Diffusion and Heat Exchange in Chemical Kinetics
Diffusion and Heat Exchange in Chemical Kinetics

Author: David Albertovich Frank-Kamenetskii

Publisher: Princeton University Press

Published: 2015-12-08

Total Pages: 383

ISBN-13: 1400877199

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Frank-Kamenetskii, a leader in Russian science, was the first to define conditions for two stable operating regimes in chemical reactions, one controlled by chemical reactions, the other by diffusion processes. In this book he treats mathematically the subjects of reaction ignition, quenching, and periodic processes in chemical kinetics as found in flames, combustion of solids, and other chemical reactions. The book was translated from the Russian by the late N. Thou and edited by R. Wilhelm. Originally published in 1955. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.

Chemical Kinetics and Transport
Chemical Kinetics and Transport

Author: Peter Jordan

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 375

ISBN-13: 1461590981

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This book began as a program of self-education. While teaching under graduate physical chemistry, I became progressively more dissatisfied with my approach to chemical kinetics. The solution to my problem was to write a detailed set of lecture notes which covered more material, in greater depth, than could be presented in undergraduate physical chemistry. These notes are the foundation upon which this book is built. My background led me to view chemical kinetics as closely related to transport phenomena. While the relationship of these topics is well known, it is often ignored, except for brief discussions of irreversible thermody namics. In fact, the physics underlying such apparently dissimilar processes as reaction and energy transfer is not so very different. The intermolecular potential is to transport what the potential-energy surface is to reactivity. Instead of beginning the sections devoted to chemical kinetics with a discussion of various theories, I have chosen to treat phenomenology and mechanism first. In this way the essential unity of kinetic arguments, whether applied to gas-phase or solution-phase reaction, can be emphasized. Theories of rate constants and of chemical dynamics are treated last, so that their strengths and weaknesses may be more clearly highlighted. The book is designed for students in their senior year or first year of graduate school. A year of undergraduate physical chemistry is essential preparation. While further exposure to chemical thermodynamics, statistical thermodynamics, or molecular spectroscopy is an asset, it is not necessary.

Modeling of Chemical Kinetics and Reactor Design
Modeling of Chemical Kinetics and Reactor Design

Author: A. Kayode Coker

Publisher: Gulf Professional Publishing

Published: 2001-07-26

Total Pages: 1132

ISBN-13: 9780884154815

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This reference conveys a basic understanding of chemical reactor design methodologies that incorporate both control and hazard analysis. It demonstrates how to select the best reactor for any particular chemical reaction, and how to estimate its size to determine the best operating conditions.

Transport Phenomena for Chemical Reactor Design
Transport Phenomena for Chemical Reactor Design

Author: Laurence A. Belfiore

Publisher: John Wiley & Sons

Published: 2003-04-11

Total Pages: 912

ISBN-13: 0471202754

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Laurence Belfiore’s unique treatment meshes two mainstream subject areas in chemical engineering: transport phenomena and chemical reactor design. Expressly intended as an extension of Bird, Stewart, and Lightfoot’s classic Transport Phenomena, and Froment and Bischoff’s Chemical Reactor Analysis and Design, Second Edition, Belfiore’s unprecedented text explores the synthesis of these two disciplines in a manner the upper undergraduate or graduate reader can readily grasp. Transport Phenomena for Chemical Reactor Design approaches the design of chemical reactors from microscopic heat and mass transfer principles. It includes simultaneous consideration of kinetics and heat transfer, both critical to the performance of real chemical reactors. Complementary topics in transport phenomena and thermodynamics that provide support for chemical reactor analysis are covered, including: Fluid dynamics in the creeping and potential flow regimes around solid spheres and gas bubbles The corresponding mass transfer problems that employ velocity profiles, derived in the book’s fluid dynamics chapter, to calculate interphase heat and mass transfer coefficients Heat capacities of ideal gases via statistical thermodynamics to calculate Prandtl numbers Thermodynamic stability criteria for homogeneous mixtures that reveal that binary molecular diffusion coefficients must be positive In addition to its comprehensive treatment, the text also contains 484 problems and ninety-six detailed solutions to assist in the exploration of the subject. Graduate and advanced undergraduate chemical engineering students, professors, and researchers will appreciate the vision, innovation, and practical application of Laurence Belfiore’s Transport Phenomena for Chemical Reactor Design.

Analytic Combustion
Analytic Combustion

Author: Anil W. Date

Publisher: Cambridge University Press

Published: 2014-06-26

Total Pages: 366

ISBN-13: 9781107448698

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Combustion involves change in the chemical state of a substance from a fuel-state to a product-state via chemical reaction accompanied by release of heat energy. Design or performance evaluation of equipment also requires knowledge of the RATE of change of state. This rate is governed by the laws of thermodynamics and by the empirical sciences of heat and mass transfer, chemical kinetics and fluid dynamics. Theoretical treatment of combustion requires integrated knowledge of these subjects and strong mathematical and numerical skills. ANALYTIC COMBUSTION is written for advanced undergraduates, graduate students and professionals in mechanical, aeronautical, and chemical engineering. Topics were carefully selected and presented to facilitate learning with emphasis on effective mathematical formulations and solution strategies. The book features over 60 solved numerical problems and analytical derivations and nearly 145 end-of-chapter exercise problems. The presentation is gradual starting from Thermodynamics of Pure and Mixture substances, Chemical Equilibrium, building to a uniquely strong chapter on Application Case-Studies.

Fluid-Solid Reactions
Fluid-Solid Reactions

Author: H. Y. Sohn

Publisher: Elsevier

Published: 2020-08-12

Total Pages: 538

ISBN-13: 0128164662

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Fluid-Solid Reactions, Second Edition takes a detailed and thorough look at the scope of fluid-solid reaction systems, focusing on the four phenomena: external mass transfer, pore diffusion, chemical reaction, and adsorption/desorption. This completely revised new edition builds on the classic original edition through the introduction of cutting-edge new theories and applications, including the formulation and application of a new and convenient law that governs fluid-solid reaction kinetics. This book will be of primary interest to practicing engineers engaged in process research, development, and design in the many fields where fluid-solid reactions are critical to workflow and research. Fluid-solid reactions play a major role in the technology of most industrialized nations. These reactions encompass a very broad field, including the extraction of metals from their ores, the combustion of solid fuels, coal gasification, and the incineration of solid refuse. Features 50% new and revised content, arming researchers with the latest developments in the field Details a new unified approach to modeling the rates of fluid-solid reaction systems Authored by one of the world’s foremost experts on fluid-solid reactions and their applications in the field

Kinetics of Soil Chemical Processes
Kinetics of Soil Chemical Processes

Author: Donald L. Sparks

Publisher: Academic Press

Published: 2013-10-22

Total Pages: 227

ISBN-13: 1483289192

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The kinetics of reactions in soil and aquatic environments is a topic of extreme importance and interest. To properly understand the fate of applied fertilizers, pesticides, and organic pollutants with time, and to thus improve nutrient availability and the quality of our groundwater, one must study kinetics. This is the first compre - Demonstrates different kinetic methodologies - Shows how reactions on soil and soil constituents can be measured by utilizing different techniques - Describes rates and mechanisms of interactions with pesticides and organic pollutants with soil - Covers the kinetics of chemical weathering - Discusses how to use mathematical modeling and computer simulation to model kinetic reactions