Environmental Simulation Chambers: Application to Atmospheric Chemical Processes

Environmental Simulation Chambers: Application to Atmospheric Chemical Processes

Author: Ian Barnes

Publisher: Springer Science & Business Media

Published: 2006-04-23

Total Pages: 453

ISBN-13: 1402042329

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Atmospheric pollution has many different detrimental impacts on air quality at urban, regional and global scales. Large volume photoreactors (often referred to as smog or simulation chambers) have been used very effectively to investigate and understand many varied aspects of atmospheric chemistry related to air pollution problems. Photochemical smog formation, which was first observed around 1945 in Los Angeles, is now a major environmental problem for all industrialised and densely populated regions of the world. Over the years many different modelling and experimental tools have been developed to analyse and simulate the complex chemical processes associated with tropspheric photooxidant formation. Work in environmental chambers has played a key role in the development of our understanding of the atmospheric chemistry associated with pollution problems on local, regional and global scales. Chamber observations have also been used in connection with environmental policy issues. In general they are used for validation of atmospheric chemical models, studies of chemical reaction mechanisms and as a direct means to test the possible impact of specific chemical compounds on air quality under simulated ambient conditions New large smog chamber installations have been recently developed in the US (Riverside, California), Europe (Jülich, Germany) and Japan, and a large number of smaller scale laboratory chambers are in operation around the world. Over the years there have been numerous new technical developments related to environmental chamber facilities such as the design of the chambers (e. g.


Environmental Simulation Chambers: Application to Atmospheric Chemical Processes

Environmental Simulation Chambers: Application to Atmospheric Chemical Processes

Author: Ian Barnes

Publisher: Springer Science & Business Media

Published: 2006-01-13

Total Pages: 492

ISBN-13: 9781402042317

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The book gives in the first instance descriptions of different types of so-called environment chambers or photoreactors used mainly for the simulation and/or investigation of important chemical processes occurring in the atmosphere. The types of reactor described include outdoor and indoor chambers, temperature regulated chambers and glass and Teflon foil chambers The practical use of chambers is demonstrated in contributions by leading scientists in the field of atmospheric chemistry using, in many cases, current results. The types of atmospherically relevant investigations described include the measurement of reactivities, the measurement of radicals, the measurement of photolysis frequencies and products, kinetic and product studies on the oxidation of different types of hydrocarbons by important oxidant species (OH, N03, 03), formation of secondary organic aerosol from hydrocarbon oxidation etc. A special section includes contributions from eastern European countries which highlight some of the environmental research being performed in these countries. An abridged version of a specially commissioned review by the JRC Ispra on the status of environmental research in eastern European countries is also included in this section.


Atmospheric Multiphase Chemistry

Atmospheric Multiphase Chemistry

Author: Hajime Akimoto

Publisher: John Wiley & Sons

Published: 2020-06-02

Total Pages: 539

ISBN-13: 1119422426

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An important guide that highlights the multiphase chemical processes for students and professionals who want to learn more about aerosol chemistry Atmospheric Multiphase Reaction Chemistry provides the information and knowledge of multiphase chemical processes and offers a review of the fundamentals on gas-liquid equilibrium, gas phase reactions, bulk aqueous phase reactions, and gas-particle interface reactions related to formation of secondary aerosols. The authors—noted experts on the topic—also describe new particle formation, and cloud condensation nuclei activity. In addition, the text includes descriptions of field observations on secondary aerosols and PM2.5. Atmospheric aerosols play a critical role in air quality and climate change. There is growing evidence that the multiphase reactions involving heterogeneous reactions on the air-particle interface and the reactions in the bulk liquid phase of wet aerosol and cloud/fog droplets are important processes forming secondary aerosols in addition to gas-phase oxidation reactions to form low-volatile compounds. Comprehensive in scope, the book offers an understanding of the topic by providing a historical overview of secondary aerosols, the fundamentals of multiphase reactions, gas-phase reactions of volatile organic compounds, aqueous phase and air-particle interface reactions of organic compound. This important text: Provides knowledge on multiphase chemical processes for graduate students and research scientists Includes fundamentals on gas-liquid equilibrium, gas phase reactions, bulk aqueous phase reactions, and gas-particle interface reactions related to formation of secondary aerosols Covers in detail reaction chemistry of secondary organic aerosols Written for students and research scientists in atmospheric chemistry and aerosol science of environmental engineering, Atmospheric Multiphase Reaction Chemistry offers an essential guide to the fundamentals of multiphase chemical processes.


Mechanisms of Atmospheric Oxidation of the Alkanes

Mechanisms of Atmospheric Oxidation of the Alkanes

Author: Jack G Calvert

Publisher: Oxford University Press

Published: 2008-09-15

Total Pages: 1005

ISBN-13: 0199710880

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An international team of eminent atmospheric scientists have prepared Mechanisms of Atmospheric Oxidation of the Alkanes as an authoritative source of information on the role of alkanes in the chemistry of the atmosphere. The book includes the properties of the alkanes and haloalkanes, as well as a comprehensive review and evaluation of the existing literature on the atmospheric chemistry of the alkanes and their major atmospheric oxidation products, and the various approaches now used to model the alkane atmospheric chemistry. Comprehensive coverage is given of both the unsubstituted alkanes and the many haloalkanes. All the existing quality measurements of the rate coefficients for the reactions of OH, Cl, O(3P), NO3, and O3 with the alkanes, the haloalkanes, and their major oxidation products have been reviewed and evaluated. The expert authors then give recommendations of the most reliable kinetic data. They also review the extensive literature on the mechanisms and rates and modes of photodecomposition of the haloalkanes and the products of atmospheric oxidation of the alkanes and the haloalkanes, and make recommendations for future use by atmospheric scientists. The evaluations presented allow an extrapolation of the existing kinetic and photochemical data to those alkanes and haloalkanes that are as yet unstudied. The current book should be of special interest and value to the modelers of atmospheric chemistry as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the alkanes, their major oxidation products, and their influence on ozone and other trace gases within the troposphere.


Multiphase Environmental Chemistry in the Atmosphere

Multiphase Environmental Chemistry in the Atmosphere

Author: Sherri W. Hunt

Publisher: ACS Symposium

Published: 2019

Total Pages: 0

ISBN-13: 9780841233638

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This book highlights new cross-disciplinary advances in aerosol chemistry that involve more than one phase, for example, unique chemical processes occurring on gas-solid and liquid-solid interfaces.


A Practical Guide to Atmospheric Simulation Chambers

A Practical Guide to Atmospheric Simulation Chambers

Author: Jean-François Doussin

Publisher: Springer Nature

Published: 2023-05-25

Total Pages: 345

ISBN-13: 3031222776

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This open access title presents atmospheric simulation chambers as effective tools for atmospheric chemistry research. State-of-the-art simulation chambers provide unprecedented opportunities for atmospheric scientists to perform experiments that address the most important questions in air quality and climate research. The book covers technical details about chamber preparation and practical guidelines on their usage, while also delivering relevant historical and contextual information. It not only serves as a key publication for knowledge transfer within the simulation chamber research community, but it also provides the global atmospheric science community with a unique resource that outlines best practice for the operation of simulation chambers. The authors summarize the latest advances in chamber interoperability and standard protocols in order to provide the research community and the next generations of scientists with a unique technical reference guide for the use of simulation chambers. The volume will be of great interest to researchers and graduates working in the fields of Atmospheric and Environmental Sciences.


Organic Chemistry

Organic Chemistry

Author: Harold H. Trimm

Publisher: CRC Press

Published: 2011-04-15

Total Pages: 367

ISBN-13: 1466559780

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This title includes a number of Open Access chapters. This book presents a range of research on important topics in the field. Of the approximately 11 million known chemical compounds, about 10 million are organic. Organic chemists are currently working to produce better polymers with specific properties, such as biodegradable plastics. The understanding of new drug structures from plants and the synthesis of improved pharmaceuticals is another area of great interest. Organic chemists are also researching the reactions that occur in living systems and understanding the molecular causes of disease.


Atmospheric Aerosols

Atmospheric Aerosols

Author: Rekha Kale

Publisher: Scitus Academics LLC

Published: 2015-03

Total Pages: 0

ISBN-13: 9781681171326

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Atmospheric Aerosols is a vital problem in current environmental research due to its importance in atmospheric optics, energetics, radiative transfer studies, chemistry, climate, biology and public health. Aerosols can influence the energy balance of the terrestrial atmosphere, the hydrological cycle, atmospheric dynamics and monsoon circulations. Because of the heterogeneous aerosol field with large spatial and temporal variability and reduction in uncertainties in aerosol quantification is a challenging task in atmospheric sciences. Keeping this in view the present study aims to assess the impact of aerosols on coastal Indian station Visakhapatnam and the adjoining Bay of Bengal. An aerosol is a colloid of fine solid particles or liquid droplets, in air or another gas. Aerosols can be natural or not. Examples of natural aerosols are fog, forest exudates and geyser steam.


Atmospheric and Biological Environmental Monitoring

Atmospheric and Biological Environmental Monitoring

Author: Young Kim

Publisher: Springer Science & Business Media

Published: 2009-06-04

Total Pages: 315

ISBN-13: 1402096747

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The extent of harmful effects of pollution on atmospheric, terrestrial and aquatic environments can be translated into extreme temperature changes, dirty air, clean water shortages, and increased incidence of toxicity that harms every life on earth. Within a lifetime, our environment is changing drastically. Much of the information of environmental pollution impacts needs to be studied, from the mechanism of toxic nanoparticles on the molecular level to the detection of trace gases on the satellite perspective. It is therefore essential to develop advanced monitoring techniques, e- cient process technologies and health impact assessment tools to ?ll the gaps in our scienti?c knowledge. This edition of “Atmospheric and Biological Environmental Monitoring” is a handful of recent developments and techniques from environmental scientists in well-diversi?ed ?elds. These collections of manuscripts are extracts from the recently concluded “7th International Symposium on Advanced Environmental Monitoring” organized by the ADvanced Environmental Monitoring and Research Center (ADEMRC), Gwangju Institute of Science and Technology (GIST), Korea and held on February 25–28, 2008 in Honolulu, Hawaii. The three parts highlight important aspects of emerging environmental monitoring technologies: Atmospheric Environment, Contaminants Control Process, and Environmental Toxicity Asse- ment. Observational tools presented in the ?rst part ranges from in-situ measurements to satellite remote sensing for atmospheric monitoring. Highlighted in the second part is the recently developed water quality monitoring system for lake strati?cation and membrane technologies for detection and removal of contaminants. Lastly, toxicity monitoring of endocrine disruptors and nanoparticles are highlighted in the third part with new discoveries.


The Mechanisms of Atmospheric Oxidation of the Aromatic Hydrocarbons

The Mechanisms of Atmospheric Oxidation of the Aromatic Hydrocarbons

Author: Jack G. Calvert

Publisher: Oxford University Press

Published: 2002-02-14

Total Pages: 570

ISBN-13: 9780199771547

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This text reviews many of the aspects of the chemistry of the aromatic hydrocarbons and a consensus evaluation of the data by seven of the leading atmospheric scientists. The book covers topics ranging from the relative importance of the compounds in ozone and haze development to methods of estimating elemantary rate coefficients based on structural features of the compounds to mechanisms of aerosol generation and atmostpheric reaction of the polycyclic compounds to photochemical processes. It identifies features of the aromatic hydrocarbons requiring further study and appendicies give the structural formulas and nomenclature of the compounds reviewed in the book.