In-Situ Studies of Metal on III-V Semiconductors

In-Situ Studies of Metal on III-V Semiconductors

Author:

Publisher:

Published: 1997

Total Pages: 8

ISBN-13:

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Research has been performed using high resolution electron microscopy under ultra-high vacuum (UHV) conditions on a number of metal semiconductor systems. The new system combining classical surface characterization techniques and growth has been installed on a UHV microscope and fully tested. The growth at the monolayer level of Au and Ay on Si (001) has been studied combining XPS and electron microscopy. Studies of the growth of Au on both air introduced and Ga-rich GaAs (001) substrates have been performed. A variety of new methodologies and techniques have been developed, most notably atomic scale imaging of surfaces at a higher level than previously possible and new methods of determining surface structures just from electron (or x-ray) diffraction data. Electron microscopy studies of MoS2 lubricant films are also described.


Equipment for In-Situ Studies of Metal on III-V Semiconductors

Equipment for In-Situ Studies of Metal on III-V Semiconductors

Author:

Publisher:

Published: 1995

Total Pages: 3

ISBN-13:

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This supplemental grant was used to purchase a badly needed workstation for modeling of quantitative electron diffraction patterns from surfaces. The equipment purchased was an Hewlett-Packard 715/75 workstation. For reasons which are not completely clear, this computer ended up costing $58.78 less than the quote from Hewlett-Packard upon which the proposed budget was based. In addition to providing additional computing power for calculating diffraction patterns from surfaces, it also opened up completely new areas. Perhaps the most exciting of these is compute intensive image filtering based around Wiener filters 4-5 which have allowed us to directly resolve atomic surface structures at a resolution of better than 0.25 nm 1,3,6. We have also used these new filter methods of image restorations in a very large number of cases for work both directly supported by AFOSR and by other agencies. It is realistic to state that with these filters we have almost completely abandoned dark-room chemical printing for digital processing images, at a substantial long-term reduction in costs. jg p.3.


Fundamentals of III-V Semiconductor MOSFETs

Fundamentals of III-V Semiconductor MOSFETs

Author: Serge Oktyabrsky

Publisher: Springer Science & Business Media

Published: 2010-03-16

Total Pages: 451

ISBN-13: 1441915478

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Fundamentals of III-V Semiconductor MOSFETs presents the fundamentals and current status of research of compound semiconductor metal-oxide-semiconductor field-effect transistors (MOSFETs) that are envisioned as a future replacement of silicon in digital circuits. The material covered begins with a review of specific properties of III-V semiconductors and available technologies making them attractive to MOSFET technology, such as band-engineered heterostructures, effect of strain, nanoscale control during epitaxial growth. Due to the lack of thermodynamically stable native oxides on III-V's (such as SiO2 on Si), high-k oxides are the natural choice of dielectrics for III-V MOSFETs. The key challenge of the III-V MOSFET technology is a high-quality, thermodynamically stable gate dielectric that passivates the interface states, similar to SiO2 on Si. Several chapters give a detailed description of materials science and electronic behavior of various dielectrics and related interfaces, as well as physics of fabricated devices and MOSFET fabrication technologies. Topics also include recent progress and understanding of various materials systems; specific issues for electrical measurement of gate stacks and FETs with low and wide bandgap channels and high interface trap density; possible paths of integration of different semiconductor materials on Si platform.


Preparation and Characterization of In-situ Deposited Metal-insulator-III-V Semiconductor Devices

Preparation and Characterization of In-situ Deposited Metal-insulator-III-V Semiconductor Devices

Author: David Sai Lai Mui

Publisher:

Published: 1992

Total Pages: 296

ISBN-13:

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In this thesis, the growth, fabrication, and characterization of in-situ deposited III-V semiconductor-based Metal-Insulator-Semiconductor (MIS) devices are described. The two III-V semiconductors investigated were $rm Insb{0.53}Gasb{0.47}As$ and GaAs. The problems related to air exposure of the semiconductor surface in ex-situ process was circumvented in this work by depositing the insulator in-situ. A special growth system which integrates several MBE growth chambers with an ultrahigh vacuum chemical vapor deposition chamber was designed and built. All of the chambers in this growth system are connected by vacuum transfer tubes and sample transfer takes place under ultrahigh vacuum conditions. The technique of electron cyclotron resonance plasma-assisted deposition was used for the deposition of $rm Sisb3Nsb4$ and Si. By using a spatially extended interface, the role of tunneling-related trapping in accumulation bias was discussed. It was shown that the circuit model on which the conventional SiO$sb2/$Si interface characterization techniques were based was not applicable when tunneling-related trapping occurred. A new circuit model appropriate for tunneling-related trapping was derived. Measured frequency dispersion on ICS interfaces was shown to be adequately explained by the new circuit model. With the new circuit model, the interface trap density near the conduction band edge and the effective thickness of the interface were deduced. In order to utilize these start-of-the-art interfaces in MISFETs, a self-aligned gate process was developed. The gaps between the gate/drain and gate/source metallizations obtained from this self-aligned technique were of the order of 1000-2000 A. Extrinsic transconductances of close to 240 mS/mm of 2.2 $mu$m gate $rm Insb{0.53}Gasb{0.47}As$ depletion mode MIS Field-Effect Transistors were obtained.


A Workshop on 3-5 Semiconductor: Metal Interfacial Chemistry and Its Effect on Electrical Properties, November 3-5, 1986

A Workshop on 3-5 Semiconductor: Metal Interfacial Chemistry and Its Effect on Electrical Properties, November 3-5, 1986

Author: William E. Spicer

Publisher:

Published: 1986

Total Pages: 659

ISBN-13:

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This workshop discusses: The Thermodynamics of Bulk Metal: III-V Systems Related to Interfacial Chemistry; Thermodynamic Considerations of Metal-GaAs Reactions plus TEM Results; Chemistry of Ti: GaAs Interfaces; Questions Concerning Interfacial Chemistry, Equilibrium, and Electrical Properties; The Chemistry and Morphology of Metal/III-V Semiconductor Interfaces; Schottky Barriers on InP(110); Comparison to GaAs(110) Interface; Stables Phases at Reactive Metal/Compound Semiconductor Interfaces; Thermally Stable Ohmic Contact to n- type GaAs; Effects in Ohmic Contacts; Non Alloyed Ohmic Contacts by Solid State Reactions; Large Variations of GaAs Schottky Barrier Height by Interface Layers; Effects on Schottky Barriers of Metal Substitution in Semiconductors; III-V Interfaces: Schottky Barriers vs. Heterojunctions; A Comparison between Conventional and in-situ UHV Processing for Ge/GaAs and Co/GaAs Structures; Electrical Study of Schottky Barriers on Atomically Clean 3-5(110) Surfaces; A Comparison to the Results of Studies Using Surface Sensitive Techniques and Au-GaAs Ohmic Contacts; The Structures of Au/GaAs and A1/GaAs Interfaces; Refractory Silicide Contacts for Self-Aligned GaAs MESFETs; Heterojunction Growth and Impurity Incorporation During Vapor Growth of Compound Semiconductors; Reflection EXAFS Studies of Semiconductor-Metal Interfaces.


III–V Semiconductors

III–V Semiconductors

Author: Herbert C. Freyhardt

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 171

ISBN-13: 3642676111

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Springer-Verlag, Berlin Heidelberg, in conjunction with Springer-Verlag New York, is pleased to announce a new series: CRYSTALS Growth, Properties, and Applications The series presents critical reviews of recent developments in the field of crystal growth, properties, and applications. A substantial portion of the new series will be devoted to the theory, mechanisms, and techniques of crystal growth. Occasionally, clear, concise, complete, and tested instructions for growing crystals will be published, particularly in the case of methods and procedures that promise to have general applicability. Responding to the ever-increasing need for crystal substances in research and industry, appropriate space will be devoted to methods of crystal characterization and analysis in the broadest sense, even though reproducible results may be expected only when structures, microstructures, and composition are really known. Relations among procedures, properties, and the morphology of crystals will also be treated with reference to specific aspects of their practical application. In this way the series will bridge the gaps between the needs of research and industry, the pos sibilities and limitations of crystal growth, and the properties of crystals. Reports on the broad spectrum of new applications - in electronics, laser tech nology, and nonlinear optics, to name only a few - will be of interest not only to industry and technology, but to wider areas of applied physics as well and to solid state physics in particular. In response to the growing interest in and importance of organic crystals and polymers, they will also be treated.