Lanthanides: Chemistry and Use in Organic Synthesis
Author: Shu Kobayashi
Publisher: Springer
Published: 2003-07-01
Total Pages: 311
ISBN-13: 3540698019
DOWNLOAD EBOOKWith contributions by numerous experts
Posts
Lanthanides
Author: Shu Kobayashi
Publisher: Springer
Published: 2014-01-15
Total Pages: 320
ISBN-13: 9783662142301
DOWNLOAD EBOOKThe use of lanthanides in organic chemistry and in organic synthesis has attracted broad interest recently because of the unique reactivities and selectivities exhibited by compounds of these rare earth elements. In particular, several major advances have been made in the last five years. This volume of "Topics in Organometallic Chemistry" is designed to provide the specialist and non-specialist alike with a much needed overview of recent developments. Contributions by leaders in the field focus on stereoselective organic synthesis using lanthanides, the principles of lanthanide chemistry, lanthanide-based chiral catalysts, low-valent lanthanide compounds, polymer synthesis using lanthanide catalysts, and polymer-supported lanthanide catalysts used in organic synthesis.
Lanthanides And Actinides, The: Synthesis, Reactivity, Properties And Applications
Author: Stephen T Liddle
Publisher: World Scientific
Published: 2021-12-30
Total Pages: 727
ISBN-13: 1800610173
DOWNLOAD EBOOKThe Lanthanides and Actinides: Synthesis, Reactivity, Properties and Applications constitutes an introduction to and comprehensive coverage of f-block chemistry encompassing the following areas: periodicity, natural occurrence and extraction, separations, electronic structure, coordination chemistry, organometallic chemistry, small molecule activation, catalysis, organic synthesis applications, magnetism, spectroscopy, computation, materials, photonics, solar cell technology, biological imaging, and technological applications. Under these subject areas the book provides a broad but deep coverage, providing basic overviews as well as detailed chapters on specific areas.This book, targeted at academics, postgraduates and advanced undergraduates, will serve as an ideal introductory text and key reference work to the Lanthanides and Actinides.
Lanthanides in Organic Synthesis
Author: Tsuneo Imamoto
Publisher:
Published: 1994
Total Pages: 184
ISBN-13:
DOWNLOAD EBOOKOrganic synthesis with lanthanides has experienced enormous growth in the last ten years. Numerous synthetic reactions have been explored by the use of lanthanide reagents, and some of these have become indispensablein modern organic synthesis. This book describes the remarkable scope and potential of these reagents, addressing this rapidly growing area from a practical point-of-view. The author has summarized synthetically useful and novel organic transformations, emphasizing the characteristic properties of lanthanide reagents. These transformations are concisely and skillfully presented in many schemes and tables, with actual illustrative preparations. The coverage includes the use of lanthanide metals, the powerful divalent reagents such as samarium (II) iodide, the key trivalent reagents and their particular role as catalysts in selective reductions and cycloadditions, and the tetravalent lanthanides as oxidants. Describes the remarkable scope and potential of lanthanide reagents from a practical point-of-view Presents actual experimental procedures Provides a concise presentation of useful and novel organic transformations in table format
The Lanthanides and Actinides
Author: Stephen Taylor Liddle
Publisher:
Published: 2021
Total Pages: 727
ISBN-13: 9781800610163
DOWNLOAD EBOOK"The Lanthanides and Actinides: Synthesis, Reactivity, Properties and Applications constitutes an introduction to and comprehensive coverage of f-block chemistry encompassing the following areas: periodicity, natural occurrence and extraction, separations, electronic structure, coordination chemistry, organometallic chemistry, small molecule activation, catalysis, organic synthesis applications, magnetism, spectroscopy, computation, materials, photonics, solar cell technology, biological imaging, and technological applications. Under these subject areas the book provides a broad but deep coverage, providing basic overviews as well as detailed chapters on specific areas. This book, targeted at academics, postgraduates and advanced undergraduates, will serve as an ideal introductory text and key reference work to the Lanthanides and Actinides"--
Synthesis of Lanthanide and Actinide Compounds
Author: G. Meyer
Publisher: Springer Science & Business Media
Published: 2012-12-06
Total Pages: 377
ISBN-13: 9401137587
DOWNLOAD EBOOKLanthanide and Actinide Chemistry
Author: Simon Cotton
Publisher: John Wiley & Sons
Published: 2013-03-15
Total Pages: 308
ISBN-13: 1118681363
DOWNLOAD EBOOKThe only introduction into the exciting chemistry of Lanthanides and Actinides. The book is based on a number of courses on "f elements" The author has a long experience in teaching this field of chemistry Lanthanides have become very common elements in research and technology applications; this book offers the basic knowledge The book offers insights into a vast range of applications, from lasers to synthesis The Inorganic Chemistry: A Textbook series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas, such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry. Lanthanide and Actinide Chemistry is a one-volume account of the Lanthanides (including scandium and yttrium), the Actinides and the Transactinide elements, intended as an introductory treatment for undergraduate and postgraduate students. The principal features of these elements are set out in detail, enabling clear comparison and contrast with the Transition Elements and Main Group metals. The book covers the extraction of the elements from their ores and their purification, as well as the synthesis of the man-made elements; the properties of the elements and principal binary compounds; detailed accounts of their coordination chemistry and organometallic chemistry, from both preparative and structural viewpoints, with a clear explanation of the factors responsible for the adoption of particular coordination numbers; spectroscopy and magnetism, especially for the lanthanides, with case studies and accounts of applications in areas like magnetic resonance imaging, lasers and luminescence; nuclear separations and problems in waste disposal for the radioactive elements, particularly in the context of plutonium. Latest developments are covered in areas like the synthesis of the latest man-made elements, whilst there is a whole chapter on the application of lanthanide compounds in synthetic organic chemistry. End-of-chapter questions suitable for tutorial discussions are provided, whilst there is a very comprehensive bibliography providing ready access to further reading on all topics.
Lanthanide Probes in Life, Chemical, and Earth Sciences
Author: J.-C. G. Bünzli
Publisher:
Published: 1989
Total Pages: 456
ISBN-13:
DOWNLOAD EBOOKLanthanide elements were first used some thirty years ago in the optical glass industry, followed shortly by their use as NMR shift reagents in organic chemistry. Since then, the application of lanthanides in studies of organic and biochemical systems by use of their NMR and spectroscopic properties has created a rapidly growing interest in the physics and chemistry of these elements. Their use in industrial catalysts, electronic and optical components, high-temperature superconductors, in medicine as X-ray intensifying materials, relaxation agents for imaging techniques or radioisotopes for pharmaceutical applications, have combined with their utilisation in science as probes of a wide variety of phenomena giving them a prominent place in modern science. In this book, leading experts describe the various facets of the application of lanthanides as probes in life, chemical and earth sciences. The aim is to provide guidance to scientists who may wish to use the unique advantages of lanthanide probes in their own fields.To supplement the chapters on the basic concepts of the application of lanthanides, chapters are provided on the basic chemistry of these elements and on the synthetic and analytical aspects of lanthanides and their compounds. The book thus provides a great deal of useful information which will no doubt assist scientists in using these fascinating and valuable elements in their research.
Strategies and Tactics in Organic Synthesis
Author: Michael J. Hudson
Publisher: Elsevier Inc. Chapters
Published: 2013-07-29
Total Pages: 35
ISBN-13: 0128056096
DOWNLOAD EBOOKThis account describes the scientific events that have led from malonamides which coextract minor actinide and lanthanide fission products, to the 1,2,4-triazines such as BTBP and BTPhen reagents that are capable of separating Am(III) from Eu(III). The journey started with Mike Hudson having a walk in hot and dusty Rome with Claude Musikas of the CEA in 1980 and continues to Mike enjoying a celebratory beer (or two) in Reading (2012) with Laurence Harwood and Frank Lewis. Throughout the journey, organic synthesis, coupled with coordination chemistry, has been the engine by which successful science has developed.
Organic Synthesis Using Samarium Diiodide
Author: David J. Procter
Publisher: Royal Society of Chemistry
Published: 2010
Total Pages: 221
ISBN-13: 1847551106
DOWNLOAD EBOOKSamarium diiodide is one of the most important reducing agents available to synthetic organic chemists. The lanthanide(II) reagent acts by single-electron transfer to organic substrates leading to the formation of both radical and/or anionic intermediates. The power of the reagent arises from its versatility - samarium diiodide can be used in processes ranging from functional group conversions to elaborate carbon-carbon bond-forming cyclization sequences that result in a dramatic increase in molecular complexity. In addition, reactions involving samarium diiodide often show high stereoselectivity as samarium ions can coordinate to Lewis basic sites on substrates and can direct the stereochemical course of reactions. The ability to fine-tune the reactivity of the reagent by the use of additives and co-solvents is an additional, attractive feature. Although samarium diiodide is used extensively by organic chemists, there is still a widely held view that the reagent can be difficult to prepare and use. In addition, samarium diiodide can mediate such a wide variety of organic chemistry that potential new users are often overawed by the extensive primary literature on the reagent. The objective of this book is to provide a concise, practical guide to the reagent. Rather than being a comprehensive review of the chemistry of samarium diiodide, this user-friendly book adopts an "an all you need to know" approach to the topic. The international authors are well-known for their work with the reagent and their expertise covers current developments in new reactivity and selectivity, applications in target synthesis, co-solvent and additive effects, coordination chemistry and mechanism. The book includes the best methods for preparing and handling the reagent, how solvents, co-solvents and additives alter reactivity, the basic mechanisms of reactions, common transformations using the reagent, and emerging areas in samarium diiodide chemistry. The authors have distilled the extensive primary literature to allow the reader to quickly grasp an understanding of the reagent and its utility. The illustrative practical procedures help the reader to prepare and use the reagent in the laboratory while references from the recent literature allow readers to pursue their interest in the popular reagent. The book also contains many illustrations and chemical schemes.
