Optical Activity and Chiral Discrimination

Optical Activity and Chiral Discrimination

Author: S.F. Mason

Publisher: Springer Science & Business Media

Published: 2013-03-14

Total Pages: 375

ISBN-13: 9401576440

DOWNLOAD EBOOK

For Louis Pasteur, the two distinctive properties of dissymmetric systems, optical activity and chiral discrimination, provided prime evidence for a Divine origin to the universe. Handedness appeared to be built into the macrocosm of the galaxies, each with a non-superposable mirror image by virtue of its rotation, as well as the microcosm of each molecule of most natural products. The best that the chemist in the laboratory could accomplish appeared to be the synthesis of the detordu internally-compensated meso-form and, as Pasteur ultimately came to admit, the externally-compensated racemic form. In the latter case the chemist generated not merely one but two chiral structures, although parity, and secondary symmetry generally, seemed to be conserved in the enantiomer antipode pair. The cosmic element in the Pasteur tradition received an augmentation in secular form from demonstrations of the non conservation of parity in the weak interactions, and from the discovery of net circularity in the extra-terrestrial photons, such as those from the less-distant planets, particularly the photons from the Jupiter red-spot. The development of the photoacoustic circular analysers a decade ago was received in fact with as much enthusiasm by the astronomers as by the chemists. It would be just to add, however, that the majority of these circular analysers are now to be found, not in the observatories, but in the physical and chemistry laboratories devoted to the molecular aspects of the Pasteur tradition.


Vibrational Optical Activity

Vibrational Optical Activity

Author: Laurence A. Nafie

Publisher: John Wiley & Sons

Published: 2011-07-12

Total Pages: 373

ISBN-13: 1119977533

DOWNLOAD EBOOK

This unique book stands as the only comprehensive introduction to vibrational optical activity (VOA) and is the first single book that serves as a complete reference for this relatively new, but increasingly important area of molecular spectroscopy. Key features: A single-source reference on this topic that introduces, describes the background and foundation of this area of spectroscopy. Serves as a guide on how to use it to carry out applications with relevant problem solving. Depth and breadth of the subject is presented in a logical, complete and progressive fashion. Although intended as an introductory text, this book provides in depth coverage of this topic relevant to both students and professionals by taking the reader from basic theory through to practical and instrumental approaches.


Ewing's Analytical Instrumentation Handbook, Fourth Edition

Ewing's Analytical Instrumentation Handbook, Fourth Edition

Author: Nelu Grinberg

Publisher: CRC Press

Published: 2019-02-21

Total Pages: 1523

ISBN-13: 1351644319

DOWNLOAD EBOOK

This handbook is a guide for workers in analytical chemistry who need a starting place for information about a specific instrumental technique. It gives a basic introduction to the techniques and provides leading references on the theory and methodology for an instrumental technique. This edition thoroughly expands and updates the chapters to include concepts, applications, and key references from recent literature. It also contains a new chapter on process analytical technology.


Chemical Evolution: Structure and Model of the First Cell

Chemical Evolution: Structure and Model of the First Cell

Author: Cyril Ponnamperuma

Publisher: Springer Science & Business Media

Published: 1995-07-31

Total Pages: 404

ISBN-13: 0792335627

DOWNLOAD EBOOK

This interdisciplinary book consists of the proceedings of the Alexander Ivanovich Oparin lOOth Anniversary Conference, The Third Trieste Conference on Chemical Evolution, which took place at the International Centre for Theoretical Physics from 29 August till 2 September, 1994. A general overview of Oparin's life and work is followed by a review of Alfonso Herera, another pioneer in the studies of the origin of life. The subject matter is organized in ten sections corresponding to various aspects of our current understanding of the subject that was initiated by Oparin. These subjects were covered by fifty three speakers. There were sixty seven participants from a wide geographical distribution; twenty seven countries were represented. We have included the invited lecture of Professor Igor Kulaev, who was unable to be present at the conference for reasons beyond his control. The conference was generously supported by the International Centre for Theoretical Physics, the Commission of the European Communities, the International Centre for Genetic Engineering and Biotechnology, the International Centre for Science and High Technology, and UNESCO. Cyril Ponnamperuma, University of Maryland, U.S.A. Julian Chela-Flores, ICTP, Italy, and IDEA, Venezuela. xi FOREWORD As this volume was going to press we learnt of the untimely death of Cyril Ponnamperuma who died of cardiac arrest on December 20, 1994.


Molecular Gels

Molecular Gels

Author: Richard G. Weiss

Publisher: Springer Science & Business Media

Published: 2006

Total Pages: 998

ISBN-13: 9781402033520

DOWNLOAD EBOOK

Molecular gels and fibrillar networks – a comprehensive guide to experiment and theory Molecular Gels: Materials with Self-Assembled Fibrillar Networks provides a comprehensive treatise on gelators, especially low molecular-mass gelators (LMOGs), and the properties of their gels. The structures and modes of formation of the self-assembled fibrillar networks (SAFINs) that immobilize the liquid components of the gels are discussed experimentally and theoretically. The spectroscopic, rheological, and structural features of the different classes of LMOGs are also presented. Many examples of the application of the principal analytical techniques for investigation of molecular gels (including SANS, SAXS, WAXS, UV-vis absorption, fluorescence and CD spectroscopies, scanning electron, transmission electron and optical microscopies, and molecular modeling) are presented didactically and in-depth, as are several of the theories of the stages of aggregation of individual LMOG molecules leading to SAFINs. Several actual and potential applications of molecular gels in disparate fields (from silicate replication of nanostructures to art conservation) are described. Special emphasis is placed on perspectives for future developments. This book is an invaluable resource for researchers and practitioners either already researching self-assembly and soft matter or new to the area. Those who will find the book useful include chemists, engineers, spectroscopists, physicists, biologists, theoreticians, and materials scientists. Richard G. Weiss is Professor of Chemistry, Department of Chemistry, Georgetown University, Washington, DC, USA. Pierre Terech is Research Director, CNRS – Atomic Energy Center – Grenoble University, Grenoble, France.


New Developments in Molecular Chirality

New Developments in Molecular Chirality

Author: Paul G. Mezey

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 296

ISBN-13: 940113698X

DOWNLOAD EBOOK

Molecular chirality is one of the fundamental aspects of chemistry. Chirality properties of molecules have implications in a wide variety of subjects, ranging from the basic quantum mechanical properties of simple of a few atoms to molecular optical activity, asymmetric synthesis, systems and the folding pattern of proteins. Chirality, in both the geometrical and the topological sense, has also been the subject of investigations in various branches of mathematics. In particular, new developments in a branch of topology, called knot theory, as well as in various branches of discrete mathematics, have led to a novel perspective on the topological aspects of molecular chirality. Some of the mathematical advances have already found applications to the interpretation of new concepts in theoretical chemistry and mathematical chemistry, as well as to novel synthetic approaches leading to new molecules of exceptional structural properties. Some of the new developments in molecular chirality have been truly fundamental to the theoretical understanding and to the actual practice of many aspects of chemistry. The progress in this field has been very rapid, even accelerating in recent years, and a review appears more than justified. This book offers a selection of subjects covering some of the latest developments. Our primary aim is to clarify some of the basic concepts that are the most prone to misinterpretation and to provide brief introductions to some of those subjects that are expected to have further, important contributions to our understanding of molecular properties and chemical reactivity.


Molecular Quantum Electrodynamics

Molecular Quantum Electrodynamics

Author: D. P. Craig

Publisher: Courier Corporation

Published: 2012-11-13

Total Pages: 338

ISBN-13: 0486135632

DOWNLOAD EBOOK

Self-contained, systematic introduction examines application of quantum electrodynamics to interpretation of optical experiments on atoms and molecules and explains the quantum theory of electromagnetic radiation and its interaction with matter.


Comprehensive Chiroptical Spectroscopy, Volume 1

Comprehensive Chiroptical Spectroscopy, Volume 1

Author: Nina Berova

Publisher: John Wiley & Sons

Published: 2011-12-14

Total Pages: 797

ISBN-13: 1118120175

DOWNLOAD EBOOK

This book provides an introduction to the important methods of chiroptical spectroscopy in general, and circular dichroism (CD) in particular, which are increasingly important in all areas of chemistry, biochemistry, and structural biology. The book can be used as a text for undergraduate and graduate students and as a reference for researchers in academia and industry, with or without the companion volume in this set. Experimental methods and instrumentation are described with topics ranging from the most widely used methods (electronic and vibrational CD) to frontier areas such as nonlinear spectroscopy and photoelectron CD, as well as the theory of chiroptical methods and techniques for simulating chiroptical properties. Each chapter is written by one or more leading authorities with extensive experience in the field.


Chirality in Biological Nanospaces

Chirality in Biological Nanospaces

Author: Nilashis Nandi

Publisher: CRC Press

Published: 2011-07-27

Total Pages: 200

ISBN-13: 1439840032

DOWNLOAD EBOOK

Chirality is widely studied and omnipresent in biological molecules. However, how the retention of enantiomeric forms persists in many life processes without racemization is still unclear, and the molecular understanding of the stringent chiral specificity in enzymatic reactions is sparse. An overview of the influence of chirality in driving reacti