Equations of State for Fluids and Fluid Mixtures
Equations of State for Fluids and Fluid Mixtures

Author: J.V. Sengers

Publisher: Elsevier

Published: 2000-10-30

Total Pages: 455

ISBN-13: 0080531180

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This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.

Equations of State for Fluids and Fluid Mixtures
Equations of State for Fluids and Fluid Mixtures

Author: J. V. Sengers

Publisher:

Published: 2000

Total Pages: 885

ISBN-13: 0444503846

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This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.

Hydrodynamic Fluctuations in Fluids and Fluid Mixtures
Hydrodynamic Fluctuations in Fluids and Fluid Mixtures

Author: Jose M. Ortiz de Zarate

Publisher: Elsevier

Published: 2006-04-19

Total Pages: 321

ISBN-13: 0080459439

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This book deals with density, temperature, velocity and concentration fluctuations in fluids and fluid mixtures. The book first reviews thermal fluctuations in equilibrium fluids on the basis of fluctuating hydrodynamics. It then shows how the method of fluctuating hydrodynamics can be extended to deal with hydrodynamic fluctuations when the system is in a stationary nonequilibrium state. In contrast to equilibrium fluids where the fluctuations are generally short ranged unless the system is close to a critical point, fluctuations in nonequilibrium fluids are always long-ranged encompassing the entire system. The book provides the first comprehensive treatment of fluctuations in fluids and fluid mixtures brought out of equilibrium by the imposition of a temperature and concentration gradient but that are still in a macroscopically quiescent state. By incorporating appropriate boundary conditions in the case of fluid layers, it is shown how fluctuating hydrodynamics affects the fluctuations close to the onset of convection. Experimental techniques of light scattering and shadowgraphy for measuring nonequilibrium fluctuations are elucidated and the experimental results thus far reported in the literature are reviewed.· Systematic exposition of fluctuating hydrodynamics and its applications· First book on nonequilibrium fluctuations in fluids· Fluctuating Boussinesq equations and nonequilibrium fluids· Fluid layers and onset of convection· Rayleigh scattering and Brillouin scattering in fluids· Shadowgraph technique for measuring fluctuations· Fluctuations near hydrodynamic instabilities

Applied Thermodynamics of Fluids
Applied Thermodynamics of Fluids

Author: A. R. H. Goodwin

Publisher: Royal Society of Chemistry

Published: 2010

Total Pages: 535

ISBN-13: 1847558062

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Published under the asspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the need of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydroncarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commericial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.

Modeling Vapor-Liquid Equilibria
Modeling Vapor-Liquid Equilibria

Author: Hasan Orbey

Publisher: Cambridge University Press

Published: 1998-05-28

Total Pages: 230

ISBN-13: 9780521620277

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Reviews the latest developments in a subject relevant to professionals involved in the simulation and design of chemical processes - includes disk of computer programs.

Multiphase Equilibria of Complex Reservoir Fluids
Multiphase Equilibria of Complex Reservoir Fluids

Author: Huazhou Li

Publisher: Springer Nature

Published: 2021-10-30

Total Pages: 220

ISBN-13: 3030874400

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This short monograph focuses on the theoretical backgrounds and practical implementations concerning the thermodynamic modeling of multiphase equilibria of complex reservoir fluids using cubic equations of state. It aims to address the increasing needs of multiphase equilibrium calculations that arise in the compositional modeling of multiphase flow in reservoirs and wellbores. It provides a state-of-the-art coverage on the recent improvements of cubic equations of state. Considering that stability test and flash calculation are two basic tasks involved in any multiphase equilibrium calculations, it elaborates on the rigorous mathematical frameworks dedicated to stability test and flash calculation. A special treatment is given to the new algorithms that are recently developed to perform robust and efficient three-phase equilibrium calculations. This monograph will be of value to graduate students who conduct research in the field of phase behavior, as well as software engineers who work on the development of multiphase equilibrium calculation algorithms.

Multiparameter Equations of State
Multiparameter Equations of State

Author: Roland Span

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 384

ISBN-13: 3662040921

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As a basis for printed property charts and tables, empirical multiparameter equa tions of state have been the most important source of accurate thermodynamic property data for more than 30 years now. However, due to increasing demands on the accuracy of thermodynamic property data in computerised calculations as well as the availability of appropriate software tools, and the ever increasing computer power, such formulations are nowadays becoming a valuable tool for everyday work. This development has substantially increased the number of scientists, engi neers, and students who are working with empirical multiparameter equations of state, and it continues to do so. Nevertheless, common knowledge on this kind of thermodynamic property models and on the ongoing progress in this scientific discipline is still very limited. Multiparameter equations of state do not belong to the topics which are taught intensively in thermodynamic courses in engineering and natural sciences and the books and articles where they are published mainly deal with the thermodynamic properties of certain substances rather than with the theoretical background of the used equations of state. In contrast to this, my concern mainly was to give a survey of the theoretical background of multiparameter equations of state both with regard to their application and their development.

Supercritical Fluids
Supercritical Fluids

Author: E. Kiran

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 775

ISBN-13: 9401582955

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Supercritical fluids which are neither gas nor liquid, but can be compressed gradually from low to high density, are gaining increasing importance as tunable solvents and reaction media in the chemical process industry. By adjusting the pressure, or more strictly the density, the properties of these fluids are customized and manipulated for the particular process at hand, be it a physical transformation, such as separation or solvation, or a chemical transformation, such as a reaction or reactive extraction. Supercritical fluids, however, differ from both gases and liquids in many respects. In order to properly understand and describe their properties, it is necessary to know the implications of their nearness to criticality, to be aware of the complex types of phase separation (including solid phases) that occur when the components of the fluid mixture are very different from each other, and to develop theories that can cope with the large differences in molecular size and shape of the supercritical solvent and the solutes that are present.

High-Pressure Fluid Phase Equilibria
High-Pressure Fluid Phase Equilibria

Author: Ulrich K Deiters

Publisher: Elsevier

Published: 2012-04-26

Total Pages: 363

ISBN-13: 0444563547

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The book begins with an overview of the phase diagrams of fluid mixtures (fluid = liquid, gas, or supercritical state), which can show an astonishing variety when elevated pressures are taken into account; phenomena like retrograde condensation (single and double) and azeotropy (normal and double) are discussed. It then gives an introduction into the relevant thermodynamic equations for fluid mixtures, including some that are rarely found in modern textbooks, and shows how they can they be used to compute phase diagrams and related properties. This chapter gives a consistent and axiomatic approach to fluid thermodynamics; it avoids using activity coefficients. Further chapters are dedicated to solid-fluid phase equilibria and global phase diagrams (systematic search for phase diagram classes). The appendix contains numerical algorithms needed for the computations. The book thus enables the reader to create or improve computer programs for the calculation of fluid phase diagrams. - introduces phase diagram classes, how to recognize them and identify their characteristic features - presents rational nomenclature of binary fluid phase diagrams - includes problems and solutions for self-testing, exercises or seminars