Cooperative Phenomena in Jahn—Teller Crystals
Cooperative Phenomena in Jahn—Teller Crystals

Author: Michael D. Kaplan

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 438

ISBN-13: 1461518598

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This book by Kaplan and Vekhter brings together the molecular world of the chemist with the condensed matter world of the physicist. Prior to the collapse of the Soviet Union, chemists in the West devoted lit to relationships between molecular electronic structure and tle attention solid-state vibronic phenomena. Treating quantum mechanical problems wherein the adiabatic Born-Oppenheimer approximation fails was done by "brute force. " With bigger and better computers available in the West, molecular orbital calculations were done on observed and conceived static structures with little concern for any cooperativity of vibrational behavior that might connect these states. While it had long been understood in the West that situations do occur in which different static structures are found for molecules that have identical or nearly identical electronic structures, little attention had been paid to understanding the vibrational states that could connect such structures. It was easier to calculate the electronic structure observed with several possible distortions than to focus on ways to couple electronic and vibrational behavior. In the former Soviet Union, computational power was not as acces sible as in the West. Much greater attention, therefore, was devoted to conserving computational time by considering fundamental ways to han dle the vibrational connectivity between degenerate or nearly degenerate electronic states.

Vibronic Interactions: Jahn-Teller Effect in Crystals and Molecules
Vibronic Interactions: Jahn-Teller Effect in Crystals and Molecules

Author: Michael D. Kaplan

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 378

ISBN-13: 9401009856

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This book is based mostly on the reports presented at the XVth International lahn-Teller Symposium on Vibronic Interactions in Crystals and Molecules and NATO Advanced Research Workshop Colossal Magnetoresistance and Vibronic Interactions that took place at Boston on August 16-22 of the year 2000. This is the first time the Symposium took place in the USA where recently the giant splash of the attention to the 1 ahn-Teller effect occurred. This tremendous interest to the field all over the world is reflected not only in the numerous publications in many American and European 10urnals, but of the leading scientists from additionally in the Symposium's participation the well known Universities, National Laboratories and industrial companies, which was the largest in the history of the Symposium. The renaissance of the 1ahn-Teller physics is closely related to the three fundamental discoveries in science. The most significant among them is the discovery of high-Tc superconductivity by K. -A. Muller and G. Bednorz, for whom the "1ahn-Teller idea" was the motivation in their search. The result of this search is well known - a wide spectrum of the 1ahn-Teller ion based materials with Tc between 24K and 135K were found. The second discovery is the existence of a new polymorph of carbon - the C60. The microscopic analysis of all physical, chemical and biological properties of the buckyballs is based on 1ahn-Teller type of interactions. The third is colossal magnetoresistance.

The Jahn-Teller Effect
The Jahn-Teller Effect

Author: Horst Köppel

Publisher: Springer Science & Business Media

Published: 2009-12-08

Total Pages: 912

ISBN-13: 3642034322

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The Jahn-Teller effect continues to be a paradigm for structural instabilities and molecular dynamical processes. This volume provides a survey of the current Jahn-Teller interactions at the interface of quantum chemistry and condensed matter physics.

Optoelectronic Properties of Inorganic Compounds
Optoelectronic Properties of Inorganic Compounds

Author: D. Max Roundhill

Publisher: Springer Science & Business Media

Published: 2013-03-09

Total Pages: 422

ISBN-13: 1475761015

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This book is intended to offer the reader a snapshot of the field of optoelectronic materials from the viewpoint of inorganic chemists. The field of inorganic chemistry is transforming from one focused on the synthesis of compounds having interesting coordination numbers, structures, and stereochemistries, to one focused on preparing compounds that have potentially useful practical applica tions. Two such applications are in the area of optics and electronics. These are fields where the use of inorganic materials has a long history. As the field of microelectronics develops the demands on the performance of such materials increases, and it becomes necessary to discover compounds that will meet these demands. The field of optoelectronics represents a merging of the two disciplines. Its emergence is a natural one because many of the applications involve both of these properties, and also because the electronic structure of a metal compound that confers novel optical properties is often one that also influences its electron transfer and conductivity characteristics. Two of the more important growth areas that have led to these developments are communications and medicine. Within the communications field there is the microelectronics that is involved in information storage and transmittal, some of which will be transferred into the optical regime. Within the medical field there are chemical probes that transmit analytical information from an in vivo environment. This information needs to be readily accessible from an external site, and then quickly converted into images or data that yield accurate and inexpensive diagnoses.

Extraction of Metals from Soils and Waters
Extraction of Metals from Soils and Waters

Author: D. Max Roundhill

Publisher: Springer Science & Business Media

Published: 2013-03-09

Total Pages: 387

ISBN-13: 1475752040

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Extractions of Metals from Soils and Waters represents a new emphasis in the series Modern Inorganic Chemistry, namely the impact inorganic chemistry can have on the environment. Also, this is the first volume ever to introduce the reader to all aspects of heavy metal extraction. While the primary emphasis is on complexation chemistry, attention is also paid to phase transfer aspects. Particular methods of note include electrokinetics, phytoremediation, and sensors. Aimed primarily at chemists, this book will also appeal to engineers, plant biochemists, environmental health specialists, and practitioners or students of environmental law.

Metal Dihydrogen and σ-Bond Complexes
Metal Dihydrogen and σ-Bond Complexes

Author: Gregory J. Kubas

Publisher: Springer Science & Business Media

Published: 2006-04-18

Total Pages: 479

ISBN-13: 0306475979

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According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview of `one of the hottest areas in chemistry'.

Vibronic Interactions in Molecules and Crystals
Vibronic Interactions in Molecules and Crystals

Author: Isaac B. Bersuker

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 434

ISBN-13: 3642834795

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Vibronic interaction effects constitute a new field of investigation in the physics and chemistry of molecules and crystals that combines all the phenomena and laws originating from the mixing of different electronic states by nuclear displacements. This field is based on a new concept which goes beyond the separate descriptions of electronic and nuclear motions in the adiabatic approximation. Publications on this topic often appear under the title of the lahn-Thller effect, although the area of application of the new approach is much wider: the term vibronic interaction seems to be more appropriate to the field as a whole. The present understanding of the subject was reached only recently, during the last quarter of a century. As a result of intensive development of the theory and experiment, it was shown that the nonadiabatic mixing of close-in-energy elec tronic states under nuclear displacements and the back influence of the modified electronic structure on the nuclear dynamics result in a series of new effects in the properties of molecules and crystals. The applications of the theory of vibronic in of spectroscopy [including visible, ultraviolet, in teractions cover the full range frared, Raman, EPR, NMR, nuclear quadrupole resonance (NQR), nuclear gam ma resonance (NOR), photoelectron and x-ray spectroscopy], polarizability and magnetic susceptibility, scattering phenomena, ideal and impurity crystal physics and chemistry (including structural as well as ferroelectric phase transitions), stereochemistry and instability of molecular (including biological) systems, mechanisms of chemical reactions and catalysis.

Mössbauer Spectroscopy Applied to Magnetism and Materials Science
Mössbauer Spectroscopy Applied to Magnetism and Materials Science

Author: G.J Long

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 370

ISBN-13: 1489917632

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This book represents Volume 2 in a series on the use of Mossbauer spectroscopy in the study of magnetism and materials. However, the perceptive reader will notice some differences from Volume 1. Specifically, in order to market the book at a more affordable price for most universities and research laboratories, the book has been prepared in camera ready format The editors and the authors agreed to do this because there is a demand for such a book in the Mossbauer community. This format has placed an extra burden on the editors and the authors and we hope we have overcome all the difficulties generated by the transfer of files between different computers. In order to make the book more attractive to materials scientists who are not experts in Mossbauer spectroscopy, this volume is particularly oriented towards the study of materials by Mossbauer spectroscopy and related complementary techniques, such as neutron scattering and a variety of surface scattering techniques. The authors of this volume can be proud of the high quality professional effort they have devoted to clearly presenting their specific topics. As a result we very much enjoyed working with the authors on this volume. We hope that their effort will help to educate the next generation of Mossbauer effect spectroscopists, a generation which will face the challenge of maintaining equally high scientific and professional standards in their research work.

Metal Complexes in Aqueous Solutions
Metal Complexes in Aqueous Solutions

Author: Arthur E. Martell

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 259

ISBN-13: 1489914862

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Stability constants are fundamental to understanding the behavior of metal ions in aqueous solution. Such understanding is important in a wide variety of areas, such as metal ions in biology, biomedical applications, metal ions in the environment, extraction metallurgy, food chemistry, and metal ions in many industrial processes. In spite of this importance, it appears that many inorganic chemists have lost an appreciation for the importance of stability constants, and the thermodynamic aspects of complex formation, with attention focused over the last thirty years on newer areas, such as organometallic chemistry. This book is an attempt to show the richness of chemistry that can be revealed by stability constants, when measured as part of an overall strategy aimed at understanding the complexing properties of a particular ligand or metal ion. Thus, for example, there are numerous crystal structures of the Li+ ion with crown ethers. What do these indicate to us about the chemistry of Li+ with crown ethers? In fact, most of these crystal structures are in a sense misleading, in that the Li+ ion forms no complexes, or at best very weak complexes, with familiar crown ethers such as l2-crown-4, in any known solvent. Thus, without the stability constants, our understanding of the chemistry of a metal ion with any particular ligand must be regarded as incomplete. In this book we attempt to show how stability constants can reveal factors in ligand design which could not readily be deduced from any other physical technique.