Comprehensive Treatise of Electrochemistry
Comprehensive Treatise of Electrochemistry

Author: Ernest B. Yeager

Publisher: Springer

Published: 1983-01-31

Total Pages: 560

ISBN-13:

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It is now time for a comprehensive treatise to look at the whole field of electrochemistry. The present treatise was conceived in 1974, and the earliest invitations to authors for contributions were made in 1975. The completion of the early volumes has been delayed by various factors. There has been no attempt to make each article emphasize the most recent situation at the expense of an overall statement of the modern view. This treatise is not a collection of articles from Recent Advances in Electro chemistry or Modern Aspects of Electrochemistry. It is an attempt at making a mature statement about the present position in the vast area of what is best looked at as a new interdisciplinary field. Texas A & M University John O'M. Bockris University of Ottawa Brian E. Conway Case Western Reserve University Ernest B. Yeager Texas A & M University Ralph E. White Preface to VoluIJJe 8 The past three decades have seen the rapid evolution of the transport aspects of electrochemical engineering into a formal part of electrochemistry as well as chemical engineering. With minor exceptions, however, this subject has not been systematically covered in any treatise or recent electrochemical text. The editors believe that the treatment in this volume will serve the function.

Comprehensive Treatise of Electrochemistry
Comprehensive Treatise of Electrochemistry

Author: Ralph E. White

Publisher: Springer

Published: 1984-09-30

Total Pages: 648

ISBN-13:

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It is now time for a comprehensive treatise to look at the whole field of electrochemistry. The present treatise was conceived in 1974, and the earliest invitations to authors for contributions were made in 1975. The completion of the early volumes has been delayed by various factors. There has been no attempt to make each article emphasize the most recent situation at the expense of an overall statement of the modern view. This treatise is not a collection of articles from Recent Advances in Electrochemistry or Modern Aspects of Electrochemistry. It is an attempt at making a mature statement about the present position in the vast area of what is best looked at as a new interdisciplinary field. Texas A & M University J. O'M. Bockris University of Ottawa B. E. Conway Case Western Reserve University Ernest Yeager Texas A & M University Ralph E. White Preface to Volume 8 Experimental methods in electrochemistry are becoming more diverse. This volume describes many of the new techniques that are being used as well as some of the well-established techniques. It begins with two chapters (1 and 2) on electronic instrumentation and methods for utilization of microcomputers for experimental data acquisition and reduction. Next, two chapters (3 and 4) on classical methods of electrochemical analysis are presented: ion selective electrodes and polarography.

Electrochemical Supercapacitors
Electrochemical Supercapacitors

Author: B. E. Conway

Publisher: Springer Science & Business Media

Published: 2013-04-17

Total Pages: 714

ISBN-13: 1475730586

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The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc ture of electrolyte solutions into the model of a metal/solution interface, by en visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti cians have introduced a number of new parameters of which people were not aware 50 years ago.