Coordination Chemistry in Non-Aqueous Solutions

Coordination Chemistry in Non-Aqueous Solutions

Author: Victor Gutmann

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 181

ISBN-13: 3709181941

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Considerable attention has been focussed on non-aqueous chemistry in the last decade and this situation has arisen no doubt from a realization of the vast application of this branch of chemistry. Within this field much energetic work has been channelled into the determination of the coordination chemistry of tran sition metals in these solvent 8ystems. Elaborate experimental techniques have been developed to discover, in particular, the magnetic and spectral properties of complex compounds, and the theoretical background of such systems has been expanded to corroborate, as far as possible, the experimental results. This text has, however, a different bias from many books currently available on this branch of chemistry, and is designed to be a survey of known facts on many of the non-aqueous solvents currently in use mainly in the field of halogen chemistry, together with a discussion of these facts in the light of accepted principles. As such, it is hoped to close a gap in the literature of which many workers and advanced students in this field will be aware. The treatment is meant to be selective rather than completely comprehensive and must unevitably reflect some of the special interests of the author.


Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents

Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents

Author: K. Burger

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 269

ISBN-13: 0444597514

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Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.


Non-Aqueous Solutions – 5

Non-Aqueous Solutions – 5

Author: J. B. Gill

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 131

ISBN-13: 1483155714

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Non-Aqueous Solutions — 5 is a collection of lectures presented at the Fifth International Conference on Non-Aqueous Solutions held in Leeds, England, on July 5-9, 1976. The papers explore reactions in non-aqueous solutions as well as the thermodynamic and kinetic properties of non-aqueous solutions. Examples of the use of spectroscopic techniques are presented, and solutions in molten salts are given. Metals in solution and liquid metal solutions are also considered. This book is comprised of 12 chapters and begins with a review of a general scheme which considers the species formed by cation-electron and electron-electron interactions at dilute to moderate concentrations, along with the influence of the solvent and the metal on these interactions. The discussion then shifts to the application of electron spin resonance spectroscopy to the study of solvation; the influence of solvent properties on ligand substitution mechanisms of labile complexes; and the effect of acidity on chemical reactions in molten salts. Subsequent chapters deal with the chemistry of solutions of salts in liquid alkali metals; preferential solvation in kinetics; and the use of non-aqueous solvents for preparation and reactions of nitrogen halogen compounds. Results of Raman spectroscopic studies of non-aqueous solutions and spectroscopic studies of coordination compounds formed in molten salts are also presented. This monograph will be of interest to chemists.


Solvents and Solvent Effects in Organic Chemistry

Solvents and Solvent Effects in Organic Chemistry

Author: Christian Reichardt

Publisher: John Wiley & Sons

Published: 2011-08-04

Total Pages: 722

ISBN-13: 3527642137

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Now in its 4th edition, this book remains the ultimate reference for all questions regarding solvents and solvent effects in organic chemistry. Retaining its proven concept, there is no other book which covers the subject in so much depth, the handbook is completely updated and contains 15% more content, including new chapters on "Solvents and Green chemistry", "Classification of Solvents by their Environmental Impact", and "Ionic Liquids". An essential part of every organic chemist's library.


Inorganic Chemistry

Inorganic Chemistry

Author: J. E. House

Publisher: Academic Press

Published: 2012-10-30

Total Pages: 848

ISBN-13: 0123851106

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This textbook provides essential information for students of inorganic chemistry or for chemists pursuing self-study. The presentation of topics is made with an effort to be clear and concise so that the book is portable and user friendly. Inorganic Chemistry 2E is divided into five major themes (structure, condensed phases, solution chemistry, main group and coordination compounds) with several chapters in each. There is a logical progression from atomic structure to molecular structure to properties of substances based on molecular structures, to behavior of solids, etc. The author emphasizes fundamental principles-including molecular structure, acid-base chemistry, coordination chemistry, ligand field theory, and solid state chemistry -and presents topics in a clear, concise manner. There is a reinforcement of basic principles throughout the book. For example, the hard-soft interaction principle is used to explain hydrogen bond strengths, strengths of acids and bases, stability of coordination compounds, etc. The book contains a balance of topics in theoretical and descriptive chemistry. New to this Edition: New and improved illustrations including symmetry and 3D molecular orbital representationsExpanded coverage of spectroscopy, instrumental techniques, organometallic and bio-inorganic chemistryMore in-text worked-out examples to encourage active learning and to prepare students for their exams . Concise coverage maximizes student understanding and minimizes the inclusion of details students are unlikely to use. . Discussion of elements begins with survey chapters focused on the main groups, while later chapters cover the elements in greater detail. . Each chapter opens with narrative introductions and includes figures, tables, and end-of-chapter problem sets.


Synthetic Coordination Chemistry: Principles And Practice

Synthetic Coordination Chemistry: Principles And Practice

Author: Julian A Davies

Publisher: World Scientific

Published: 1996-09-20

Total Pages: 472

ISBN-13: 9814501131

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Although coordination chemistry naturally centers on the synthesis of coordination compounds, the synthesis of these materials is typically not an end in itself. Coordination compounds are utilized in all branches of chemistry; from theoretical modeling to industrial and consumer products. While a large amount of information is available on coordination chemistry in general and synthetic methods in particular, no comprehensive work has been presented on the preparation of coordination compounds with an emphasis on synthetic strategies rather than on detailed descriptions of specific syntheses. The goal of this book is to provide an approach to coordination chemistry that is based upon preparative strategies.The main aim of the authors is to present a systematic classification of synthetic reactions rather than an encyclopedic listing of experimental results. Hence, the coverage is more selective than exhaustive. Despite this, the book provides access to the original literature with ca. 2000 references. The edition is well-illustrated and contains almost 250 schemes, figures and illustrations of crystal structures of selected complexes.


Nonaqueous Solution Chemistry

Nonaqueous Solution Chemistry

Author: Orest Popovych

Publisher:

Published: 1981-05-12

Total Pages: 512

ISBN-13:

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From the Publisher: "Kenan Malik shows that race is not a biological reality-but also why it is so useful in scientific and medical research. He claims that it is not through scientific research into human differences but through our obsession with identity and diversity that dangerous ideas about race are once more catching fire. Blaming the preservation of racial ideas on the liberal antiracist movement with its emphasis on human difference over human commonalities, Malik shows how antiracists have, in recent years, become increasingly hostile to both scientific ideas and freedom of thought." Blending politics, history, science, and philosophy, Malik explores the science of skull measurement and the politics of the Holocaust; diabetes rates among Hispanics and the fate of the Elgin Marbles; the genetics of altruism and the struggle for Aboriginal rights; the successes of Human Genome Project and the failures of multiculturalism. Confronting issues such as the link between race and intelligence, the promotion of race-specific drugs, the fashion for genealogy, and why scientific research into controversial areas should not be constrained, Malik proves that the debate about race is back-and shows us how to deal with it.


Nonaqueous Electrochemistry

Nonaqueous Electrochemistry

Author: Doron Aurbach

Publisher: CRC Press

Published: 1999-07-27

Total Pages: 980

ISBN-13: 9780824741389

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An examination of applications of electrochemical techniques to many organic and inorganic compounds that are either unstable or insoluble in water. It focuses on the continuing drive toward miniaturization in electronics met by designs for high-energy density batteries (based on nonaqueous systems). It addresses applications to nonaqueous batteries, supercapacitators, highly sensitive reagents, and electroorganic and electroinorganic synthesis.


Comprehensive Coordination Chemistry II

Comprehensive Coordination Chemistry II

Author: J. A. McCleverty

Publisher: Newnes

Published: 2003-12-03

Total Pages: 11845

ISBN-13: 0080913164

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Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.