Operating Experience During High-level Waste Vitrification at the West Valley Demonstration Project

Operating Experience During High-level Waste Vitrification at the West Valley Demonstration Project

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Published: 1999

Total Pages: 39

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This report provides a summary of operational experiences, component and system performance, and lessons learned associated with the operation of the Vitrification Facility (VF) at the West Valley Demonstration Project (WVDP). The VF was designed to convert stored high-level radioactive waste (HLW) into a stable waste form (borosilicate glass) suitable for disposal in a federal repository. Following successful completion on nonradioactive test, HLW processing began in July 1995. Completion of Phase 1 of HLW processing was reached on 10 June 1998 and represented the processing of 9.32 million curies of cesium-137 (Cs-137) and strontium-90 (Sr-90) to fill 211 canisters with over 436,000 kilograms of glass. With approximately 85% of the total estimated curie content removed from underground waste storage tanks during Phase 1, subsequent operations will focus on removal of tank heel wastes.


High-level Waste Canister Storage Final Design, Installation, and Testing. Topical Report

High-level Waste Canister Storage Final Design, Installation, and Testing. Topical Report

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Published: 1998

Total Pages: 43

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This report is a description of the West Valley Demonstration Project's radioactive waste storage facility, the Chemical Process Cell (CPC). This facility is currently being used to temporarily store vitrified waste in stainless steel canisters. These canisters are stacked two-high in a seismically designed rack system within the cell. Approximately 300 canisters will be produced during the Project's vitrification campaign which began in June 1996. Following the completion of waste vitrification and solidification, these canisters will be transferred via rail or truck to a federal repository (when available) for permanent storage. All operations in the CPC are conducted remotely using various handling systems and equipment. Areas adjacent to or surrounding the cell provide capabilities for viewing, ventilation, and equipment/component access.


Idaho Waste Vitrification Facilities Project Vitrified Waste Interim Storage Facility

Idaho Waste Vitrification Facilities Project Vitrified Waste Interim Storage Facility

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Published: 2001

Total Pages:

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This feasibility study report presents a draft design of the Vitrified Waste Interim Storage Facility (VWISF), which is one of three subprojects of the Idaho Waste Vitrification Facilities (IWVF) project. The primary goal of the IWVF project is to design and construct a treatment process system that will vitrify the sodium-bearing waste (SBW) to a final waste form. The project will consist of three subprojects that include the Waste Collection Tanks Facility, the Waste Vitrification Facility (WVF), and the VWISF. The Waste Collection Tanks Facility will provide for waste collection, feed mixing, and surge storage for SBW and newly generated liquid waste from ongoing operations at the Idaho Nuclear Technology and Engineering Center. The WVF will contain the vitrification process that will mix the waste with glass-forming chemicals or frit and turn the waste into glass. The VWISF will provide a shielded storage facility for the glass until the waste can be disposed at either the Waste Isolation Pilot Plant as mixed transuranic waste or at the future national geological repository as high-level waste glass, pending the outcome of a Waste Incidental to Reprocessing determination, which is currently in progress. A secondary goal is to provide a facility that can be easily modified later to accommodate storage of the vitrified high-level waste calcine. The objective of this study was to determine the feasibility of the VWISF, which would be constructed in compliance with applicable federal, state, and local laws. This project supports the Department of Energy's Environmental Management missions of safely storing and treating radioactive wastes as well as meeting Federal Facility Compliance commitments made to the State of Idaho.


Design of Equipment Used for High-level Waste Vitrification at the West Valley Demonstration Project

Design of Equipment Used for High-level Waste Vitrification at the West Valley Demonstration Project

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Published: 1997

Total Pages: 74

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The equipment as designed, started, and operated for high-level radioactive waste vitrification at the West Valley Demonstration Project in western New York State is described. Equipment for the processes of melter feed make-up, vitrification, canister handling, and off-gas treatment are included. For each item of equipment the functional requirements, process description, and hardware descriptions are presented.


Conceptual Design of a Nuclear Waste Vitrification Facility

Conceptual Design of a Nuclear Waste Vitrification Facility

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Published: 1978

Total Pages:

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This document describes a conceptual high-level waste immobilization facility. The facility would have the capability to calcine and then vitrify high-level liquid waste (HLLW). The vitrification would be accomplished in a canister which is seal-welded, checked for integrity, and decontaminated for movement to storage. Included in the facility would be the capability to repair faulty canister-lid seal welds, overpack failed canisters, and treat the process off-gas and cell ventilation air prior to release to the fuel reprocessing plant (FRP) atmospheric protection system (APS). The nuclear waste vitrification facility (NWVF) would be an integral part of the FRP structure. The operations of the facilities would be centered in the waste vitrification cell (WVC) which performs most of the facility functions. The cell is a reinforced concrete hot cell, lined with stainless steel. Most operation and maintenance activities would be performed remotely using a crane equipped with an impact wrench or yoke. The major facility equipment includes a feed tank, spray calciner, two melters, weld-inspection stations, canister storage rack, and a canister decontamination cubicle. Installation and removal of equipment in the cell would be done through shielding doors. The air lock system of the canister decontamination cubicle would permit placement and removal of the canister. Activities in the cell may be observed through four shielding glass windows and/or up to three periscopes. The operating, service, and pipe galleries which house operating personnel and equipment necessary for cell operations are located adjacent to the cell.


Predisposal Management of High Level Radioactive Waste

Predisposal Management of High Level Radioactive Waste

Author: International Atomic Energy Agency

Publisher: IAEA

Published: 2003

Total Pages: 74

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This Safety Guide provides regulatory bodies and the operators that generate and manage radioactive waste with recommendations on how to meet the principles and requirements established for the predisposal management of high level waste.


Design Features of a Full-scale High-level Waste Vitrification System

Design Features of a Full-scale High-level Waste Vitrification System

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Publisher:

Published: 1976

Total Pages:

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A system has been designed and is currently under construction for vitrification of commercial high-level waste. The process consists of a spray calciner coupled to an in-can melter. Due to the high radiation levels expected, this equipment is designed for totally remote operation and maintenance. The in-cell arrangement of this equipment has been developed cooperatively with a nuclear fuel reprocessor. The system will be demonstrated both full scale with nonradioactive simulated waste and pilot scale with actual high-level waste.


Radioactive Waste Forms for the Future

Radioactive Waste Forms for the Future

Author: Werner Lutze

Publisher: North Holland

Published: 1988

Total Pages: 802

ISBN-13:

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This volume presents a compilation of important information on the full range of radioactive waste forms that have been developed, or at least suggested, for the incorporation of high-level nuclear waste. Many of the results were published in the ''gray literature'' of final reports of national laboratories or in various, generally less available, proceedings volumes. This is the first publication to draw information on nuclear waste forms for high-level wastes together into a single volume. Although borosilicate glass has become the standard waste form, additional research in this compound is still necessary. With improved technology (particularly processing technologies) and with a more detailed knowledge of repository conditions, glasses and second generation waste forms with improved performance properties can be developed. Sustained research programs on nuclear waste form development will yield results that can only add to public confidence and the final, safe disposal of nuclear waste. The aim of this volume is to provide a 'spring board' for these future research efforts. A detailed presentation is given on the properties and performance of non-crystalline waste forms (borosilicate glass, sintered glass, and lead-iron phosphate glass), and crystalline waste forms (Synroc, tailored ceramics, TiO 2 - ceramic matrix, glass-ceramics and FUETAP concrete). A chapter on Novel Waste Forms reviews a number of methods that warrant further development because of their potential superior performance and unique applications. The final chapter includes a tabulated comparison of important waste form properties and an extended discussion on the corrosion process and radiation damage effects for each waste form. Of particular interest is a performance assessment of nuclear waste borosilicate glass and the crystalline ceramic Synroc. This is the first detailed attempt to compare these two important waste forms on the basis of their materials properties. The discussion emphasizes the difficulties in making such a comparison and details the types of data that are required. Each chapter has been written by an expert and includes a current compilation of waste form properties with an extensive list of references. This volume will provide a stimulus for future research as well as useful reference material for scientists working in the field of nuclear waste disposal and materials science.