Ignition of upholstered furniture by small open flames from matches, cigarette lighters, and candles is one of the leading causes of residential-fire deaths in the United States. These fires accounted for about 16% of civilian fire deaths in 1996. On average, each year since 1990, about 90 deaths (primarily of children), 440 injuries, and property losses amounting to 50 million dollars have resulted from fires caused by the ignition of upholstered furniture by small open flames. Certain commercial seating products (such as aircraft and bus seats) are subject to flammability standards and sometimes incorporate FR-treated upholstery cover materials, but there is no federal-government requirement for residential upholstered furniture, and it is generally not treated with FR chemicals. It is estimated that less than 0.2% of all U.S. residential upholstery fabric is treated with flame-retardant (FR) chemicals. The Consumer Product Safety Act of 1972 created the U.S. Consumer Product Safety Commission (CPSC) as an independent federal regulatory agency whose mission is to protect the public from unreasonable risks of injury and death associated with consumer products. CPSC also administers the Flammable Fabrics Act, under which it regulates flammability hazards and the Federal Hazardous Substances Act (FHSA), which regulates hazardous substances including chemicals. In 1993, the National Association of State Fire Marshals petitioned CPSC to issue a performance-based flammability standard for upholstered furniture to reduce the risk of residential fires. The Commission granted that portion of the petition relating to small open flame ignition risks. In response to concerns regarding the safety of FR chemicals, Congress, in the fiscal year 1999 appropriations report for CPSC, requested that the National Research Council conduct an independent study of the health risks to consumers posed by exposure to FR chemicals that are likely to be used in residential upholstered furniture to meet a CPSC standard. The National Research Council assigned the project to the Committee on Toxicology (COT) of the Commission on Life Sciences' Board on Environmental Studies and Toxicology. COT convened the Subcommittee on Flame-Retardant Chemicals, which prepared this report. Subcommittee members were chosen for their recognized expertise in toxicology, pharmacology, epidemiology, chemistry, exposure assessment, risk assessment, and biostatistics. Toxicological Risks of Selected Flame-Retardant Chemicals is organized into 18 chapters and two appendices. Chapter 2 describes the risk assessment process used by the subcommittee in determining the risk associated with potential exposure to the various FR chemicals. Chapter 3 describes the method the subcommittee used to measure and estimate the intensity, frequency, extent, and duration of human exposure to FR chemicals. Chapters 4-19 provide the subcommittee's review and assessment of health risks posed by exposure to each of the 16 FR chemicals. Data gaps and research needs are provided at the end of these chapters.
Environmental Chemistry is a relatively young science. Interest in this subject, however, is growing very rapidly and, although no agreement has been reached as yet about the exact content and limits of this interdisciplinary discipline, there appears to be increasing interest in seeing environmental topics which are based on chemistry embodied in this subject. One of the first objectives of Environ mental Chemistry must be the study of the environment and of natural chemical processes which occur in the environment. A major purpose of this series on Environmental Chemistry, therefore, is to present a reasonably uniform view of various aspects of the chemistry of the environment and chemical reactions occurring in the environment. The industrial activities of man have given a new dimension to Environ mental Chemistry. We have now synthesized and described over five million chemical compounds and chemical industry produces about hundred and fifty million tons of synthetic chemicals annually. We ship billions of tons of oil per year and through mining operations and other geophysical modifications, large quantities of inorganic and organic materials are released from their natural deposits. Cities and metropolitan areas of up to 15 million inhabitants produce large quantities of waste in relatively small and confined areas. Much of the chemical products and waste products of modern society are released into the environment either during production, storage, transport, use or ultimate disposal. These released materials participate in natural cycles and reactions and frequently lead to interference and disturbance of natural systems.
Chlorinated paraffins are one of the last classes of chlorinated compounds that are still being produced worldwide and used in high quantities in many applications. They are particularly used in cutting oils in the metal industry, but also as lubricants, plasticizers, flame retardants and as additives in adhesives, rubber, paints and sealants. This volume covers the state-of-the-art of methods for the synthesis and analysis of chlorinated paraffins. Experts in the field provide an overview of their worldwide occurrence and utilization and describe their toxicological properties. International regulations and production volumes are presented as well as an example of a risk assessment study that was carried out in Japan. This book is a valuable and comprehensive source of information for environmental scientists interested in the occurrence and toxicology of chlorinated paraffins and for authorities and producers.
This indispensable book describes lubricant additives, their synthesis, chemistry, and mode of action. All important areas of application are covered, detailing which lubricants are needed for a particular application. Laboratory and field performance data for each application is provided and the design of cost-effective, environmentally friendly technologies is fully explored. This edition includes new chapters on chlorohydrocarbons, foaming chemistry and physics, antifoams for nonaqueous lubricants, hydrogenated styrene–diene viscosity modifiers, alkylated aromatics, and the impact of REACh and GHS on the lubricant industry.
An excellent, concise, and interdisciplinary overview of different classes of emerging pollutants arising, for example, from pharmaceuticals, pesticides, personal care products, and industrial chemicals and their impact on water, soil, and air. Following an introduction to chemical pollutants, with special attention focused on organic compounds and their properties, the book goes on to describe major emerging pollutants grouped according to their applications in different sectors of industrial or economic activity. For each type of compound, the chemical structure, main properties, and source are presented, along with their fate in the environment as pollutants, the latest analytical methods for detection, possible health or ecology consequences, as well as current regulatory laws. New developments, such as nanotechnology as a pollution source, are also included. The book closes with a chapter devoted to conclusions and future perspectives.
Textile auxiliaries are defined as chemicals of formulated chemical products which enables a processing operation in preparation, dyeing, printing of finishing to be carried out more effectively or which is essential if a given effect is to be obtained. Certain Textile Auxiliaries are also required in order to produce special finishing effects such as wash & wear, water repellence, flame retardancy, aroma finish, anti odour, colour deepening etc. The prime consideration in the choice of Textile materials is the purpose for which they are intended, but colour has been termed the best salesman in the present scenario. The modern tendency is towards an insistence on colour which is fast to light, washing, rubbing, and bleaching; this movement makes a great demand on the science of dyeing. Auxiliaries, dyes and dye intermediates play a vital role in textile processing industries. The manufacture and use of dyes is an important part of modern technology. Because of the variety of materials that must be dyed in a complete spectrum of hues, manufacturer now offer many hundreds of distinctly different dyes. The major uses of dyes are in coloration of textile fibers and paper. The substrates can be grouped into two major classes-hydrophobic and hydrophilic. Hydrophilic substances such as cotton, wool, silk, and paper are readily swollen by water making access of the day to substrate relatively easy. On other hand hydrophobic fibers, synthetic polyesters, acrylics, polyamides and polyolefin fibers are not readily swollen by water hence, higher application temperatures and smaller molecules are generally required. Dye, are classified according to the application method. Some of the examples of dyes are acid dyes, basic or cationic dyes, direct dyes, sulfur dyes, vat dyes, reactive dyes, mordant dyes etc. Colorants and auxiliaries will remain the biggest product segment, while faster gains will be seen in finishing chemicals. World demand for dyes and organic pigments is forecast to increase 3.9 percent per year through 2013, in line with real gains in manufacturing activity. Volume demand will grow 3.5 percent annually. While the textile industry will remain the largest consumer of dyes and organic pigments, faster growth is expected in other markets such as printing inks, paint and coatings, and plastics. Market value will benefit from consumer preferences for environmentally friendly products, which will support consumption of high performance dyes and organic pigments. Some of the fundamentals of the book are antimony and other inorganic compounds, halogenated flame retardants, phosphorous compounds, dyes and dye intermediates, textile fibers, pigment dyeing and printing, dry cleaning agents, dry cleaning detergents, acrylic ester resins, alginic acid, polyvinyl chloride, sodium carboxy methyl cellulose, guar gum, industries using guar gum, gum tragacanth, hydroxyethyl cellulose, polyethylene glycol, industries using polyethylene glycols, etc. The book covers details of antimony and other inorganic compounds, halogenated flame retardants, silicone oils, solvents, dyes and dye intermediates, dry cleaning agents, different types of gums used in textile industries, starch, flame retardants for textile and many more. This is very resourceful book for new entrepreneurs, technologists, research scholars and technical institutions related to textile. 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For more than eighty years, the name Ullmann's Encyclopedia of Industrial Chemistry has been synonymous with information of the highest quality. Chemists and engineers in industry and academia know that they can rely on the knowledge and expertise of around 3,000 first-class authors. The Fifth Edition, now available in print as a complete set, is a monumental reference work containing about 1,000 major articles, more than 16 million words, 30,000 figures, 10,000 tables, and innumerable references to further sources of information. Ullmann's users worldwide testify that this superb encyclopedia contains the most complete and up-to-date coverage of chemical technology currently available, including economic aspects, production, transportation, and toxicology. Ullmann's is unsurpassed in terms of organization and presentation. The encyclopedia consists of 37 volumes: 28 "A" volumes, 8 "B" volumes, and one cumulative Index volume. Volumes A1 - A28 contain alphabetically ordered articles on industrial chemicals, product groups, and production processes. Volumes B1 - B8 describe in detail the principles of chemical engineering, new and proven analytical methods, and the essentials of environmental protection technology. "This is a major work, which will prove immensely valuable to institutions and authorities related to the chemical industry." - Chemistry & Industry "...no science or engineering library should be without it." - Angewandte Chemie "Ullmann's might well be preferred...because of its many convenience features and excellent organisation." - Chemical Engineering
Summary Evaluates the risks to human health and the environment posed by exposure to chlorinated paraffins. These complex mixtures are widely used throughout the world as a secondary plasticizer in polyvinyl chloride, as extreme pressure lubricant additives in the metal-working industry, and in fire-retardant and water-repellent fabric treatment. Chlorinated paraffins are also added to paints, coatings, and sealants to improve resistance to water and chemicals. The most extensive section assesses findings from toxicity studies in experimental mammals and in vitro test systems. Studies demonstrate low acute oral toxicity and suggest that acute toxicity by the inhalation and dermal routes is also low. Repeated dose toxicity studies by the oral route consistently show that the liver, kidney and thyroid are the primary targets of toxic action. Long-term carcinogenicity studies in rodents have demonstrated increases in the incidence of hepatic, renal, and thyroid tumours following exposure to a short-chain compound. Following exposure to a long-chain compound, an increased incidence of malignant lymphomas and tumours of the adrenal gland has been observed. In reviewing the limited data on human health effects, the report notes that, despite widespread use of these compounds, no case reports of skin irritation or sensitization have been recorded. This observation is supported by studies of dermal exposure in human volunteers. The report concludes that, when proper personal hygiene and safety procedures are followed, risks to the health of exposed workers should be minimal. Since chlorinated paraffins bioaccumulate and are toxic to environmental organisms, the report recommends that use and disposal of these compounds should be controlled to avoid release to the environment.
This text of applied chemistry considers the interface between chemistry and chemical engineering, using examples of some of the important process in dustries. Integrated with this is detailed consideration of measures which may be taken for avoidance or control of potential emissions. This new emphasis in applied chemistry has been developed through eight years of experience gained from working in industry in research, development and environment al control fields, plus twelve years of teaching here using this approach. It is aimed primarily towards science and engineering students as well as to envi ronmentalists and practising professionals with responsibilities or an interest in this interface. By providing the appropriate process information back to back with emis sions and control data, the potential for process fine-tuning is improved for both raw material efficiency and emission control objectives. This approach also emphasizes integral process changes rather than add-on units for emis sion control. Add-on units have their place, when rapid action on an urgent emission problem is required, or when control simply is not feasible by pro cess integral changes alone. Obviously fundamental process changes for emission containment are best conceived at the design stage. However, at whatever stage process modifications are installed, this approach to control should appeal to the industrialist in particular, in that something more sub stantial than decreased emissions may be gained.
