Methods for Monitoring and Diagnosing the Efficiency of Catalytic Converters

Methods for Monitoring and Diagnosing the Efficiency of Catalytic Converters

Author: M. Sideris

Publisher: Elsevier

Published: 1998-06-19

Total Pages: 465

ISBN-13: 0080536492

DOWNLOAD EBOOK

The dramatic evolution of catalytic converters in the last thirty years was a result of a need worldwide to reduce pollution created by the exhaust gases of internal combustion engines. Environmental concerns have led American, Japanese and European Union (EU) legislation to pose continuously stricter emission limits for petrol engines in the last decades. The catalytic converter has become the most important means of exhaust treatment to achieve the desired emission limits. The international legislation has also created a need for a regular assessment of the efficiency of the catalytic converter in order to detect a deterioration of its conversion efficiency as soon as this deterioration takes place. The assessment of conversion efficiency of a catalytic converter can take place during normal driving of a vehicle (on-board diagnosis or OBD) or in a workshop by specialized technicians. The most important methods nowadays are the OBD methods. The evolution of methods concerned with OBD and non-OBD monitoring and diagnosing of efficiency of catalytic converters of internal combustion engines is described based on patents and published patent applications. Non-patent references are also used. The basic principles of modern catalytic converters are described in an extensive Introduction, where the importance of monitoring and diagnosing the efficiency of catalytic converters is demonstrated. The book is divided into four parts. The first part describes methods involving the use of oxygen or air/fuel exhaust gas sensors to determine the oxygen storage capacity of a catalytic converter. The second part describes methods involving the use of temperature sensors to determine the exothermic reaction capacity of a catalytic converter. The third part describes all other methods existing in patent literature that monitor and diagnose the efficiency of catalytic converters. The great majority of the methods of the third part involves exhaust gas concentration measurements. The fourth part comprises a general discussion of all methods described. In the beginning of each part, a short introduction is given to explain the problem that the methods attempt to solve. The methods in each part are presented in chronological order per patent applicant. This helps to evaluate how the patent applicant has improved his methods over time. A patent number index with information about the patent applicants, inventors, priorities and patent-families, an inventor index, a company index and a subject index can be found at the end of the book.


Oxygen storage dominated three-way catalyst modeling

Oxygen storage dominated three-way catalyst modeling

Author: Jeremias Bickel

Publisher: Logos Verlag Berlin GmbH

Published: 2022-01-20

Total Pages: 286

ISBN-13: 3832553827

DOWNLOAD EBOOK

The key to achieve optimal emission performance of a modern three-way catalyst (TWC) under transient engine operating conditions is to maintain an optimal oxidation state of the oxygen storage material inside the washcoat of the catalyst. This work demonstrates how simplified kinetic models can be developed that allow for accurately predicting the oxygen storage level under dynamic operation.


New Trends and Developments in Automotive Industry

New Trends and Developments in Automotive Industry

Author: Marcello Chiaberge

Publisher: BoD – Books on Demand

Published: 2011-01-08

Total Pages: 410

ISBN-13: 9533079991

DOWNLOAD EBOOK

This book is divided in five main parts (production technology, system production, machinery, design and materials) and tries to show emerging solutions in automotive industry fields related to OEMs and no-OEMs sectors in order to show the vitality of this leading industry for worldwide economies and related important impacts on other industrial sectors and their environmental sub-products.


Catalytic Polymerization of Cycloolefins

Catalytic Polymerization of Cycloolefins

Author: V. Dragutan

Publisher: Elsevier

Published: 2000-06-26

Total Pages: 1293

ISBN-13: 0080528627

DOWNLOAD EBOOK

This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trends in design of chiral metallocene catalysts, well-defined living metathesis catalysts, catalysts tolerant toward functionalities and water systems are highlighted. The book discusses in detail the relevant aspects of these processes including reaction thermodynamics, kinetics, mechanisms and stereochemistry and correlates the structure of produced polymers with their chemical and physical-mechanical properties. Related important topics include Ziegler-Natta polymerization of olefins and dienes, atom transfer radical polymerization of vinyl compounds, metathesis of olefins and acetylenes, acyclic diene metathesis reaction, carbonyl olefination reaction, metathesis polymerization of acetylenes, metathesis degradation of polymers and ring-opening polymerization of heterocycles. Special emphasis is laid upon the manufacture of commerical products, new polymers and copolymers of potential interest for industry and design and synthesis of speciality polymers with particular structures and architectures and desired properties. The book critically evaluates the most recent achievements reported in this field and outlines the modern trends on the research and application of the catalytic processes for cycloolefin polymerization. For the first time, comprehensive information about the published data on the subject up to now is provided for both academic and industrial researchers working in the areas of polymer chemistry, organic and organometallic chemistry, surface science and catalysis, petrochemistry and chemical engineering. This stimulating book offers an enlightening introduction and a quick documentation on the subject as well as a solid background in this field. Moreover, the work offers a wealth of useful information for specialists applying polymers in various scientific and industrial areas.


Fluid Catalytic Cracking V

Fluid Catalytic Cracking V

Author: M.L. Occelli

Publisher: Elsevier

Published: 2001-04-27

Total Pages: 355

ISBN-13: 0080531717

DOWNLOAD EBOOK

Catalyst production for the transformation of crudes into gasoline and other fuel products is a billion dollar/year business and fluid cracking catalysts (FCCs) represent almost half of the refinery catalyst market. During the cracking reactions, the FCC surface is contaminated by metals (Ni, V, Fe, Cu, Na) and by coke deposition. As a result, the catalyst activity and product selectivity is reduced to unacceptable levels thus forcing refiners to replace part of the recirculating equilibrium FCC inventory with fresh FCC to compensate for losses in catalyst performance. About 1,100 tons/day of FCC are used worldwide in over 200 fluid cracking catalyst units (FCCUs). It is for these reasons that refiners' interest in FCC research has remained high through the years almost independantly, of crude oil prices. However, recent oil company mergers and the dissolution of research laboratories, have drastically decreased the number of researchers involved in petroleum refining research projects; as a result the emphasis of research has shifted from new materials to process improvements and this trend is clearly reflected in the type of papers contained in this volume. Modern spectroscopic techniques continue to be essential in the understanding of catalyst performance and several chapters in the book describe the use of 27Al, 29Si and 13C NMR to study variation in FCC acidity during aging and coke deposition. In addition several chapters have been dedicated to the modeling of FCC deactivation, and to the understanding of contact times on FCC performance. Refiners efforts to conform with environmental regulations are reflected in chapters dealing with sulfur removal, metals contaminants and olefin generation.


Fluid Catalytic Cracking VI: Preparation and Characterization of Catalysts

Fluid Catalytic Cracking VI: Preparation and Characterization of Catalysts

Author: Mario L. Occelli

Publisher: Elsevier

Published: 2004-07-06

Total Pages: 391

ISBN-13: 0080531725

DOWNLOAD EBOOK

This volume looks at the recent progress of this technology as reported in the 21 papers presented during the 219th National Meeting of the ACS in New York, September 5-11, 2003.In addition, the volume focuses on the use of modern spectroscopic techniques for the generation of detailed structural analysis required for the advancement of the science of FCC design.Other chapters look at the use and importance of solid state nuclear magnetic resonance (NMR), microcalorimetry and atomic force microscopy (AFM) to the study of FCCs and discussing strategies to control pollutant emissions from a refinery FCCU and looking at advances in FCC preparation.


Experiments in Catalytic Reaction Engineering

Experiments in Catalytic Reaction Engineering

Author: J.M. Berty

Publisher: Elsevier

Published: 1999-08-11

Total Pages: 289

ISBN-13: 0080531423

DOWNLOAD EBOOK

The science of catalytic reaction engineering studies the catalyst and the catalytic process in the laboratory in order to predict how they will perform in production-scale reactors. Surprises are to be avoided in the scaleup of industrial processes. The laboratory results must account for flow, heat and mass transfer influences on reaction rate to be useful for scaleup. Calculated performance based on these results must also be useful to maximization of profit and safety and minimization of pollution. To this end, information on products as well as byproducts and heat produced must be generated. If a sufficiently large database of knowledge is produced, optimization studies will be possible later if economic conditions change.The field of reaction engineering required new tools. For kinetic and catalyst testing, the most successful of these tools was the internal recycle reactor. Studies in recycle reactors can be made under well-defined conditions of flow and associated transfer processes, and close to commercial operation. The recycle reactor eliminates or minimizes the effect of transfer process, and allows the remaining ones to be known.Features of this book:• Provides insight into a field that is neither well understood nor properly appreciated.• Gives a deeper understanding of reaction engineering practice.• Helps avoid frustration and disappointment in industrial research. This book is short and clear enough to assist all members of the R&D and Engineering team, whether reaction engineers, or specialists in other fields. This is critical in this new age of computation and communication, when team members must each know at least something of their colleagues' fields. Additionally, many scientists in more exploratory or fundamental fields can use recycle reactors to study basic phenomena free of transfer interactions.


Reaction Kinetics and the Development of Catalytic Processes

Reaction Kinetics and the Development of Catalytic Processes

Author: G.F. Froment

Publisher: Elsevier

Published: 1999-03-18

Total Pages: 491

ISBN-13: 0080540279

DOWNLOAD EBOOK

The symposium "Reaction Kinetics and the Development of Catalytic Processes" is the continuation of the very successful International Symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis", held in September 1997 in Antwerp, Belgium. These proceedings contain a unique series of top level plenary lectures mainly focused on• the dynamics of catalytic surfaces• the interaction of the reacting molecules with the solid catalyst• the elementary steps of reaction pathways and molecular kinetics.Surface science techniques, molecular modeling, transient kinetic studies, sophisticated and specific reactors are included to a growing extent in the kinetic modeling and the development of catalytic processes. How this is practiced today and how it will evolve in the coming years, and what benefit can be expected for a more fundamentally based approach is the aim of the symposium.


Catalyst Deactivation 2001

Catalyst Deactivation 2001

Author: J.J. Spivey

Publisher: Elsevier

Published: 2001-09-21

Total Pages: 537

ISBN-13: 0080528686

DOWNLOAD EBOOK

This proceedings contains the papers presented at the 9th International Symposium on Catalyst Deactivation, held in Lexington, KY, USA, on 7-10 October 2001.


Preparation of Catalysts VII

Preparation of Catalysts VII

Author: R. Maggi

Publisher: Elsevier

Published: 1998-08-17

Total Pages: 1007

ISBN-13: 0080539459

DOWNLOAD EBOOK

The proceedings of the VIIth International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts, are in line with the general scope of this series of events. Emphasis in all Symposia has been on the scientific aspects of the preparation of new and industrial catalysts, or on new methods of preparation, rather than on the catalytic reactions in which such solids are ultimately used. In the present context, the catalytic event itself has only been considered as another, though often decisive, method of catalyst characterization.