The Nitro Group in Organic Synthesis

The Nitro Group in Organic Synthesis

Author: Noboru Ono

Publisher: John Wiley & Sons

Published: 2003-05-08

Total Pages: 392

ISBN-13: 0471458465

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The most useful reactions of organonitro compounds in organic synthesis Compounds containing nitro groups are useful intermediates for the synthesis of natural products and other complex organic molecules. The Nitro Group in Organic Synthesis focuses on reactions that proceed under mild conditions, important functional groups that can be synthesized by conversion of nitro groups, and the stereoselectivity of reactions of nitro compounds. These issues are of great importance to practicing researchers in today's pharmaceutical, agrochemical, and fine chemical industries. The Nitro Group in Organic Synthesis also emphasizes environmentally-friendly methods for nitration, the importance of aliphatic nitro compounds, and modern preparation of nitro compounds. Other topics discussed include: * Henry reaction * Asymmetric Michael addition * Alkylation, acylation, halogenation, and related reactions of RNO2 * Substitution and elimination of NO2 and RNO2 The Nitro Group in Organic Synthesis is a useful resource for researchers and students in organic and medicinal chemistry.


Basic Principles of Organic Chemistry

Basic Principles of Organic Chemistry

Author: John D. Roberts

Publisher:

Published: 1977

Total Pages: 1596

ISBN-13: 9780805383218

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Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.


Nitro Compounds

Nitro Compounds

Author: Tadeusz Urbański

Publisher: Elsevier

Published: 2013-09-03

Total Pages: 559

ISBN-13: 1483284425

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Nitro Compounds provides information pertinent to the formation, mechanism, synthesis, and structure of nitro compounds. This book discusses the behavioral uniqueness of the nitro group in electric field. Organized into 50 chapters, this book begins with an overview of the amphoterism of HNO3 and its role in the reactions of HNO3 with organic substances. This text then examines the secondary nitroheptane obtained byvapor-phase nitration of n-heptane with nitrogen dioxide. Other chapters consider the explosion hazard of gaseous mixtures in exothermic reactions of oxidation and nitration. This book discusses as well the method used for the investigation of nitration of phenosulphonic acids. The final chapter deals with the relationship between the structure of nitrofuranoic compounds and the fungicidal, bactericidal, and herbicidal activity. This book is a valuable resource for chemists and organic chemists. Chemical researchers who are interested in the mechanism and synthesis of nitro compounds will also find this book useful.


Nitro Compounds—Advances in Research and Application: 2012 Edition

Nitro Compounds—Advances in Research and Application: 2012 Edition

Author:

Publisher: ScholarlyEditions

Published: 2012-12-26

Total Pages: 150

ISBN-13: 1481604260

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Nitro Compounds—Advances in Research and Application: 2012 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Nitro Compounds. The editors have built Nitro Compounds—Advances in Research and Application: 2012 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Nitro Compounds in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Nitro Compounds—Advances in Research and Application: 2012 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.


Nitro Compounds—Advances in Research and Application: 2013 Edition

Nitro Compounds—Advances in Research and Application: 2013 Edition

Author:

Publisher: ScholarlyEditions

Published: 2013-06-21

Total Pages: 199

ISBN-13: 1481690337

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Nitro Compounds—Advances in Research and Application: 2013 Edition is a ScholarlyEditions™ book that delivers timely, authoritative, and comprehensive information about Nitrobenzenes. The editors have built Nitro Compounds—Advances in Research and Application: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Nitrobenzenes in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Nitro Compounds—Advances in Research and Application: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.


Infrared Spectral Interpretation

Infrared Spectral Interpretation

Author: Brian C. Smith

Publisher: CRC Press

Published: 1998-12-10

Total Pages: 286

ISBN-13: 9780849324635

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This author's second volume introduces basic principles of interpreting infrared spectral data, teaching its readers to make sense of the data coming from an infrared spectrometer. Contents include spectra and diagnostic bands for the more common functional groups as well as chapters on polyester spectra and interpretation aids. Discussions include: Science of infrared interpretation Light and molecular vibrations How and why molecules absorb infrared radiation Peak heights, intensities, and widths Hydrocarbons, carbonyl groups, and molecules with C-N bonds Polymers and inorganic molecules The use of atlases, library searching, spectral subtraction, and the Internet in augmenting interpretation Each chapter presents an introduction to the nomenclature and structure of a specific functional group and proceeds with the important diagnostic bands for each group. Infrared Spectral Interpretation serves both novices and experienced practitioners in this field. The author maintains a website and blog with supplemental material. His training course schedule is also available online.


Relationships Between Chemical Structure and Rat Repellency

Relationships Between Chemical Structure and Rat Repellency

Author: Walter A. Bowles

Publisher:

Published: 1974

Total Pages: 402

ISBN-13:

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Over 4,600 compounds, chiefly organic types, were evaluated using both a food acceptance test and a barrier penetration bioassay to correlate relationships between chemical structure and rodent repellency. These chemicals are indexed and classified according to the functional groups present and to the degree of substitution within their molecular structures. The results of reduction in food consumption for each compound appraised are calculated and their K values listed. The repellent activities of the functional groups represented, alone or in combinations, are expressed by a Functional Group Repellency Index. There were 123 active, interesting or promising compounds included in the 699 having K values of 85 or greater, which were selected for the barrier appraisal study. These chemicals were formulated in selective solvents at several concentrations and applied to burlap, and exposed to rodent attack following storage periods of varying intervals. The results of these tests are listed.


Nitroalkanes

Nitroalkanes

Author: Roberto Ballini

Publisher: John Wiley & Sons

Published: 2021-04-26

Total Pages: 322

ISBN-13: 3527347453

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Discover a comprehensive exploration of recent progress in the preparation of nitroalkanes from two leading voices in the field Nitroalkanes: Synthesis, Reactivity, and Applications delivers a thorough summary of the importance of nitroalkanes in organic synthesis. The book covers their preparation, transformation into other functional groups, like carbonyls and amines, and their use in the formation of single carbon-carbon or double carbon-carbon bonds. The distinguished authors have included chapters on acyclic and cyclic alpha-nitro ketones as well as the synthesis of cyclopropanes and spiro ketals. The book provides treatments of the application of nitroalkanes for the synthesis of important heterocycles, poly-functionalized structures, natural products, and compounds of biological and pharmaceutical interest. A one-stop resource in a topic that hasn???t been fully addressed by any other book in decades, this book covers the most important synthetic routes toward nitroalkanes. Readers will also benefit from the inclusion of: A thorough introduction to the synthesis of nitroalkanes, as well as the transformation of the nitro group into other functionalities An exploration of the formation of C-C single bonds, C=C double bonds, and the breaking of C3C bonds from cyclic alpha-nitro ketones Discussions of acyclic alpha-nitro ketones, nitroalkanes as precursors of cyclopropanes, and the synthesis of spiro ketals An examination of the preparation and synthetic applications of 1,3-Dinitroalkanes Perfect for organic chemists, natural products chemists, and catalytic chemists, Nitroalkanes: Synthesis, Reactivity, and Applications will also earn a place in the libraries of medicinal chemists seeking a one-stop resource for the most recent developments in the preparation of nitroalkanes, their functionalization, and their applications.