This book of general analytical chemistry – as opposed to instrumental analysis or separation methods – in aqueous solutions is focuses on fundamentals, which is an area too often overlooked in the literature. Explanations abound of the chemical and physical principles of different operations of chemical analysis in aqueous solutions. Once these principle are firmly established, numerous examples of applications are also given.
A celebrated classic in the field updated and expanded to includethe latest computerized calculation techniques In 1964, James N. Butler published a book in which he presentedsome simple graphical methods of performing acid-base, solubility,and complex formation equilibrium calculations. Today, both thebook and these methods have become standard for generations ofstudents and professionals in fields ranging from environmentalscience to analytical chemistry. Named a "Citation Classic" by theScience Citation Index in 1990, the book, Ionic Equilibrium,continues to be one of the most widely used texts on the subject.So why tamper with near-perfection by attempting a revision of thatclassic? The reason is simple-- the recent rapid development andwide availability of personal computers. In the revised Ionic Equilibrium, Dr. Butler updates his 1964 workby abandoning the slide rule and graph paper for the PCspreadsheet. He also expands the original coverage with extensivematerial on basic principles and recent research. The first part of Ionic Equilibrium is devoted to the fundamentalsof acid-base, solubility, and complex formation equilibria. In thesecond part, the author discusses oxidation-reduction equilibria,develops the principles of carbon dioxide equilibria, presents casestudies demonstrating the ways in which carbon dioxide equilibriaare used in physiology and oceanography, and explores thepossibility of a pH scale for brines. The concluding chapter,written by David R. Cogley, gives examples of general computerprograms that are capable of performing equilibrium calculations onsystems of many components. Replete with real-world examples, details of importantcalculations, and practical problems, Ionic Equilibrium is an idealcourse text for students of environmental chemistry, engineering,or health; analytical chemistry; oceanography; geochemistry;biochemistry; physical chemistry; and clinical chemistry. It isalso a valuable working resource for professionals in those fieldsas well as industrial chemists involved with solution chemistry.
This book of general analytical chemistry – as opposed to instrumental analysis or separation methods – in aqueous solutions is focuses on fundamentals, which is an area too often overlooked in the literature. Explanations abound of the chemical and physical principles of different operations of chemical analysis in aqueous solutions. Once these principle are firmly established, numerous examples of applications are also given.
This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been paid to the rigor of mathematical developments. This sixth volume is made up of two parts. The first part focuses on the study of ionic equilibria in water or non-aqueous solvents. The following are then discussed in succession: the dissociation of electrolytes, solvents and solvation, acid-base equilibria, formation of complexes, redox equilibria and the problems of precipitation. Part 2 discusses electrochemical thermodynamics, with the study of two groups: electrodes and electrochemical cells. The book concludes with the study of potential-pH diagrams and their generalization in an aqueous or non-aqueous medium.
Buy Latest (Chemistry) Physical Chemistry: States of Matter and Ionic Equilibrium e-Book in English Edition for B.Sc 2nd Semester Bihar State By Thakur publication.
This book provides a comprehensive overview of ionic liquid based separation techniques. The glimpse of thermodynamic predictive models along with global optimization techniques will help readers understand the separation techniques at molecular and macroscopic levels. Experimental and characterization techniques are coupled with model based predictions so as to provide multicomponent data for the scientific community. The models will focus more on the a-priori based predictions which gives higher emphasis on hydrogen-bonded systems. Particle Swarm Optimization (PSO) technique will also eventually help the readers to apply optimization technique to an extraction process. The overriding goal of this work is to provide pathways for leading engineers and researchers toward a clear understanding and firm grasp of the phase equilibria of Ionic Liquid systems.
Concepts, procedures and programs described in this book make it possible for readers to solve both simple and complex equilibria problems quickly and easily and to visualize results in both numerical and graphical forms. They allow the user to calculate concentrations of reactants and products for both simple and complicated situations. The user can spend less time doing calculations and more time thinking about what the results mean in terms of a larger problem in which she or he may be interested.
