Hydrate research has expanded substantially over the past decade, resulting in more than 4,000 hydrate-related publications. Collating this vast amount of information into one source, Clathrate Hydrates of Natural Gases, Third Edition presents a thoroughly updated, authoritative, and comprehensive description of all major aspects of natural gas cla
Hydrate research has expanded substantially over the past decade, resulting in more than 4,000 hydrate-related publications. Collating this vast amount of information into one source, Clathrate Hydrates of Natural Gases, Third Edition presents a thoroughly updated, authoritative, and comprehensive description of all major aspects of natural gas clathrate hydrates. What’s New in the Third Edition? This new edition of a bestseller offers updated information on the clathrate hydrate compounds discovered in the past decade, provides a balance between experimental and theoretical perspectives, and incorporates two software programs that can be downloaded from the CRC press website. It also presents case studies on low dosage hydrate inhibitor prevention and hydrate drilling in nature, phase equilibrium data and kinetic models, and descriptions of the paradigm change in flow assurance to risk management. Other new material discusses the paradigm transition from hydrate reservoir assessment to reservoir production and summarizes the in situ conditions for hydrates in the permafrost and oceans. With this modern account of clathrate hydrates, you will acquire a fresh perspective on both new and old theories and data, hopefully leading you to pursue exciting research directions and practical applications.
This book is a companion to “Natural Gas Hydrate in Oceanic and Permafrost Environments” (Max, 2000, 2003), which is the first book on gas hydrate in this series. Although other gases can naturally form clathrate hydrates (referred to after as ‘hydrate’), we are concerned here only with hydrocarbon gases that form hydrates. The most important of these natural gases is methane. Whereas the first book is a general introduction to the subject of natural gas hydrate, this book focuses on the geology and geochemical controls of gas hydrate development and on gas extraction from naturally occurring hydrocarbon hydrates. This is the first broad treatment of gas hydrate as a natural resource within an economic geological framework. This book is written mainly to stand alone for brevity and to minimize duplication. Information in Max (2000; 2003) should also be consulted for completeness. Hydrate is a type of clathrate (Sloan, 1998) that is formed from a cage structure of water molecules in which gas molecules occupying void sites within the cages stabilize the structure through van der Waals or hydrogen bonding.
Gas hydrates, or clathrate hydrates, are crystalline solids resembling ice, in which small (guest) molecules, typically gases, are trapped inside cavities formed by hydrogen-bonded water (host) molecules. They form and remain stable under low temperatures – often well below ambient conditions – and high pressures ranging from a few bar to hundreds of bar, depending on the guest molecule. Their presence is ubiquitous on Earth, in deep-marine sediments and in permafrost regions, as well as in outer space, on planets or comets. In addition to water, they can be synthesized with organic species as host molecules, resulting in milder stability conditions: these are referred to as semi-clathrate hydrates. Clathrate and semi-clathrate hydrates are being considered for applications as diverse as gas storage and separation, cold storage and transport and water treatment. This book is the first of two edited volumes, with chapters on the experimental and modeling tools used for characterizing and predicting the unique molecular, thermodynamic and kinetic properties of gas hydrates (Volume 1) and on gas hydrates in their natural environment and for potential industrial applications (Volume 2).
Striking a balance between theoretical and experimental perspectives, this book presents a historical overview of clathrate hydrates and examines future trends, reviews crystal structures and properties, reveals industrial applications of clathrate hydrates in the production and processing of natural gas, discusses hydrate kinetics and elucidates the current status of hydrate time dependence, analyzes time-independent phase equilibria, and more. With nearly 300 tables and illustrations, the book is a practical guide for chemical, design, process, petroleum, and mechanical engineers; chemists and geochemists; geologists; geophysicists; and graduate-level students in these disciplines.
The petroleum industry spends millions of dollars every year to combat the formation of hydrates-the solid, crystalline compounds that form from water and small molecules-that cause problems by plugging transmission lines and damaging equipment. They are a problem in the production, transmission and processing of natural gas, and it is even possible for them to form in the reservoir itself if the conditions are favorable. Natural Gas Hydrates is written for the field engineer working in the natural gas industry. This book explains how, when and where hydrates form, while providing the knowledge necessary to apply remedies in practical applications. New to the second edition, the use of new inhibitors: Kinetic Inhibitors and Anticoagulants and the topic of kinetics of hydrates. How fast do they form? How fast do they melt? New chapters on Hydrates in Nature, hydrates on the seafloor and a new section has also been added regarding the misconceptions about water dew points. Chapters on Hydrate Types and Formers, Computer Methods, Inhibiting Hydrate Formation with Chemicals, Dehydration of Natural Gas and Phase Diagrams Hydrate Dehydration of Natural Gas and Phase Diagrams have been expanded and updated along with the companion website. - Understand what gas hydrates are, how they form and what can be done to combat their formation - Avoid the same problems BP experienced with clogged pipelines - Presents the four most common approaches to evaluate hydrates: heat, depressurization, inhibitor chemicals, and dehydration
With millions of kilometres of onshore and offshore oil and gas pipelines in service around the world, pipelines are the life's blood of the world. Notorious for disrupting natural gas production or transmission, the formation of natural gas hydrates can cost a company hundreds of millions and lead to catastrophic equipment breakdowns and safety and health hazards. Written by an international group of experts, Natural Gas Hydrates in Flow Assurance provide an expert overview of the practice and theory in natural gas hydrates, with applications primarily in flow assurance. Compact and easy to use, the book provides readers with a wealth of materials which include the key lessons learned in the industry over the last 20 years. Packed with field case studies, the book is designed to provide hands-on training and practice in calculating hydrate phase equilibria and plug dissociation. In addition readers receive executable programs to calculate hydrate thermodynamics. - Case studies of hydrates in flow assurance - The key concepts underlying the practical applications - An overview of the state of the art flow assurance industrial developments
