Molecular Catalysts

Molecular Catalysts

Author: Lutz H. Gade

Publisher: John Wiley & Sons

Published: 2014-06-30

Total Pages: 632

ISBN-13: 3527673296

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Highlighting the key aspects and latest advances in the rapidly developing field of molecular catalysis, this book covers new strategies to investigate reaction mechanisms, the enhancement of the catalysts' selectivity and efficiency, as well as the rational design of well-defined molecular catalysts. The interdisciplinary author team with an excellent reputation within the community discusses experimental and theoretical studies, along with examples of improved catalysts, and their application in organic synthesis, biocatalysis, and supported organometallic catalysis. As a result, readers will gain a deeper understanding of the catalytic transformations, allowing them to adapt the knowledge to their own investigations. With its ideal combination of fundamental and applied research, this is an essential reference for researchers and graduate students both in academic institutions and in the chemical industry. With a foreword by Nobel laureate Roald Hoffmann.


Bifunctional Molecular Catalysis

Bifunctional Molecular Catalysis

Author: Takao Ikariya

Publisher: Springer Science & Business Media

Published: 2011-06-26

Total Pages: 219

ISBN-13: 3642207308

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Masakatsu Shibasaki, Motomu Kanai, Shigeki Matsunaga, and Naoya Kumagai: Multimetallic Multifunctional Catalysts for Asymmetric Reactions.- Takao Ikariya: Bifunctional transition metal-based molecular catalysts for asymmetric syntheses.- Chidambaram Gunanathan and David Milstein: Bond Activation by Metal-Ligand Cooperation: Design of ”Green” Catalytic Reactions Based on Aromatization-Dearomatization of Pincer Complexes.- Madeleine C. Warner, Charles P. Casey, and Jan-E. Bäckvall: Shvo’s Catalyst in Hydrogen Transfer Reactions.- Noritaka Mizuno, Keigo Kamata, and Kazuya Yamaguchi: Liquid-Phase Selective Oxidation by Multimetallic Active Sites of Polyoxometalate-Based Molecular Catalysts.- Pingfan Li and Hisashi Yamamoto: Bifunctional Acid Catalysts for Organic Synthesis.- Jun-ichi Ito, Hisao Nishiyama: Bifunctional Phebox Complexes for Asymmetric Catalysis.


Molecular Catalysts for Energy Conversion

Molecular Catalysts for Energy Conversion

Author: Tatsuhiro Okada

Publisher: Springer Science & Business Media

Published: 2008-10-10

Total Pages: 450

ISBN-13: 3540707581

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Over the past decade the topic of energy and environment has been ackno- edged among many people as a critical issue to be solved in 21st century since the Kyoto Protocol came into e?ect in 1997. Its political recognition was put forward especially at Heiligendamm in 2007, when the e?ect of carbon dioxide emission and its hazard in global climate were discussed and shared univ- sallyascommonknowledge.Controllingtheglobalwarmingintheeconomical framework of massive development worldwide through this new century is a very challenging problem not only among political, economical, or social c- cles but also among technological or scienti?c communities. As long as the humans depend on the combustion of fossil for energy resources, the waste heat exhaustion and CO emission are inevitable. 2 In order to establish a new era of energy saving and environment benign society, which is supported by technologies and with social consensus, it is important to seek for a framework where new clean energy system is inc- porated as infrastructure for industry and human activities. Such a society strongly needs innovative technologies of least CO emission and e?cient en- 2 ergy conversion and utilization from remaining fossil energies on the Earth. Energy recycling system utilizing natural renewable energies and their c- version to hydrogen may be the most desirable option of future clean energy society. Thus the society should strive to change its energy basis, from foss- consuming energy to clean and recycling energy.


Molecularly Imprinted Catalysts

Molecularly Imprinted Catalysts

Author: Songjun Li

Publisher: Elsevier

Published: 2015-09-30

Total Pages: 312

ISBN-13: 012801444X

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Molecularly Imprinted Catalysts: Principle, Synthesis, and Applications is the first book of its kind to provide an in-depth overview of molecularly imprinted catalysts and selective catalysis, including technical details, principles of selective catalysis, preparation processes, the catalytically active polymers themselves, and important progress made in this field. It serves as an important reference for scientists, students, and researchers who are working in the areas of molecular imprinting, catalysis, molecular recognition, materials science, biotechnology, and nanotechnology.Comprising a diverse group of experts from prestigious universities and industries across the world, the contributors to this book provide access to the latest knowledge and eye-catching achievements in the field, and an understanding of what progress has been made and to what extent it is being advanced in industry. - The first book in the field on molecularly imprinted catalysts (MIPs) - Provides a systematic background to selective catalysis, especially the basic concepts and key principles of the different MIP-based catalysts - Features state-of-the art presentation of preparation methods and applications of MIPs - Written by scientists from prestigious universities and industries across the world, and edited by veteran researchers in molecular imprinting and selective catalysis


Advanced Zeolite Science and Applications

Advanced Zeolite Science and Applications

Author: Michael Stöcker

Publisher: Elsevier

Published: 1994-07-19

Total Pages: 715

ISBN-13: 0080886957

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Zeolites and related microporous materials are used in oil processing and in the fine and petrochemical industries on a large scale. New applications of zeolites contribute to environmentally friendly processes and refined zeolites such as catalytic zeolite membranes and zeolites containing exhaust-pipe reactors are being introduced. Recent diversity in zeolite research has been fueled by the increase in number of microporous materials and the combination with interfacing science areas. The possibility to accommodate ions, large molecules or nanostructures in the crystalline matrix has been explored and the performance of electronic, acoustic and photonic modified response of the materials has been tested.This volume provides up-to-date information on new zeolite and related materials and composites, their applications, testing of new processes and techniques, and promising laboratory results as well. A vast amount of work from a fundamental aspect is incorporated. In particular, the combination of science and application offers useful information for readers interested in molecular sieves.


Fundamentals of Molecular Catalysis

Fundamentals of Molecular Catalysis

Author:

Publisher: Elsevier

Published: 2003-04-02

Total Pages: 537

ISBN-13: 0080532136

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Almost all contemporary organic synthesis involve transition metal complexes as catalysts or particular reagents. The aim of this book is to provide the reader with detailed accounts of elementary processes within molecular catalysis to allow its development and as an aid in designing novel catalytic systems. The book comprises authoritative reviews on elementary processes from experts working at the forefront of organometallic chemistry. · This is the first book that focuses on elementary processes in transition metal complexes for understanding catalytic mechanisms· Provides detailed description of elementary processes involved in catalytic cycles by experts in the field· Provides an overview of the mechanisms of various homogeneous catalyses


Heterogeneous Catalysis for Sustainable Energy

Heterogeneous Catalysis for Sustainable Energy

Author: Landong Li

Publisher: John Wiley & Sons

Published: 2022-05-03

Total Pages: 755

ISBN-13: 3527815910

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Heterogeneous Catalysis for Sustainable Energy Explore the state-of-the-art in heterogeneous catalysis In Heterogeneous Catalysis for Sustainable Energy, a team of distinguished researchers delivers a comprehensive and cutting-edge treatment of recent advancements in energy-related catalytic reactions and processes in the field of heterogeneous catalysis. The book includes extensive coverage of the hydrogen economy, methane activation, methanol-to-hydrocarbons, carbon dioxide conversion, and biomass conversion. The authors explore different aspects of the technology, like reaction mechanisms, catalyst synthesis, and the commercial status of the reactions. The book also includes: A thorough introduction to the hydrogen economy, including hydrogen production, the reforming of oxygen-containing chemicals, and advances in Fischer-Tropsch Synthesis Comprehensive explorations of methane activation, including steam and dry reforming of methane and methane activation over zeolite catalysts Practical discussions of alkane activation, including cracking of hydrocarbons to light olefins and catalytic dehydrogenation of light alkanes In-depth examinations of zeolite catalysis and carbon dioxide as C1 building block Perfect for catalytic, physical, and surface chemists, Heterogeneous Catalysis for Sustainable Energy also belongs in the libraries of materials scientists with an interest in energy-related reactions and processes in the field of heterogeneous catalysis.


Designed Molecular Space in Material Science and Catalysis

Designed Molecular Space in Material Science and Catalysis

Author: Seiji Shirakawa

Publisher: Springer

Published: 2018-09-26

Total Pages: 263

ISBN-13: 9811312567

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This book focuses on molecular space chemistry, which is recognized as an important concept for the design of novel functional materials and catalysts. A wide variety of topics and ideas included in this book are based on that concept. The book showcases recent representative examples of molecular space design to create functional materials and catalysts possessing unique properties. This unique volume will be of great interest to chemists in a wide variety of research fields, including organic, inorganic, biological, polymer, and supramolecular chemistry. Readers will obtain new ideas and directions to create novel functional molecules, and those ideas will lead to innovative views of science.


Molecular Spectroscopy of Oxide Catalyst Surfaces

Molecular Spectroscopy of Oxide Catalyst Surfaces

Author: Anatoli Davydov

Publisher: John Wiley & Sons

Published: 2003-06-27

Total Pages: 706

ISBN-13:

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As in the study of transition metal complexes in solution, molecular spectroscopic methods - principally the infrared, ultraviolet/visible and electron spin resonance spectroscopies - have played key roles in establishing the concepts of coordination chemistry occurring at the surfaces of solids. This book describes the development of the principals of coordination chemistry of oxide surfaces using analyses of data obtained by these methods. The nature, properties, concentration of the surface adsorption centers and their influence on the character of interaction with different molecules are investigated. The book commences with an account of the basic theoretical principles and experimental techniques of the various spectroscopy methods, with special attention devoted to in situ measurements where the oxide or catalyst sample is in contact with the adsorbate or the reactant. A detailed account is presented of the methods for characterizing the oxidation state and degree of coordination of surface cations and oxygen anions by the adsorption of probe molecules. The complexation of many inorganic, organometallic and organic molecules with different oxide systems is critically examined, and a classification of formed surface compounds, based on the interaction with definite type of adsorption centers, is given. Possible mechanisms of numerous catalytic reactions, including the transformation of organic molecules over acidic catalysts via the carboionic mechanism, are discussed using the spectroscopic identifications of reaction intermediates. A comprehensive analysis of the literature on the interpretation of the spectra of surface compounds on oxides is presented. This highly illustrated and extensively referenced volume is intended for specialists working in the fields of surface physical chemistry, surface and materials sciences, and adsorption phenomena and is essential reading for those involved in the heterogeneous catalysis by transition metal-oxides.