Inorganic Chemistry

Inorganic Chemistry

Author: William W. Porterfield

Publisher: Academic Press

Published: 2013-04-12

Total Pages: 938

ISBN-13: 0323138942

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This is one of the few books available that uses unifying theoretical concepts to present inorganic chemistry at the advanced undergraduate and graduate levels--most texts are organized around the periodic table, while this one is structured after bonding models, structure types, and reaction patterns. But the real strength of Porterfield's Second Edition is its clear presentation of ample background description, especially in recent areas of development such as cluster molecules, industrial catalysis, and bio-inorganic chemistry. This information will enable students to understand most current journals, empowering them to stay abreast of the latest advances in the field. Specific improvements of the Second Edition include new chapters on materials-science applications and bioinorganic chemistry, an extended discussion of transition-metal applications (including cuprate superconductors), and extended Tanabe-Sugano diagrams. - Extended treatment of inorganic materials science--ceramics, refractories, magnetic materials, superconductors--in the context of solid-state chemistry - Extended coverage of biological systems and their chemical and physiological consequences--02 metabolism, N2 fixation, muscle action, iron storage, cisplatin and nucleic acid structural probes, and photosynthesis - Unusual structures and species--silatranes, metallacarboranes, alkalides and electrides, vapor-deposition species, proton and hybrid sponges, massive transition-metal clusters, and agostic ligands - Thorough examination of industrial processes using organometallic catalysts and their mechanisms - Entropy-driven reactions - Complete discussion of inorganic photochemistry


Advanced Inorganic Chemistry

Advanced Inorganic Chemistry

Author: F. Albert Cotton

Publisher: John Wiley & Sons

Published: 1999-04-13

Total Pages: 1380

ISBN-13: 0471199575

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For more than a quarter century, Cotton and Wilkinson's Advanced Inorganic Chemistry has been the source that students and professional chemists have turned to for the background needed to understand current research literature in inorganic chemistry and aspects of organometallic chemistry. Like its predecessors, this updated Sixth Edition is organized around the periodic table of elements and provides a systematic treatment of the chemistry of all chemical elements and their compounds. It incorporates important recent developments with an emphasis on advances in the interpretation of structure, bonding, and reactivity.“/p> From the reviews of the Fifth Edition: "The first place to go when seeking general information about the chemistry of a particular element, especially when up-to-date, authoritative information is desired." —Journal of the American Chemical Society "Every student with a serious interest in inorganic chemistry should have [this book]." —Journal of Chemical Education "A mine of information . . . an invaluable guide." —Nature "The standard by which all other inorganic chemistry books are judged." —Nouveau Journal de Chimie "A masterly overview of the chemistry of the elements." —The Times of London Higher Education Supplement "A bonanza of information on important results and developments which could otherwise easily be overlooked in the general deluge of publications." —Angewandte Chemie


Descriptive Inorganic Chemistry

Descriptive Inorganic Chemistry

Author: Geoff Rayner-Canham

Publisher: Macmillan Higher Education

Published: 2014-09-19

Total Pages: 764

ISBN-13: 1464176809

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This bestselling text gives students a less rigorous, less mathematical way of learning inorganic chemistry, using the periodic table as a context for exploring chemical properties and uncovering relationships between elements in different groups. The authors help students understand the relevance of the subject to their lives by covering both the historical development and fascinating contemporary applications of inorganic chemistry (especially in regard to industrial processes and environmental issues). The new edition offers new study tools, expanded coverage of biological applications, and new help with problem-solving.


A Textbook of Inorganic Chemistry – Volume 1

A Textbook of Inorganic Chemistry – Volume 1

Author: Mandeep Dalal

Publisher: Dalal Institute

Published: 2017-01-01

Total Pages: 482

ISBN-13: 8193872002

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An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.


Fundamentals of Inorganic Chemistry

Fundamentals of Inorganic Chemistry

Author: J Barrett

Publisher: Horwood Publishing

Published: 1998

Total Pages: 324

ISBN-13: 9781898563389

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With Fundamentals of Inorganic Chemistry, two well-known teachers combine their experience to present an introductory text for first and second year undergraduates.


Synthesis and Technique in Inorganic Chemistry

Synthesis and Technique in Inorganic Chemistry

Author: Gregory S. Girolami

Publisher: University Science Books

Published: 1999

Total Pages: 292

ISBN-13: 9780935702484

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Previously by Angelici, this laboratory manual for an upper-level undergraduate or graduate course in inorganic synthesis has for many years been the standard in the field. In this newly revised third edition, the manual has been extensively updated to reflect new developments in inorganic chemistry. Twenty-three experiments are divided into five sections: solid state chemistry, main group chemistry, coordination chemistry, organometallic chemistry, and bioinorganic chemistry. The included experiments are safe, have been thoroughly tested to ensure reproducibility, are illustrative of modern issues in inorganic chemistry, and are capable of being performed in one or two laboratory periods of three or four hours. Because facilities vary from school to school, the authors have included a broad range of experiments to help provide a meaningful course in almost any academic setting. Each clearly written & illustrated experiment begins with an introduction that hig! hlights the theme of the experiment, often including a discussion of a particular characterization method that will be used, followed by the experimental procedure, a set of problems, a listing of suggested Independent Studies, and literature references.


Inorganic Chemistry

Inorganic Chemistry

Author: Gary Wulfsberg

Publisher: University Science Books

Published: 2000-03-16

Total Pages: 1012

ISBN-13: 9781891389016

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This is a textbook for advanced undergraduate inorganic chemistry courses, covering elementary inorganic reaction chemistry through to more advanced inorganic theories and topics. The approach integrates bioinorganic, environmental, geological and medicinal material into each chapter, and there is a refreshing empirical approach to problems in which the text emphasizes observations before moving onto theoretical models. There are worked examples and solutions in each chapter combined with chapter-ending study objectives, 40-70 exercises per chapter and experiments for discovery-based learning.


Chemistry

Chemistry

Author: Bruce Averill

Publisher:

Published: 2007

Total Pages: 1233

ISBN-13: 9780321413703

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Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.