nanostructured Composites for Electrochemical Power Sources: Fuel Cells, Supercapacitors and Batteries, Bismuth Vanadate Based Nanostructured and Nanocomposite Photocatalyst Materials for Water Splitting Application.