Determination Of Organic Structures By Physical Methods V6
Determination Of Organic Structures By Physical Methods V6

Author: F.C. Nachod

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 468

ISBN-13: 0323149200

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Determination of Organic Structures by Physical Methods, Volume 6 is a six-chapter text that describes the refinements of some established physical methods for organic structure determination. The opening chapters examine the application of mass spectroscopy to amino acid sequencing of oligopeptides and the computerized organic structure retrieval. The following chapters discuss the historical developments, principles, instrumentation, and application of flash photolysis and 29Si nuclear magnetic resonance to structure determination. A chapter considers the relevant theory from which information on internuclear distances can be obtained and the steady-state measurements, transient methods, as well as the use of Fourier transform technique. This chapter also explores the application of nuclear overhauser effect measurements to structural and stereochemical problems. The concluding chapter deals with the liquid crystal structure determination using NMR spectroscopy. This work will be of value to organic and analytical chemists and researchers.

Physical Methods in Heterocyclic Chemistry V6
Physical Methods in Heterocyclic Chemistry V6

Author: A Katritzky

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 318

ISBN-13: 0323156142

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Physical Methods in Heterocyclic Chemistry, Volume VI discusses several topics including bond energies, electron-spin resonance, microwave spectroscopy, and photoelectron spectroscopy. This book explores the thermochemical applications to heterocyclic chemistry. Comprised of five chapters, this volume starts with an overview of the technique of photoelectron spectroscopy. This text then illustrates the various potentialities of photoelectron spectroscopy by discussing four examples taken from the field of heterocyclic compounds. Other chapters determine the magnitudes as well as the lines of action of electric dipole moments in the molecular framework. This book discusses as well the emission of light by individual molecules in solution, particularly heterocyclic molecules, which are electronically excited as a result of the absorption of visible or ultraviolet light. The final chapter deals with the aspects of heats of combustion, heats of hydrogenation, heats of formation, and bond energies. Heterocyclic chemists, chemists, biochemists, molecular biologists, and researchers will find this book extremely useful.

Determination of Organic Structures by Physical Methods
Determination of Organic Structures by Physical Methods

Author: E. A. Braude

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 825

ISBN-13: 1483275728

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Determination of Organic Structures by Physical Methods, Volume 1 focuses on the processes, methodologies, principles, and approaches involved in the determination of organic structures by physical methods, including infrared light absorption, thermodynamic properties, Raman spectra, and kinetics. The selection first elaborates on the phase properties of small molecules, equilibrium and dynamic properties of large molecules, and optical rotation. Discussions focus on simple acyclic compounds, carbohydrates, steroids, diffusion, viscosity, osmotic pressure, sedimentation velocity, melting and boiling points, and molar volume. The book then examines ultraviolet and visible light absorption, infrared light absorption, Raman spectra, and the theory of magnetic susceptibility. Concerns cover applications to the study of organic compounds, applications to the determination of structure, determination of thermodynamic properties, and experimental methods and evaluation of data. The text ponders on wave-mechanical theory, reaction kinetics, and dissociation constants, including dissociation of molecular addition compounds, principles of reaction kinetics, and valence-bond treatment of aromatic systems. The selection is a valuable source of data for researchers interested in the determination of organic structures by physical methods.

Physical Acoustics V6
Physical Acoustics V6

Author: Warren P. Mason

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 409

ISBN-13: 0323151671

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Physical Acoustics: Principles and Methods, Volume VI provides five chapters covering the whole of physical acoustics. The first chapter extends the methods for studying high frequency sound waves in the hypersonic range by the technique of Brillouin scattering. The next chapter discusses the acoustic properties of materials of the perovskite structure. These materials have ""soft"" modes, which are transverse optic modes of the phonon spectrum that have unusually low and strongly temperature dependent frequencies. This chapter expounds the influence of the soft modes, with particular attention to potassium tantalate and strontium titanate. The third chapter gives a theoretical treatment of the properties and possibilities of surface waves in crystals that are becoming of increasing interest for delay lines, amplifiers of sound waves, and other practical applications. The fourth chapter discusses the experimental methods and results of the dynamic shear properties of solvents and polystyrene solutions from 20 to 300 MHz, including a description of its materials and steady-flow properties. The final chapter deals with condensed helium, which requires quantum reactions to account for its properties. While the experimental data on solid helium are still insufficient, this chapter gives both a theoretical and an experimental account of sound propagation in solid helium, including various liquid forms. This book is recommended to both students and physicists conducting research on physical acoustics.

Progress in Physical Organic Chemistry
Progress in Physical Organic Chemistry

Author: Andrew Streitwieser

Publisher: John Wiley & Sons

Published: 2009-09-17

Total Pages: 466

ISBN-13: 0470172061

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Progress in Physical Organic Chemistry is dedicated to reviewing the latest investigations into organic chemistry that use quantitative and mathematical methods. These reviews help readers understand the importance of individual discoveries and what they mean to the field as a whole. Moreover, the authors, leading experts in their fields, offer unique and thought-provoking perspectives on the current state of the science and its future directions. With so many new findings published in a broad range of journals, Progress in Physical Organic Chemistry fills the need for a central resource that presents, analyzes, and contextualizes the major advances in the field. The articles published in Progress in Physical Organic Chemistry are not only of interest to scientists working in physical organic chemistry, but also scientists working in the many subdisciplines of chemistry in which physical organic chemistry approaches are now applied, such as biochemistry, pharmaceutical chemistry, and materials and polymer science. Among the topics explored in this series are reaction mechanisms; reactive intermediates; combinatorial strategies; novel structures; spectroscopy; chemistry at interfaces; stereochemistry; conformational analysis; quantum chemical studies; structure-reactivity relationships; solvent, isotope and solid-state effects; long-lived charged, sextet or open-shell species; magnetic, non-linear optical and conducting molecules; and molecular recognition.