New Synthetic Routes to Polyoxometalate Containing Ionic Liquids
New Synthetic Routes to Polyoxometalate Containing Ionic Liquids

Author: Sven Herrmann

Publisher: Springer

Published: 2015-02-11

Total Pages: 138

ISBN-13: 365808796X

DOWNLOAD EBOOK

In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Mößbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.

Applied Polyoxometalate-Based Electrocatalysis
Applied Polyoxometalate-Based Electrocatalysis

Author: Diana M. Fernandes

Publisher: John Wiley & Sons

Published: 2024-10-11

Total Pages: 386

ISBN-13: 3527842705

DOWNLOAD EBOOK

Well-researched reference on stable alternative electrocatalysts and electrode materials with the potential to transform chemistry and processes in sensor- and energy-related technologies Applied Polyoxometalate-based Electrocatalysis delivers an overview of the variety of efficient applications of free POM and POM-based (nano)composites as exciting materials in the field of electrocatalysis. With a variety of sizes, shapes, composition, and physical and chemical properties, these composites have important properties, such as the ability to undergo reversible multivalence reductions/oxidations, leading to the formation of mixed-valence species, which brings about favorable electrocatalytic properties with regard to several electrochemical processes. Edited by a highly qualified independent researcher internationally recognized for her contributions to materials for electrochemical energy-related reactions, Applied Polyoxometalate-based Electrocatalysis includes information on: General methodologies used in the preparation of free POMs and POM-based nanocomposites and different strategies employed in electrode modification Role of POM-modified electrodes in oxidative and reductive electrocatalysis, including the detection/sensing of several (bio)molecules of interest and carbon dioxide electroreduction Application of POM-based (nano)composites, including the oxygen reduction reaction relevant to fuel cells, the oxygen and hydrogen evolution reactions, and batteries and supercapacitors Applied Polyoxometalate-based Electrocatalysis is an essential reference on the subject for chemists, material scientists, chemical engineers, and institutions involved in work related to free POM and POM-based (nano)composites.

Structures and Interactions of Ionic Liquids
Structures and Interactions of Ionic Liquids

Author: Suojiang Zhang

Publisher: Springer

Published: 2013-12-20

Total Pages: 201

ISBN-13: 3642386199

DOWNLOAD EBOOK

Structures, Bonding and Hydrogen Bonds, by Kun Dong, Qian Wang, Xingmei Lu, Suojiang Zhang Aggregation in System of Ionic Liquids, by Jianji Wang, Huiyong Wang Dissolution of Biomass Using Ionic Liquids, by Hui Wang, Gabriela Gurau, Robin D. Rogers Effect of the Structures of Ionic Liquids on Their Physical-Chemical Properties, by Yu-Feng Hu, Xiao-Ming Peng Microstructure study of Ionic liquids by spectroscopy, by Haoran Li Structures and Thermodynamic Properties of Ionic Liquids, by Tiancheng Mu, Buxing Han

Fundamentals of Ionic Liquids
Fundamentals of Ionic Liquids

Author: Douglas R. MacFarlane

Publisher: John Wiley & Sons

Published: 2017-12-04

Total Pages: 275

ISBN-13: 352733999X

DOWNLOAD EBOOK

Written by experts who have been part of this field since its beginnings in both research and academia, this textbook introduces readers to this evolving topic and the broad range of applications that are being explored. The book begins by examining what it is that defines ionic liquids and what sets them apart from other materials. Chapters describe the various types of ionic liquids and the different techniques used to synthesize them, as well as their properties and some of the methods used in their measurement. Further chapters delve into synthetic and electrochemical applications and their broad use as "Green" solvents. Final chapters examine important applications in a wide variety of contexts, including such devices as solar cells and batteries, electrochemistry, and biotechnology. The result is a must-have resource for any researcher beginning to work in this growing field, including senior undergraduates and postgraduates.

Supported Ionic Liquids
Supported Ionic Liquids

Author: Rasmus Fehrmann

Publisher: John Wiley & Sons

Published: 2014-03-24

Total Pages: 498

ISBN-13: 3527324291

DOWNLOAD EBOOK

This unique book gives a timely overview about the fundamentals and applications of supported ionic liquids in modern organic synthesis. It introduces the concept and synthesis of SILP materials and presents important applications in the field of catalysis (e.g. hydroformylation, hydrogenation, coupling reactions, fine chemical synthesis) as well as energy technology and gas separation. Written by pioneers in the field, this book is an invaluable reference book for organic chemists in academia or industry.

Cellulose Solvents: For Analysis, Shaping and Chemical Modification
Cellulose Solvents: For Analysis, Shaping and Chemical Modification

Author: Tim Liebert

Publisher: OUP USA

Published: 2010-09-23

Total Pages: 424

ISBN-13: 9780841200067

DOWNLOAD EBOOK

This book will give an overview of the current state-of-the-art concerning the activation and dissolution of cellulose in a broad variety of solvents. Research on this topic can lead to new pathways for the utilization of the most abundant terrestrial biomolecule and may therefore be the basis for new green strategies towards advanced materials.

Ionic Liquid Crystals
Ionic Liquid Crystals

Author: Giacomo Saielli

Publisher: MDPI

Published: 2019-06-24

Total Pages: 108

ISBN-13: 3039210866

DOWNLOAD EBOOK

In this book we have collected a series of state-of-the art papers written by specialists in the field of ionic liquid crystals (ILCs) to address key questions concerning the synthesis, properties, and applications of ILCs. New compounds exhibiting ionic liquid crystalline phases are presented, both of calamitic as well as discotic type. Their dynamic and structural properties have been investigated with a series of experimental techniques including differential scanning calorimetry, polarized optical spectroscopy, X-ray scattering, and nuclear magnetic resonance, impedance spectroscopy to mention but a few. Moreover, computer simulations using both fully atomistic and highly coarse-grained force fields have been presented, offering an invaluable microscopic view of the structure and dynamics of these fascinating materials.

Applications of Ionic Liquids in Polymer Science and Technology
Applications of Ionic Liquids in Polymer Science and Technology

Author: David Mecerreyes

Publisher: Springer

Published: 2015-04-08

Total Pages: 392

ISBN-13: 366244903X

DOWNLOAD EBOOK

This book summarizes the latest knowledge in the science and technology of ionic liquids and polymers in different areas. Ionic liquids (IL) are actively being investigated in polymer science and technology for a number of different applications. In the first part of the book the authors present the particular properties of ionic liquids as speciality solvents. The state-of-the art in the use of ionic liquids in polymer synthesis and modification reactions including polymer recycling is outlined. The second part focuses on the use of ionic liquids as speciality additives such as plasticizers or antistatic agents. The third part examines the use of ionic liquids in the design of functional polymers (usually called polymeric ionic liquids (PIL) or poly(ionic liquids)). Many important applications in diverse scientific and industrial areas rely on these polymers, like polymer electrolytes in electrochemical devices, building blocks in materials science, nanocomposites, gas membranes, innovative anion sensitive materials, smart surfaces, and a countless set range of emerging applications in different fields such as energy, optoelectronics, analytical chemistry, biotechnology, nanomedicine or catalysis.

Metallomesogens
Metallomesogens

Author: Jose Luis Serrano

Publisher: John Wiley & Sons

Published: 2008-09-26

Total Pages: 517

ISBN-13: 3527615083

DOWNLOAD EBOOK

Research on metal-containing liquid crystals is a rapidly expanding, multidisciplinary field with new materials continually being synthesized and novel applications being developed. 'Metallomesogens' is the first comprehensive survey of the field, introducing the reader to: * materials design * synthesis * physical properties * emerging applications Carefully selected references round off this well-organized compendium. It is an indispensable guide to experienced researchers in coordination and organometallic chemistry as well as in liquid-crystal and materials science. Newcomers and graduate students will also benefit from this didactically sound introduction to the field.