Controlled and Living Polymerizations
Controlled and Living Polymerizations

Author: Krzysztof Matyjaszewski

Publisher: John Wiley & Sons

Published: 2009-09-28

Total Pages: 640

ISBN-13: 9783527324927

DOWNLOAD EBOOK

Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

Controlled and Living Polymerizations
Controlled and Living Polymerizations

Author: Krzysztof Matyjaszewski

Publisher: John Wiley & Sons

Published: 2009-12-23

Total Pages: 634

ISBN-13: 9783527629107

DOWNLOAD EBOOK

Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

Fundamentals of Controlled/Living Radical Polymerization
Fundamentals of Controlled/Living Radical Polymerization

Author: Nicolay V Tsarevsky

Publisher: Royal Society of Chemistry

Published: 2013-04-25

Total Pages: 379

ISBN-13: 1849737428

DOWNLOAD EBOOK

Controlled/living radical polymerization (CRP) has revolutionized and revitalized the field of synthetic polymer chemistry over the last twenty years as it is now possible to prepare a wide variety of previously inaccessible macromolecules under relatively mild conditions. Fundamentals of Controlled/Living Radical Polymerization provides an in-depth coverage of the essential chemical principles that enable and govern each of the CRP methods. The book starts with a brief historical overview of the major findings in polymer science which eventually led to the development of living ionic and living radical systems. It then goes on to introduce the main CRP techniques including their mechanistic understanding. The book also provides the information needed to select the appropriate reagents and conditions to conduct various CRP methods in a practical setting. Therefore, in addition to a newcomer gaining an appreciation for what has already been accomplished, the reader will be armed with the tools needed to begin independent research. Fundamentals of Controlled/Living Radical Polymerization provides essential insight into a rapidly growing field that goes beyond a simple literature review of the area. Written by leading experts in the field, the book is an indispensible resource for all researchers, instructors, and students in polymer chemistry.

Living and Controlled Polymerization
Living and Controlled Polymerization

Author: Joseph Jagur-Grodzinski

Publisher: Nova Publishers

Published: 2006

Total Pages: 398

ISBN-13: 9781594543302

DOWNLOAD EBOOK

The living/controlled polymerisation techniques opened new vistas in polymer chemistry. The leading authorities in this field and its pioneers contributed chapters to this collective volume. The controlled polymerisation techniques have enabled preparation of polymers, copolymers, and block copolymers with predetermined molecular weights and narrow polydispersity, in which functional groups or biologically active molecules could be placed at well defined locations. They have also enabled preparation of advanced polymeric structures with precisely determined architectures and improved properties. Moreover, they have provided opportunities for preparation of novel polymeric materials from monomers, which before have not been suitable or accessible for such purposes. Properties of some of these polymeric materials may be significantly different from those of the existing ones. They provide opportunities for new applications. Several patents have already been approved for such speciality applications as, drug delivery, biocompatible surfaces, thermoplastic elastomers, moisture curable sealants, and so on. Many more products, based on polymers fabricated by the living/ controlled polymerisation techniques, will certainly emerge in such specialised areas as, nanotechnology, medical devices, "smart polymers", sensors , smart separation technologies, optical fibres and other optical applications, various biomaterials, etc.

Handbook of Radical Polymerization
Handbook of Radical Polymerization

Author: Krzysztof Matyjaszewski

Publisher: John Wiley & Sons

Published: 2003-04-14

Total Pages: 934

ISBN-13: 0471461571

DOWNLOAD EBOOK

Klassische und moderne Verfahren der radikalischen Polymerisation: In diesem handlichen Band finden Sie Antworten auf theoretische und praktische Fragen. Neben grundlegenden Ausführungen zur Einteilung radikalischer Polymere sind Angaben über die wichtigsten experimentellen Verfahren zur Synthese, Reinigung und Charakterisierung von Polymeren enthalten. Interessante Zugabe: ein Abriß der Geschichte der Radikalkettenpolymerisation.

Controlled/Living Radical Polymerization
Controlled/Living Radical Polymerization

Author: Krzysztof Matyjaszewski

Publisher: OUP USA

Published: 2007-01-04

Total Pages: 0

ISBN-13: 9780841239913

DOWNLOAD EBOOK

The preparation and characterization of new materials with precisely controlled macromolecular dimensions, functionalities, and decomposition, as well as with well-defined topologies, is perhaps the main focus of contemporary polymer synthesis. The best control of molecular functions can be achieved in a controlled/living polymerization -- a chain growth process without chain breaking reactions. Recently, controlled/living polymerizations have extended to radical systems which are not only commercially important, but also have the largest potential due to the availability of radically polymerizable monomers, facile copolymerization and undemanding experimental conditions. Controlled Radical Polymerization will examine recent advances in mechanistic and synthetic aspects of controlled/living radical (co)polymerization systems. Not only will this book be focused on recent progress in the dynamically developing field of controlled/living radical polymerization, but it will be a sequel to the very popular ACS Symposium Series 685, 768, and 854. The book will consist of >30 chapters separated into seven subsections: Fundamentals, Mechanism of ATRP, Mechanisms of SFRP and Degenerative Transfer Processes, Controlled Architecture by CRP, Organic-inorganic Hybrids by CRP, Biomaterials by CRP and Industrial Applications. This book targets chemists and polymer scientists in academia and in industry.

Out-of-Equilibrium (Supra)molecular Systems and Materials
Out-of-Equilibrium (Supra)molecular Systems and Materials

Author: Nicolas Giuseppone

Publisher: John Wiley & Sons

Published: 2021-03-30

Total Pages: 448

ISBN-13: 3527821988

DOWNLOAD EBOOK

A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.

Advances in Controlled/living Radical Polymerization
Advances in Controlled/living Radical Polymerization

Author: Krzysztof Matyjaszewski

Publisher:

Published: 2003

Total Pages: 712

ISBN-13:

DOWNLOAD EBOOK

Advances in Controlled/Living Radical Polymerization presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). This book also includes synthesis and characterization of many new materials.

Monitoring Polymerization Reactions
Monitoring Polymerization Reactions

Author: Wayne F. Reed

Publisher: John Wiley & Sons

Published: 2014-01-21

Total Pages: 493

ISBN-13: 0470917385

DOWNLOAD EBOOK

Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.