Earth History of Oxygen and the iprOxy
Earth History of Oxygen and the iprOxy

Author: Zunli Lu

Publisher: Cambridge University Press

Published: 2020-10-08

Total Pages: 49

ISBN-13: 1009028413

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How oxygen levels in Earth's atmosphere and oceans evolved has always been a central question in Earth System Science. Researchers have developed numerous tracers to tackle this question, utilizing geochemical characteristics of different elements. Iodine incorporated in calcium carbonate (including biogenic) minerals, reported as I/Ca, is a proxy for dissolved oxygen in seawater. Here we review the rationale behind this proxy, its recent applications and some potential future research directions.

Reconstructing Precambrian pCO2 and pO2 Using Paleosols
Reconstructing Precambrian pCO2 and pO2 Using Paleosols

Author: Nathan D. Sheldon

Publisher: Cambridge University Press

Published: 2021-03-04

Total Pages: 38

ISBN-13: 1108876811

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Paleosols formed in direct contact with the Earth's atmosphere, so they can record the composition of the atmosphere through weathering processes and products. Herein we critically review a variety of different approaches for reconstructing atmospheric O2 and CO2 over the past three billion years. Paleosols indicate relatively low CO2 over that time, requiring additional greenhouse forcing to overcome the 'faint young Sun' paradox in the Archean and Mesoproterozoic, as well as low O2 levels until the Neoproterozoic. Emerging techniques will revise the history of Earth's atmosphere further and may provide a window into atmospheric evolution on other planets.

Vanadium Isotopes
Vanadium Isotopes

Author: Sune G. Nielsen

Publisher: Cambridge University Press

Published: 2021-01-28

Total Pages: 39

ISBN-13: 110885270X

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Vanadium isotope ratios (51V/50V) have potential to provide information about changes in past ocean oxygen contents. In particular, V isotopes may find utility in tracing variations at non-zero oxygen concentrations because the redox couple that controls V elemental and isotopic abundances in seawater (vanadate-vanadyl) appears to operate around 10M O2. This characteristic sets V isotopes apart from many other metal isotope redox proxies that require more reducing conditions to register significant changes in their isotope budgets. The oxygen abundance sensitivity range of V isotopes suggests that this paleoproxy could be particularly useful in tracing marine oxygenation changes throughout the Phanerozoic and potentially beyond.

Cerium Anomalies and Paleoredox
Cerium Anomalies and Paleoredox

Author: Rosalie Tostevin

Publisher: Cambridge University Press

Published: 2021-02-25

Total Pages: 46

ISBN-13: 1108847579

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Ce anomalies track changes in oxygen availability due to the anomalous redox-sensitivity of Ce compared with the other rare earth elements. The proxy systematics have been calibrated experimentally as well as in modern anoxic water bodies. Ce anomalies are unique because they track intermediate manganous conditions, rather than fully anoxic conditions. In addition, they are sensitive to local–regional redox conditions, and can be analysed in chemical sediments such as carbonate rocks. This makes them especially useful as a tool to track local oxygen distribution in shallow shelf environments, where biodiversity is highest. This review focusses on the systematics of the Ce anomaly proxy, the preservation and extraction of the signal in sedimentary rocks, and the potential applications of the proxy.

The Marine Iodine Cycle, Past, Present and Future
The Marine Iodine Cycle, Past, Present and Future

Author: Rosie Chance

Publisher: Frontiers Media SA

Published: 2024-05-17

Total Pages: 153

ISBN-13: 2832549160

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The marine iodine cycle has remained enigmatic despite decades of research. As a redox active element that is accumulated by many marine organisms, it exists in multiple oxidation states and phases in the oceans. Abiotic, photochemical and biological processes occurring at the ocean surface, at depth, and at the sediment-water interface all drive transformations between iodine species. A recent resurgence in interest in marine iodine speciation has been driven by its importance in a diverse range of fields, from atmospheric chemistry to paleoceanography.

Pelagic Barite
Pelagic Barite

Author: Weiqi Yao

Publisher: Cambridge University Press

Published: 2021-01-28

Total Pages: 46

ISBN-13: 1108847552

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Reconstruction of ocean paleoproductivity and paleochemistry is paramount to understanding global biogeochemical cycles such as the carbon, oxygen and sulfur cycles and the responses of these cycles to changes in climate and tectonics. Paleo-reconstruction involves the application of various tracers that record seawater compositions, which in turn may be used to infer oceanic processes. Several important tracers are incorporated into pelagic barite, an authigenic mineral that forms in the water column. Here we summarize the utility of pelagic barite for the reconstruction of export production and as a recorder of seawater S, O, Sr, Ca and Ba.

Calcium Isotopes
Calcium Isotopes

Author: Elizabeth M. Griffith

Publisher: Cambridge University Press

Published: 2021-01-21

Total Pages: 56

ISBN-13: 1108847595

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Precise measurements of the calcium (Ca) isotopes have provided constraints on Ca cycling at global and local scales, and quantified rates of carbonate diagenesis in marine sedimentary systems. Key to applying Ca isotopes as a geochemical tracer of Ca cycling, carbonate (bio)mineralization, and diagenesis is an understanding of the impact of multiple factors potentially impacting Ca isotopes in the rock record. These factors include variations in stable isotopic fractionation factors, the influence of local-scale Ca cycling on Ca isotopic gradients in carbonate settings, carbonate dissolution and reprecipitation, and the relationship between the Ca isotopic composition of seawater and mineral phases that record the secular evolution of seawater chemistry.

A Global Synthesis of the Ordovician System: Part 1
A Global Synthesis of the Ordovician System: Part 1

Author: D.A.T. Harper

Publisher: Geological Society of London Special Publications

Published: 2023-06-07

Total Pages: 514

ISBN-13: 1786205882

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The Ordovician was one of the longest of the geological periods, characterized by major magmatic and tectonic activity, an immense biodiversification, swings in climate and sea levels and the first Phanerozoic mass extinction. ‘A Global Synthesis of the Ordovician System’ is presented in two volumes in The Geological Society, Special Publications. This first volume (SP532) charts the history of the Ordovician System and explores significant advances in our understanding of its biostratigraphy, including more precise calibration of its timescale with tephra chronology and regional alignments using astrochronology and cyclostratigraphy. Changes in the world’s oceans, their shifting currents and sea levels, the biogeography of their biotas and the ambient climate are described and discussed against a background of changing palaeogeography. This first volume also includes syntheses of the Ordovician geology for most European countries, including historical key areas, such as Great Britain, Baltoscandia and Bohemia. The second volume (SP533) provides synthetic aspects of the Ordovician geology of most other parts of the world.

Principles of Planetary Climate
Principles of Planetary Climate

Author: Raymond T. Pierrehumbert

Publisher: Cambridge University Press

Published: 2010-12-02

Total Pages: 679

ISBN-13: 1139495062

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This book introduces the reader to all the basic physical building blocks of climate needed to understand the present and past climate of Earth, the climates of Solar System planets, and the climates of extrasolar planets. These building blocks include thermodynamics, infrared radiative transfer, scattering, surface heat transfer and various processes governing the evolution of atmospheric composition. Nearly four hundred problems are supplied to help consolidate the reader's understanding, and to lead the reader towards original research on planetary climate. This textbook is invaluable for advanced undergraduate or beginning graduate students in atmospheric science, Earth and planetary science, astrobiology, and physics. It also provides a superb reference text for researchers in these subjects, and is very suitable for academic researchers trained in physics or chemistry who wish to rapidly gain enough background to participate in the excitement of the new research opportunities opening in planetary climate.

Surface Temperature Reconstructions for the Last 2,000 Years
Surface Temperature Reconstructions for the Last 2,000 Years

Author: National Research Council

Publisher: National Academies Press

Published: 2007-01-05

Total Pages: 160

ISBN-13: 0309102251

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In response to a request from Congress, Surface Temperature Reconstructions for the Last 2,000 Years assesses the state of scientific efforts to reconstruct surface temperature records for Earth during approximately the last 2,000 years and the implications of these efforts for our understanding of global climate change. Because widespread, reliable temperature records are available only for the last 150 years, scientists estimate temperatures in the more distant past by analyzing "proxy evidence," which includes tree rings, corals, ocean and lake sediments, cave deposits, ice cores, boreholes, and glaciers. Starting in the late 1990s, scientists began using sophisticated methods to combine proxy evidence from many different locations in an effort to estimate surface temperature changes during the last few hundred to few thousand years. This book is an important resource in helping to understand the intricacies of global climate change.