Mössbauer Spectroscopy and Transition Metal Chemistry

Mössbauer Spectroscopy and Transition Metal Chemistry

Author: P. Gütlich

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 292

ISBN-13: 3662125455

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Two decades have passed since the original discovery of recoilless nuclear gamma resonance by Rudolf Mossbauer; the spectroscopic method based on this resonance effect - referred to as Mossbauer spectroscopy - has developed into a powerful tool in solid-state research. The users are chemists, physicists, biologists, geologists, and scientists from other disciplines, and the spectrum of problems amenable to this method has become extraordinarily broad. In the present volume we have confined ourselves to applications of Mossbauer spectroscopy to the area of transition elements. We hope that the book will be useful not only to non-Mossbauer special ists with problem-Oriented activities in the chemistry and physics of transition elements, but also to those actively working in the field of Mossbauer spectroscopy on systems (compounds as well as alloys) of transition elements. The first five chapters are directed to introducing the reader who is not familiar with the technique to the principles of the recoilless nuclear resonance effect, the hyperfme interactions between nuclei and electronic properties such as electric and magnetic fields, some essential aspects about measurements, and the evaluation of Moss bauer spectra. Chapter 6 deals with the interpretation of Mossbauer parameters of iron compounds. Here we have placed emphasis on the information about the electronic structure, in correlation with quantum chemical methods, because of its importance for chemical bonding and magnetic properties.


Applications of Mossbauer Spectroscopy

Applications of Mossbauer Spectroscopy

Author: Richard L. Cohen

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 363

ISBN-13: 0323154093

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Applications of Mössbauer Spectroscopy, Volume I is a collection of essays that discusses the research performed using Mössbauer spectroscopy. The book presents the effect of some stabilizers of polyethylene. It demonstrates the polymerization processes and structure of catalytically active centers. The text also describes the chemical processes in butyl rubber vulcanization. It discusses the experimental studies of iron transport proteins and the thermal decomposition of solids. The section that follows describes the paramagnetic hyperfine structure. The book will provide valuable insights for scientists, chemists, students, and researchers in the field of organic chemistry.


Mössbauer Spectroscopy Applied to Inorganic Chemistry

Mössbauer Spectroscopy Applied to Inorganic Chemistry

Author: G.J Long

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 652

ISBN-13: 148992289X

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In 1988 the Mossbauer effect community completed 30 years of continual contribution to the fields of nuclear physics, solid state science, and a variety of related disciplines. To celebrate this anniversary, Professor Gonser of the Universitat des Saarlandes has contributed a chapter to this volume on the history of the effect. Although Mossbauer spectroscopy has reached its mature years, the chapters in this volume illustrate that it is still a dynamic field of science with applications to topics ranging from permanent magnets to biologi cal mineralization. During the discussion of a possible chapter for this volume, a potential author asked, "Do we really need another Mossbauer book?" The editors responded in the affirmative because they believe that a volume of this type offers several advantages. First, it provides the author with an opportunity to write a personal view of the subject, either with or without extensive pedagogic content. Second, there is no artificially imposed restriction on length. In response to the question, "How long should my chapter be?," we have responded that it should be as long as is necessary to clearly present, explain, and evaluate the topic. In this type of book, it is not necessary to condense the topic into two, four, or eight pages as is now so often a requirement for publication in the research literature.


Chemical Mössbauer Spectroscopy

Chemical Mössbauer Spectroscopy

Author: R.H. Herber

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 381

ISBN-13: 1461324319

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The past twenty five years - roughly the period from 1960 to 1985 - have been by all measures among the most exciting and challenging times of our science. The increasing sensitivity of chemical instrumentation, the introduction of the routine use of computers for data reduction and of microprocessors for instrumental control, the wide-spread utilization of lasers, and the disappearance of traditional disciplinary boundaries between scientific fields are but a few of the examples one could cite to support the introductory contention. Almost all of these developments have had their impact on the development of Mossbauer Effect Spectroscopy into a technique par excellence for the elucidation of problems in all areas of chemistry and its associated sister sciences. Indeed, because this spectroscopy is based on fundamental phenomena in nuclear physics, is described in terms of the theory of the solid state and structural chemistry, is useful in the understanding of chemical reactivity and biological phenomena, and can serve to supplement information developed by many other experimental techniques, it has provided an unparalleled opportunity for the exchange of ideas among practitioners of a very wide variety of subfields of the physical and biological sciences. The present collection of contributions is the direct result of such an interaction.


Mössbauer Spectroscopy

Mössbauer Spectroscopy

Author: Yann Garcia

Publisher: John Wiley & Sons

Published: 2023-08-04

Total Pages: 342

ISBN-13: 3527824936

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Mössbauer Spectroscopy Unique and comprehensive overview of versatile applications of Mössbauer spectroscopy in chemistry and material sciences Mössbauer Spectroscopy provides a comprehensive overview of relevant applications of this physical analysis method in chemistry and material sciences. The book shows the versatility of Mössbauer spectroscopy in finding useful information on electronic structure, structural insights, and solid-state effects of chemical systems. A wide range of chemical applications and applied concepts are covered as well as numerous examples, selected from recent literature. To aid in reader comprehension and accessibility, contents are well-structured and divided in different sections covering energy, catalysis, coordination chemistry, spin crossover, sensing, photomagnetism. Edited by prominent scientists in the field and authored by a group of international experts, Mössbauer Spectroscopy covers sample topics such as: Li-ion batteries, catalysts, fuel cells, Fe based silicides and iron phosphates containing minerals Gold clusters and gold mixed valence complexes Molecule based magnets, photoswitchable spin crossover coordination polymers and molecular sensors for meat freshness control With comprehensive coverage of the developments in the technique, Mössbauer Spectroscopy is a beneficial resource for researchers, professionals, and academics in chemistry related fields, such as material science, sustainable environment, and molecular electronics. It can be used by newcomers as well as for educational purposes at the master and PhD levels.


Chemistry of Tin

Chemistry of Tin

Author: P.J. Smith

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 592

ISBN-13: 9401149380

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In common with the editor of the first edition, my own personal involvement with tin chemistry began when I had the privilege of studying for a PhD degree under the supervision of Professor Alwyn G. Davies FRS at University College London (UCL) almost exactly 30 years ago. Then, following 21 years' service with the International Tin Research Institute, it was a great pleasure for me when the wheel turned full circle and, in 1994, Alwyn - now an Emeritus Professor - asked me to return to UCL as an Honorary Research Fellow in the Chemistry Department. One of my first tasks was when I received an invitation from Blackie A&P to edit the second edition of the Chemistry of Tin, which I was delighted to accept, since it enabled me to continued my life-long interest in tin chemistry and to maintain contact with my former friends and colleagues, many of whom have contributed to this book.


Nanobiomaterials

Nanobiomaterials

Author: Dong Yi

Publisher: CRC Press

Published: 2013-08-14

Total Pages: 461

ISBN-13: 1439876428

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There is a continuous exchange of ideas taking place at the border of the biological and physical sciences in many areas of nanoscience. Nanotechnology uses biomimetic or bio-inspired processes to produce nanosized materials for applications in biology and other fields. In return, the fruits of nanotechnology are applied to expanding areas of biome


Dynamical Properties of Solids

Dynamical Properties of Solids

Author: George K. Horton

Publisher: North Holland

Published: 1974

Total Pages: 516

ISBN-13: 9780444867803

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Volume 5 in the series Dynamical Properties of Solids contains two chapters. Chapter 1 is concerned with the Mossbauer effect on the studies of the dynamical properties of solids. The author has concentrated on fields in ME spectroscopy to which less attention has been paid in recent years. Chapter 2 concentrates on structural phase transitions driven by lattice instability of solids. Structural transitions show a fantastic variety in materials as well as in microscopic mechanisms. The chapter presents a unified view of microscopic mechanisms of various kinds of phase transitions and shows the basic relationship between neutron scattering and generalized susceptibility.