The handbook provides ready information on the fire and chemical reactivity of commonly used chemicals. Its purpose is to provide basic information important to the safe handling of chemicals and to help provide guidance in responding to a hazardous materials incident, in particular, incidents involving reactive chemicals and materials posing fire and explosion hazards. The volume has been written for chemical handling specialists, first responders to hazardous materials incidents, and firefighters. The basic definition used for a hazard materials incident is any situation that may potentiall.
The handbook provides ready information on the fire and chemical reactivity of commonly used chemicals. Its purpose is to provide basic information important to the safe handling of chemicals and to help provide guidance in responding to a hazardous materials incident, in particular, incidents involving reactive chemicals and materials posing fire and explosion hazards. The volume has been written for chemical handling specialists, first responders to hazardous materials incidents, and firefighters. The basic definition used for a hazard materials incident is any situation that may potentially lead to catastrophic fire or explosion, and or human exposed to a toxic chemical. This situation may result from a spill of a hazardous material, a leak from a storage vessel or shipping container, or the mixing of incompatible chemicals whereby a chemical reaction could occur resulting in the release of energy and generation of toxic and perhaps flammable by-products. The volume provides chemical specific information, providing the reader with rigorous information on the chemical of interest.This book is a compendium of chemical specific fire and chemical reactivity data and information. More than 1,000 chemicals have been researched and organized into a reference handbook for fire specialists, chemical handling specialists, and plant safety engineers. The specific information provided for chemicals includes the flammability characteristics, recommended fire extinguishing practices, fire extinguishing agents not to be used, behavior in fires, burning characteristics, chemical reactivity with regard to water and common materials, incompatible chemical mixtures, containment and neutralization methods for spills. This reference book has been designed as a data bank for the hazardous materials handling specialist and industrial safety managers dealing with large chemical inventories. It is intended to be used by fire and loss prevention specialists and as a basis for developing procedures for safe storing and handling of chemicals. The authors have included an extensive physical properties section on chemicals, with information most pertinent to fire response situations.
Written by an engineer for engineers, this book is both training manual and on-going reference, bringing together all the different facets of the complex processes that must be in place to minimize the risk to people, plant and the environment from fires, explosions, vapour releases and oil spills. Fully compliant with international regulatory requirements, relatively compact but comprehensive in its coverage, engineers, safety professionals and concerned company management will buy this book to capitalize on the author's life-long expertise. This is the only book focusing specifically on oil and gas and related chemical facilities. This new edition includes updates on management practices, lessons learned from recent incidents, and new material on chemical processes, hazards and risk reviews (e.g. CHAZOP). Latest technology on fireproofing, fire and gas detection systems and applications is also covered. An introductory chapter on the philosophy of protection principles along with fundamental background material on the properties of the chemicals concerned and their behaviours under industrial conditions, combined with a detailed section on modern risk analysis techniques makes this book essential reading for students and professionals following Industrial Safety, Chemical Process Safety and Fire Protection Engineering courses. - A practical, results-oriented manual for practicing engineers, bringing protection principles and chemistry together with modern risk analysis techniques - Specific focus on oil and gas and related chemical facilities, making it comprehensive and compact - Includes the latest best practice guidance, as well as lessons learned from recent incidents
Accidents involving reactive chemicals can often be prevented, or their effects alleviated, if those handling them have a sound knowledge both of their hazardous properties and of appropriate handling methods. This book addresses this need.It opens with a definition of the key technical terms and evaluation methods for hazardous materials are outlined. Chapter 2 covers accidents involving self-reactive substances, accidents occurring during chemical reactions, and accidents involving hazardous products in the event of an earthquake. In the next three chapters, methods for evaluating fire and explosion hazards of reactive substances are covered. The test methods described include DSC test using a sealed cell, impact sensitivity tests, the ignitability test, burning tests, the pyrolytic severity test, and shock sensitivity tests. Recently, the Japanese Fire Services Law was amended, requiring hazardous materials to be evaluated and classified by appropriate tests. These test methods, described in chapter 4, are related to oxidising solids, combustible solids, spontaneous ignition substances, and water-reactive substances. The final chapter gives examples of the safety assessment of various pyrotechnics.There are few books available on this subject and none so comprehensive. Each of the methods described is practical, effective and of low cost; and many of the application results are from the author's own laboratory. The book will be invaluable to those in public and industrial safety laboratories, R & D chemical laboratories, Fire Departments, explosives manufacturers, and those responsible for the transportation of hazardous materials.
Bretherick's Handbook of Reactive Chemical Hazards, Fourth Edition, has been prepared and revised to give access to a wide and up-to-date selection of documented information to research students, practicing chemists, safety officers, and others concerned with the safe handling and use of reactive chemicals. This will allow ready assessment of the likely potential for reaction hazards which may be associated with an existing or proposed chemical compound or reaction system. A secondary, longer-term purpose is to present the information in a way which will, as far as possible, bring out the causes of, and interrelationships between, apparently disconnected facts and incidents. This handbook includes all information which had become available to the author by April 1989 on the reactivity hazards of individual elements or compounds, either alone or in combination. It begins with an introductory chapter that provides an overview of the complex subject of reactive chemical hazards, drawing attention to the underlying principles and to some practical aspects of minimizing such hazards. This is followed by two sections: Section 1 provides detailed information on the hazardous properties of individual chemicals, either alone or in combination with other compounds; the entries in Section 2 are of two distinct types. The first type of entry gives general information on the hazardous behavior of some recognizably discrete classes or groups of the 4,600 or so individual compounds for which details are given in Section 1. The second type of entry concerns reactive hazard topics, techniques, or incidents which have a common theme or pattern of behavior involving compounds of several different groups, so that no common structural feature exists for the compounds involved.
Summarizes core information for quick reference in the workplace, using tables and checklists wherever possible. Essential reading for safety officers, company managers, engineers, transport personnel, waste disposal personnel, environmental health officers, trainees on industrial training courses and engineering students. This book provides concise and clear explanation and look-up data on properties, exposure limits, flashpoints, monitoring techniques, personal protection and a host of other parameters and requirements relating to compliance with designated safe practice, control of hazards to people's health and limitation of impact on the environment. The book caters for the multitude of companies, officials and public and private employees who must comply with the regulations governing the use, storage, handling, transport and disposal of hazardous substances. Reference is made throughout to source documents and standards, and a Bibliography provides guidance to sources of wider ranging and more specialized information. Dr Phillip Carson is Safety Liaison and QA Manager at the Unilever Research Laboratory at Port Sunlight. He is a member of the Institution of Occupational Safety and Health, of the Institution of Chemical Engineers' Loss Prevention Panel and of the Chemical Industries Association's `Exposure Limits Task Force' and `Health Advisory Group'. Dr Clive Mumford is a Senior Lecturer in Chemical Engineering at the University of Aston and a consultant. He lectures on several courses of the Certificate and Diploma of the National Examining Board in Occupational Safety and Health. [Given 5 star rating] - Occupational Safety & Health, July 1994 - Loss Prevention Bulletin, April 1994 - Journal of Hazardous Materials, November 1994 - Process Safety & Environmental Prot., November 1994
Besides its obvious destructive potential, military R&D also serves to protect human lives, equipment and facilities against the effects of weapons. Concepts have therefore been developed that improve safety of stationary and mobile facilities against pressure waves, thermal radiation and fire. Effective, fast fire extinguishing equipment has been designed for tank compartments and motors. Closed buildings are demolished and landmines are removed with gas and dust explosions. Stringent safety requirements have been developed for the production of ammunition and explosives. Military and related industries have accumulated a vast knowledge and sophisticated experience that are very valuable in a variety of civil applications. The knowledge is based on theoretical and experimental research work, the origin of which sometimes dates back many centuries. It has often been classified and therefore has remained unknown to the civilian population, until now.
Significant loss to business occurs through fires in the workplace. Whether large or small, fire causes personal suffering, damage to plant, equipment and buildings, and loss of business. Fire legislation has changed over the past few years, especially with the introduction of European Directives. New regulations mean that employers have to carry out fire risk assessment and then, as a result of their findings, put in place control measures to prevent loss of life. Fire Hazards in Industry has been designed to cover, in general terms, exactly what is required of employers. It is written in simple language and considers the basics of good fire safety management. After reading Fire Hazards in Industry, any employer, safety professional or fire safety officer should be able to install a system for carrying out fire risk assessment. In addition to sections relating to the legal aspects of fire prevention, the book explains the concepts of fire modelling, explosions and combustion reactions. There is also a section relating to common industry fire hazards and hazards associated with electrical equipment. Knowledge of all these topics would be required if a person were to attempt to carry out fire risk assessment. Throughout the book, past case histories are used to illustrate certain aspects of fire and the causes of fire. The cases used have all been published by the Health and Safety Executive as a result of their investigations. These include; Abbeystead, Frodingham steelworks, HMS Glasgow, BP Grangemouth and many more.This book will be equally relevant to motor manufacturing as it is to the chemical industry. There are many case studies included that deal with fire hazards that are found in general industry.Fire Hazards in Industry is suitable for those who have relatively limited experience in fire safety and therefore use it as part of their career and educational development, but also can be used as reference material for those experienced professionals who have fire safety included in their day to day responsibility.
Does the identification number 60 indicate a toxic substance or a flammable solid, in the molten state at an elevated temperature? Does the identification number 1035 indicate ethane or butane? What is the difference between natural gas transmission pipelines and natural gas distribution pipelines? If you came upon an overturned truck on the highway that was leaking, would you be able to identify if it was hazardous and know what steps to take? Questions like these and more are answered in the Emergency Response Guidebook. Learn how to identify symbols for and vehicles carrying toxic, flammable, explosive, radioactive, or otherwise harmful substances and how to respond once an incident involving those substances has been identified. Always be prepared in situations that are unfamiliar and dangerous and know how to rectify them. Keeping this guide around at all times will ensure that, if you were to come upon a transportation situation involving hazardous substances or dangerous goods, you will be able to help keep others and yourself out of danger. With color-coded pages for quick and easy reference, this is the official manual used by first responders in the United States and Canada for transportation incidents involving dangerous goods or hazardous materials.
Unfortunately, dust explosions are common and costly in a wide array of industries such as petrochemical, food, paper and pharmaceutical. It is imperative that practical and theoretical knowledge of the origin, development, prevention and mitigation of dust explosions is imparted to the responsible safety manager. The material in this book offers an up to date evaluation of prevalent activities, testing methods, design measures and safe operating techniques. Also provided is a detailed and comprehensive critique of all the significant phases relating to the hazard and control of a dust explosion. An invaluable reference work for industry, safety consultants and students. - A completely new chapter on design of electrical equipment to be used in areas containing combustible/explosible dust - A substantially extended and re-organized final review chapter, containing nearly 400 new literature references from the years 1997-2002 - Extensive cross-referencing from the original chapters 1-7 to the corresponding sections of the expanded review chapter
