Inorganic Chemistry Series One; Volume 5: Transition Metals
Author: Emeleus HJ.
Publisher:
Published: 1972
Total Pages:
ISBN-13:
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Author: Emeleus HJ.
Publisher:
Published: 1972
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: Jon McCleverty
Publisher: OUP Oxford
Published: 1999-01-28
Total Pages: 100
ISBN-13: 9780198501510
DOWNLOAD EBOOKThe transition metals titanium, vanadium, chromium, manganese, iron, cobalt, nickel and copper are essential for many life-processes, are at the heart of important industrial processes, and are used in everyday life. Their properties are dependent on the electronic structure of the metals. The connection between this and the chemical behaviour of these metals is described in this book.
Author: Emeleus HJ.
Publisher:
Published: 1972
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: Mandeep Dalal
Publisher: Dalal Institute
Published: 2017-01-01
Total Pages: 480
ISBN-13: 8193872002
DOWNLOAD EBOOKAn advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author: H.J. Emeléus
Publisher:
Published: 1972
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: B F G Johnson
Publisher: Royal Society of Chemistry
Published: 2007-10-31
Total Pages: 542
ISBN-13: 1847556469
DOWNLOAD EBOOKSpecialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author:
Publisher:
Published: 1972
Total Pages: 418
ISBN-13:
DOWNLOAD EBOOKAuthor: H.J. Emeléus
Publisher:
Published: 1972
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: R. Bruce King
Publisher: John Wiley & Sons
Published: 2005-10-14
Total Pages: 304
ISBN-13:
DOWNLOAD EBOOKThe ultimate resource on inorganic chemistry – new and completely revised, 10 years after publication of the First Edition The first edition of the Encyclopedia of Inorganic Chemistry treated the elements of the periodic system in alphabetical order, with multiple entries for key elements. The articles from the First Edition were written more than 10 years ago and all areas of inorganic chemistry have seen such a vigorous development that it was necessary to update most articles and to add a considerable number of new articles. The result of this major work is the proud Encylopedia of Inorganic Chemistry Second Edition (EIC-2). New – now includes colour 30% growth on previous edition – now 6,640 pages, published in 10 volumes EIC-2 continues to present articles in alphabetical order, but the content has been slightly reorganized to the following subject areas: Main Group Elements; Transition Metals and Coordination Chemistry; Organometallic Chemistry; Bioinorganic Chemistry; Solid State, Materials, Nanomaterials and Catalysis; and General Inorganic Chemistry, Theoretical and Computational Methods.
Author: Louis S. Hegedus
Publisher: University Science Books
Published: 1999
Total Pages: 358
ISBN-13: 9781891389047
DOWNLOAD EBOOKThis second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.