These proceedings reflect the important role of catalysis in petroleum refining and the effects of factors such as environmental legislation on the industry. They also show the emergence of significant scientific expertise in the Middle East - the cradle of the oil industry. Participants from all over the world took part in the meeting and the book contains a well-balanced selection of articles from both academia and industry. Current trends in the oil industry focused attention mainly on heavy end hydrotreating, but other processes also gained their share of attention. An invaluable feature of the meeting was the two panel discussions where participants took the opportunity to obtain advance on many real and immediate problems.
Catalysis plays an increasingly critical role in modern petroleum refining and basic petrochemical industries as market demands for and specifications of petroleum and petrochemical products are continuously changing. As we enter the 21st century, new challenges for catalysis science and technology are anticipated in almost every field. Particularly, better utilization of petroleum resources and demands for cleaner transportation fuels are major items. It was against this background that the 2nd International Conference on Catalysts in Petroleum Refining and Petrochemical Industries was organized. The conference was attended by around 300 specialists in the catalysis field from both academia and industry from over 30 countries. It provided a forum for the exchange of ideas between scientists and engineers from the region with their counterparts from industrialized countries.The papers from the conference, which were carefully selected from around 100 submissions, were refereed in terms of scientific and technical content and format in accordance with internationally accepted standards. They comprise a mix of reviews providing an overview of selected areas, original fundamental research results, and industrial experiences.
The field of petrochemicals started some years ago with the simple addition reaction of water to propylene for the production of isopropyl alcohol. Currently, the petrochemical industry has become a multi-billion dollar enterprise which encompasses a wide field of chemical products. Almost all the basic organic reactions such as hydrogenation, alkylation, substitution, polymerization, etc. are utilized for the production of these chemicals. It may not, however, have been possible to establish this huge industry without the use of different catalysts. In other words, the great advancements in the catalytic area have supported the vast developments in the petrochemical field. In this book, we have adopted the idea of discussing the petrochemical industry from the point of view of reactants' activities and susceptibilities toward different catalysts. The book is thus classified according to the reaction type. This will eriable students and other users of the book to base their understanding of the petrochemical field on the fundamental principles learned in chemistry. How ever, the first chapter is aimed at establishing some basic facts on the petro chemical industry and its major uses. It discusses, without going into details, the raw materials used, the intermediates and the downstream products. The next eight chapters discuss in some detail the main reactions and the catalysts used for the production of chemicals and polymers from petroleum. The last chapter is devoted to a discussion of some of the practical techniques used in the catalytic field.
These proceedings reflect the important role of catalysis in petroleum refining and the effects of factors such as environmental legislation on the industry. They also show the emergence of significant scientific expertise in the Middle East - the cradle of the oil industry. Participants from all over the world took part in the meeting and the book contains a well-balanced selection of articles from both academia and industry. Current trends in the oil industry focused attention mainly on heavy end hydrotreating, but other processes also gained their share of attention. An invaluable feature of the meeting was the two panel discussions where participants took the opportunity to obtain advance on many real and immediate problems.
The topics covered in this book include a variety of adsorption and model reaction studies on clean and modified single crystal metal surfaces obtained by means of properly selected surface sensitive techniques. The accent is on the revelation of the physics and chemistry involved in the effects of various modifiers on the adsorptive and reactivity properties of the surface with respect to different reactants. In this book current information that contributes to the fundamental understanding of the effect of additives is summarized. Some of the additives act as promoters, others as poisons, in a number of important catalytic reactions. A description of single- and double-component systems has been obtained by using surface-sensitive techniques, particularly suited for this purpose. For the benefit of the reader, a short summary of the main surface science techniques has been given in Chapter 2. Three general and interrelated topics are reviewed. The first concerns the interaction of electronegative (Cl, S, Se, C, N, O, P) and electropositive (alkali metals) atoms with metal surfaces (Chapter 4). The second topic covers the chemisorptive properties of metal surfaces modified by varying amounts of additives with respect to different reactants (CO, NO, N2, O2, H2, CO2, NH3, H2O and hydrocarbons) (Chapters 5 and 6). In particular the adsorption kinetics and energetics, and the electronic, structural and reactive properties of the coadsorbate systems are considered, whereby particular attention is given to recent surface science studies with well-characterized, single crystal, metal surfaces. In these chapters, special attention is paid to showing the contribution of different factors (the nature and adsorption state of the modifier and the coadsorbed molecule, the structure of the adsorbed layer, the type of interactions in the mixed overlayers, etc.) to the modifier effects. In the discussion of the third topic, model studies of several important catalytic reactions (Fischer-Tropsch synthesis, ammonia synthesis, CO oxidation, water-gas shift synthesis) on modified metal surfaces (Chapter 8) are considered.The book will be particularly useful to scientists who are interested in adsorption phenomena, surface properties and catalysis. It should also prove invaluable to those addressing the questions of condensed matter (surfaces and interfaces), materials science (e.g. corrosion of metals) and electrochemistry.
Key Features: Describes feedstock evaluation and the effects of elemental, chemical and fractional composition. Details reactor types and bed types. Explores the process options and parameters involved. Assesses coke formation and additives. Considers next generation processes and developments.
Solid catalysts play a fundamental role in all areas between basic research and industrial applications. This book offers a large amount of information about the preparation of solid catalysts. All types of solid catalysts and all important aspects of their preparation are discussed. The highly topical contributions are written by leading experts in disciplines ranging from solid state, interface and solution chemistry to industrial engineering. The straightforward presentation of the material and the comprehensive coverage make this book an essential and indispensible tool for every scientist and engineer working with solid catalysts.
Introduction to Zeolite Molecular Sieves, 3rd Edition presents a collection of the most important results and ideas in the field of molecular sieve chemistry and technology, the most important experimental techniques related to the research activities in molecular sieves, and identifies new areas of molecular sieve chemistry. Chapters start at a reasonably simple entry level, but also covers the present state-of-the-art in the field. Topics covered include structure, synthesis, characterization, ion exchange, adsorption, diffusion, separations, and natural zeolites.* 6 years since the last edtion this book brings together the rapid development within the field of molecular sieve chemistry and applications * Accessible to newcomers to the field, also containing valuable information for experienced researchers * 27 chapters written by renowned scientists in their field, including updates on some 2nd edition chapters
Presents advances in the field of hydrocracking. The volume includes catalytic materials, reaction mechanisms and pathways, as well as hydrocracking processes and applications. It discusses hydrocracking processes and hydrocracking technology in catalytic dewaxing, resid upgrading, and fluid catalytic cracking feedstock improvement