New Directions in the Modeling of Organometallic Reactions

New Directions in the Modeling of Organometallic Reactions

Author: Agustí Lledós

Publisher: Springer Nature

Published: 2020-11-05

Total Pages: 276

ISBN-13: 3030569969

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This book focuses on the computational modeling of organometallic reactivity. In recent years, computational methods, particularly those based on Density Functional Theory (DFT) have been fully incorporated into the toolbox of organometallic chemists’ methods. Nowadays, energy profiles of multistep processes are routinely calculated, and detailed mechanistic pictures of the reactions arise from these calculations. This type of analysis is increasingly performed even by experimentalists themselves. The volume aims to connect established computational organometallics with the more recent theoretical and methodological developments applied to this field. This would allow broadening of the simulation scope toward emergent organometallic areas (as ligand design or photoactivated processes), to narrow the gap between calculations and experiments (microkinetic models) and even to discover new reactions (automated methods). Given the broad interest and extensive application that computational methods have reached within the organometallic community, this new volume will attract the interest of both experimental and computational organometallic chemists.


Asymmetric Synthetic Methodology

Asymmetric Synthetic Methodology

Author: David John Ager

Publisher: CRC Press

Published: 1995-11-21

Total Pages: 506

ISBN-13: 9780849389429

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This comprehensive text presents a critical discussion of the scopes and limitations of various organic synthetic methodologies that are available for performing asymmetric transformations. In addition to purely chemical methods, the book covers applications of new enzymes and other biological systems that are increasingly useful in asymmetric methodology.


Carbocation Chemistry

Carbocation Chemistry

Author: Jie Jack Li

Publisher: CRC Press

Published: 2016-10-03

Total Pages: 304

ISBN-13: 1315353199

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Gives a comprehensive and up-to-date summary of carbocation chemistry. Discusses the widespread applications of carbocation chemistry, with an emphasis on organic synthesis. Contains the contributions of highly experienced authors. Provides a panoramic view of carbocation chemistry, which is part of the foundation of organic chemistry.


Chemical Approaches to the Synthesis of Peptides and Proteins

Chemical Approaches to the Synthesis of Peptides and Proteins

Author: Paul Lloyd-Williams

Publisher: CRC Press

Published: 1997-04-23

Total Pages: 306

ISBN-13: 9780849391422

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Organic chemists working on the synthesis of natural products have long found a special challenge in the preparation of peptides and proteins. However, more reliable, more efficient synthetic preparation methods have been developed in recent years. This reference evaluates the most important synthesis methods available today, and also considers methods that show promise for future applications. This text describes the state of the art in efficient synthetic methods for the synthesis of both natural and artificial large peptide and protein molecules. Subjects include an introduction to basic topics, linear solid-phase synthesis of peptides, peptide synthesis in solution, convergent solid-phase synthesis, methods for the synthesis of branched peptides, formation of disulfide bridges, and more. The book emphasizes strategies and tactics that must be considered for the successful synthesis of peptides.


Early Main Group Metal Catalysis

Early Main Group Metal Catalysis

Author: Sjoerd Harder

Publisher: John Wiley & Sons

Published: 2020-04-06

Total Pages: 400

ISBN-13: 3527344489

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Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.


New Directions In Physics

New Directions In Physics

Author: N. Metropolis

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 305

ISBN-13: 0323141315

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New Directions in Physics represents a fascinating view of the future as seen by some of the remarkable men who were here over 40 years ago. It makes it quite clear that we are still in the dawn of physics—the excitement and challenge that lie ahead are extraordinary. We also get a glimpse of where these remarkable men have been since the end of Project Y of the Manhattan Project and where they see the future directions for physics. This book comprises 20 chapters, with the first being an introductory chapter describing Los Alamos in the 1980s. The following chapters go on to discuss tiny computers obeying quantum mechanical laws; the past, present, and future of nuclear magnetic resonance; and experimental evidence that an asteroid impact led to the extinction of many species 65 million years ago. Other chapters cover the lunar laboratory; the future of particle accelerators; models, hypotheses and approximations; and comments on three thermonuclear paths for the synthesis of helium. The book also describes how the sad augurs mock their own presage; experiments on time reversal symmetry and parity; the course of our magnetic fusion energy enterprise; early days in the Lawrence Laboratory; nuclear charge distribution in fission; developing larger software systems; reflections on style in physics; tuning up the TPC; remarks on the future of particle physics; the supernova theory; and the history and hierarchy of structure. This book will be of interest to practitioners in the field of theoretical physics.


The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals

Author: Robert H. Crabtree

Publisher: John Wiley & Sons

Published: 2009-04-06

Total Pages: 523

ISBN-13: 0470257628

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"One impressive and compressive book. . . . This review would have to be book size to do full justice to all the insights in this volume." —Journal of Metals Online Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and?detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date. New to the Fifth Edition: Chapters have been updated with relevant examples in the field, modern trends, and new applications; the organic applications chapter has been completely rewritten New end-of-chapter problems, along with their solutions Coverage enhanced with developments in nanoparticle science Increased focus on green chemistry An unparalleled pedagogic resource as well as a valuable working reference for professional chemists, with comprehensive coverage and up-to-date information, students and researchers?in organic and organometallic chemistry will turn to The Organometallic Chemistry of the Transition Metals, Fifth Edition for the critical information they need on organometallic compounds, their preparation, and their use in synthesis.


Current Catalog

Current Catalog

Author: National Library of Medicine (U.S.)

Publisher:

Published: 1982

Total Pages: 1068

ISBN-13:

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First multi-year cumulation covers six years: 1965-70.


Organometallic Chemistry

Organometallic Chemistry

Author: Ian J S Fairlamb

Publisher: Royal Society of Chemistry

Published: 2009-09-30

Total Pages: 258

ISBN-13: 1847551033

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Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies, the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis, synthetic organic chemistry and also in the development of new materials. Each volume in the series is published either annually or biennially and is a superb reference point for researchers.


Advances in Organometallic Chemistry

Advances in Organometallic Chemistry

Author:

Publisher: Academic Press

Published: 2022-06-29

Total Pages: 244

ISBN-13: 0323990916

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Advances in Organometallic Chemistry, Volume 78, the latest release in this longstanding serial known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more includes a variety of new chapters in this updated release. Users will find amazing coverage on Multiple bonds stabilized by Terphenyl Ligands, Selectivity in the Activation of C-H Bonds by Rhodium and Iridium Complexes, Transition Metal-Catalyzed C–C and C-B Bond Formation Reactions: Lessons from Computational Studies, Effect of C-Donor Ligands onto Metal-Catalyzed Carbene and/or Nitrene Transfer Reactions, Chemical Bonding and Dynamic Magnetism in f-Element Organometallic Sandwich Compounds, and much more. - Contains contributions from leading authorities in the field of organometallic chemistry - Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more - Informs and updates readers on the latest developments in the field