Exploration of the Kinetic Behavior of Redox Mediators, and the Development of a Recyclable Electrolyte with Applications to Synthesis
Exploration of the Kinetic Behavior of Redox Mediators, and the Development of a Recyclable Electrolyte with Applications to Synthesis

Author: Seung Joon Yoo

Publisher:

Published: 2014

Total Pages: 143

ISBN-13: 9781321568851

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As a promising class of organic electron transfer redox mediators, the recently developed triarylimidazoles (TAIs) have been used to achieve indirect electrochemical C-H bonds activation and functionalization. Herein the diffusion and electron transfer rates for the oxidation of 4-methoxybenzyl alcohol using TAI are reported and compared its electrochemical behavior with that of tris(4-bromophenyl)amine (TBPA), an organic electron transfer mediator that is frequently used for indirect oxidative electrolysis. The results contribute to the understanding of the electron transfer process of electrocatalytic oxidation using TAIs, and offer useful guidelines for their further development and use.

Encyclopedia of Electrochemical Power Sources
Encyclopedia of Electrochemical Power Sources

Author: Jürgen Garche

Publisher: Newnes

Published: 2013-05-20

Total Pages: 4532

ISBN-13: 0444527451

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The Encyclopedia of Electrochemical Power Sources is a truly interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With a focus on the environmental and economic impact of electrochemical power sources, this five-volume work consolidates coverage of the field and serves as an entry point to the literature for professionals and students alike. Covers the main types of power sources, including their operating principles, systems, materials, and applications Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers Incorporates nearly 350 articles, with timely coverage of such topics as environmental and sustainability considerations

Nanocatalysis
Nanocatalysis

Author: Vivek Polshettiwar

Publisher: John Wiley & Sons

Published: 2013-09-30

Total Pages: 755

ISBN-13: 111814886X

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Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations. Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors’ first-hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book’s nineteen chapters offer a broad perspective, covering: Nanocatalysis for carbon-carbon and carbon-heteroatom coupling reactions Nanocatalysis for various organic transformations in fine chemical synthesis Nanocatalysis for oxidation, hydrogenation, and other related reactions Nanomaterial-based photocatalysis and biocatalysis Nanocatalysts to produce non-conventional energy such as hydrogen and biofuels Nanocatalysts and nano-biocatalysts in the chemical industry Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance. Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing the information and guidance needed for designing green, sustainable catalytic processes.

Bioelectrochemical Systems
Bioelectrochemical Systems

Author: Korneel Rabaey

Publisher: IWA Publishing

Published: 2009-12-01

Total Pages: 525

ISBN-13: 184339233X

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In the context of wastewater treatment, Bioelectrochemical Systems (BESs) have gained considerable interest in the past few years, and several BES processes are on the brink of application to this area. This book, written by a large number of world experts in the different sub-topics, describes the different aspects and processes relevant to their development. Bioelectrochemical Systems (BESs) use micro-organisms to catalyze an oxidation and/or reduction reaction at an anodic and cathodic electrode respectively. Briefly, at an anode oxidation of organic and inorganic electron donors can occur. Prime examples of such electron donors are waste organics and sulfides. At the cathode, an electron acceptor such as oxygen or nitrate can be reduced. The anode and the cathode are connected through an electrical circuit. If electrical power is harvested from this circuit, the system is called a Microbial Fuel Cell; if electrical power is invested, the system is called a Microbial Electrolysis Cell. The overall framework of bio-energy and bio-fuels is discussed. A number of chapters discuss the basics – microbiology, microbial ecology, electrochemistry, technology and materials development. The book continues by highlighting the plurality of processes based on BES technology already in existence, going from wastewater based reactors to sediment based bio-batteries. The integration of BESs into existing water or process lines is discussed. Finally, an outlook is provided of how BES will fit within the emerging biorefinery area.

Electro-Fenton Process
Electro-Fenton Process

Author: Minghua Zhou

Publisher: Springer

Published: 2017-11-25

Total Pages: 437

ISBN-13: 9811064067

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This volume discusses the theoretical fundamentals and potential applications of the original electro-Fenton (EF) process and its most innovative and promising versions, all of which are classified as electrochemical advanced oxidation processes. It consists of 15 chapters that review the latest advances and trends, material selection, reaction and reactor modeling and EF scale-up. It particularly focuses on the applications of EF process in the treatment of toxic and persistent organic pollutants in water and soil, showing highly efficient removal for both lab-scale and pre-pilot setups. Indeed, the EF technology is now mature enough to be brought to market, and this collection of contributions from leading experts in the field constitutes a timely milestone for scientists and engineers.

Electrochemical Reactors: Fundamentals, electrolysers, batteries, and fuel cells
Electrochemical Reactors: Fundamentals, electrolysers, batteries, and fuel cells

Author: M. I. Ismail

Publisher: Elsevier Publishing Company

Published: 1989

Total Pages: 574

ISBN-13:

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This book provides a guide for professionals interested in energy transfer and electrochemical technology systems. It covers the state-of-the-art of materials, electrochemistry and electrochemical engineering as related to electrochemical reactors, batteries and fuel cells. The fifteen chapters, written by experts in fields related to every aspect affecting reactor performance, are grouped into three parts. The first is devoted to fundamentals of reactors, batteries and fuel cells and covers various aspects of design, parts, construction, materials operation and control systems. The second group is devoted to specific reactors such as aqueous electro-organic and inorganic synthesis, electrochemical polymerization, molten salt electrolysis, electrochemical machining, metal finishing, reactor performance, failure mechanisms, corrosion control, materials selection and techniques. The third group deals with manufacturing techniques and surface treatment of materials for commercial reactors, commercial parts/materials, fastening, assembly and production of reactor parts and mathematical modelling of various reactor processes.

Redox Flow Batteries
Redox Flow Batteries

Author: Huamin Zhang

Publisher: CRC Press

Published: 2017-11-22

Total Pages: 409

ISBN-13: 1351648721

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Flow batteries have received attention in large-scale energy storage due to their flexible design, high safety, high energy efficiency, and environmental friendliness. In recent years, they have been rapidly developed and tested in a variety of scales that prove their feasibility and advantages of use. As energy becomes a global focus, it is important to consider flow battery systems. This book offers a detailed introduction to the function of different kinds of redox flow batteries, including vanadium flow batteries, as well as the electrochemical processes for their development, materials and components, applications, and near future prospects. Redox Flow Batteries: Fundamentals and Applications will give readers a full understanding of flow batteries from fundamentals to commercial applications.

Chemical Oxidation Applications for Industrial Wastewaters
Chemical Oxidation Applications for Industrial Wastewaters

Author: Olcay Tunay

Publisher: IWA Publishing

Published: 2010-10-12

Total Pages: 361

ISBN-13: 1843393077

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This book covers the most recent scientific and technological developments (state-of-the-art) in the field of chemical oxidation processes applicable for the efficient treatment of biologically-difficult-to-degrade, toxic and/or recalcitrant effluents originating from different manufacturing processes. It is a comprehensive review of process and pollution profiles as well as conventional, advanced and emerging treatment processes & technologies developed for the most relevant and pollution (wet processing)-intensive industrial sectors. It addresses chemical/photochemical oxidative treatment processes, case-specific treatability problems of major industrial sectors, emerging (novel) as well as pilot/full-scale applications, process integration, treatment system design & sizing criteria (figure-of-merits), cost evaluation and success stories in the application of chemical oxidative treatment processes. Chemical Oxidation Applications for Industrial Wastewaters is an essential reference for lecturers, researchers, industrial and environmental engineers and practitioners working in the field of environmental science and engineering. Visit the IWA WaterWiki to read and share material related to this title: http://www.iwawaterwiki.org/xwiki/bin/view/Articles/CHEMICALOXIDATIONAPPLICATIONSFORINDUSTRIALWASTEWATERS Authors: Professor Olcay Tünay, Professor Isik Kabdasli, Associate Professor Idil Arslan-Alaton and Assistant Professor Tugba Ölmez-Hanci, Environmental Engineering Department, Istanbul Technical University, Turkey.

Lignin Valorization
Lignin Valorization

Author: Gregg T. Beckham

Publisher: Royal Society of Chemistry

Published: 2018-03-29

Total Pages: 544

ISBN-13: 1782625542

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"Chapters will specifically focus on the production of fuels and chemicals from lignin."--Page [4] of cover.

Mineral Surfaces
Mineral Surfaces

Author: D. Vaughan

Publisher: Springer

Published: 1995

Total Pages: 388

ISBN-13:

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30% discount for members of The Mineralogical Society of Britain and Ireland This text summarises the state-of-the-art in the study of mineral surfaces and some of the key applications of surface science in mineralogy and mineral chemistry. Each chapter covers a particular aspect of the subject and is written by an expert who raises the key issues involved for those requiring an introduction to the subject, whilst highlighting most recent developments. Advanced undergraduates, postgraduates and researchers alike will find this essential reading as it is the first book to review the fast developing field of mineral surfaces.