Flexible Polymer Chains in Elongational Flow
Flexible Polymer Chains in Elongational Flow

Author: Tuan Q. Nguyen

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 413

ISBN-13: 3642582524

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The behavior of polymer solutions in simple shear flows has been the subject of considerable research in the past. On the other hand, reports on polymers in elongational flow have appeared comparatively recently in the literature. Elongational flow with an inherent low vorticity is known to be more effective in extending polymer chains than simple shear flow and thus is more interesting from the point of view of basic (molecular chain dynamics at high deformation) and applied polymer science (rheology, fiber extrusion, drag reduction, flow through porous media). Undoubtly, one landmark in the field of polymer dynamics in elongational flow was the notion of critical strain-rate for chain extension, initially put forward by A. Peterlin (1966) and later refined into the "coil-stretching" transition by P. G. de Gennes and H. Hinch (1974). In the two decades which followed, significant progress in the understanding of chain conformation in "strong" flow has been accomplished through a combination of advances in instrumentation, computation techniques and theoretical studies. As a result of the multidisciplinary nature of the field, information on polymer chains in "strong" flow is accessible only from reviews and research papers scattered in disparate scientific journals. An important objective of this book is to remedy that situation by providing the reader with up-to-date knowledge in a single volume. The editors therefore invited leading specialists to provide both fundamental and applied information on the multiple facets of chain deformation in elongational flow.

Mathematical Analysis of Viscoelastic Flows
Mathematical Analysis of Viscoelastic Flows

Author: Michael Renardy

Publisher: SIAM

Published: 2000-01-01

Total Pages: 110

ISBN-13: 0898714575

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This monograph is based on a series of lectures presented at the 1999 NSF-CBMS Regional Research Conference on Mathematical Analysis of Viscoelastic Flows. It begins with an introduction to phenomena observed in viscoelastic flows, the formulation of mathematical equations to model such flows, and the behavior of various models in simple flows. It also discusses the asymptotics of the high Weissenberg limit, the analysis of flow instabilities, the equations of viscoelastic flows, jets and filaments and their breakup, as well as several other topics.

Engineering Rheology
Engineering Rheology

Author: Roger I. Tanner

Publisher: OUP Oxford

Published: 2000-03-02

Total Pages: 590

ISBN-13: 0191590169

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This book sets out to provide a guide, with examples, for those who wish to make predictions about the mechanical and thermal behaviour of non-Newtonian materials in engineering and processing technology. After an introductory survey of the field and a review of basic continuum mechanics, the radical differences between elongational and shear behaviour are shown. Two chapters, one based on a continuum approach and the other using microstructural approaches, lead to useful mathematical desriptions of materials for engineering applications. As examples of nearly-viscometric and nearly-elongational flows, there is a discussion of lubrication and related shearing flows, and fibre- spinning and film-blowing respectively. A long chapter is devoted to the important new field of computational rheology, and this is followed by chapters on stability and turbulence and the all-important temperature effects in flow. This new edition contains much new material not available in book form elsewhere-for example wall slip, suspension rheology, computational rheology and new results in stability theory.

Advances in Physical Organic Chemistry
Advances in Physical Organic Chemistry

Author: Ian Williams

Publisher: Academic Press

Published: 2018-11-15

Total Pages: 156

ISBN-13: 0128155396

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Advances in Physical Organic Chemistry, Volume 52 in the series, is the definitive resource for authoritative reviews of work in physical organic chemistry. It aims to provide a valuable source of information that is ideal not only for physical organic chemists applying their expertise to both novel and traditional problems, but also for non-specialists across diverse areas who identify a physical organic component in their approach to research. Its hallmark is a quantitative, molecular level understanding of phenomena across a diverse range of disciplines. - Reviews the application of quantitative and mathematical methods to help readers understand chemical problems - Provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry - Covers organic, organometallic, bioorganic, enzymes and materials topics - Presents the only regularly published resource for reviews in physical organic chemistry - Written by authoritative experts who cover a wide range of topics that require a quantitative, molecular-level understanding of phenomena across a diverse range of disciplines

Applied Polymer Rheology
Applied Polymer Rheology

Author: Marianna Kontopoulou

Publisher: John Wiley & Sons

Published: 2011-11-22

Total Pages: 370

ISBN-13: 047041670X

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Explore polymer rheology from an industrial standpoint Presenting state-of-the-art polymer rheology as observed by well-recognized authors, Applied Polymer Rheology: Polymeric Fluids with Industrial Applications is designed to help readers understand the relationship between molecular structure and the flow behavior of polymers. In particular, it focuses on polymeric systems that elicit special attention from industry. Providing a comprehensive overview of the rheological characteristics of polymeric fluids, the book bridges the gap between theory and practice/application, enabling readers to see the connection between molecular structure and the behavior of the polymers studied. Beginning with a discussion of the properties, processability, and processing aids of specific polymers, later chapters examine filled polymers and composites, and the theoretical framework upon which their analysis is based. Various systems containing microstructure are presented subsequently, with the final chapter introducing paste extrusion of polytetrafluoroethylene paste. An invaluable reference guide that covers the literature and vast array of technical approaches to polymer rheology, Applied Polymer Rheology's coverage of polymeric fluids of interest to industry make it an essential resource for plastics, polymer, and chemical engineers, materials scientists, polymer chemists, and polymer physicists to use when interpreting findings and planning experiments.