Dense Phase Carbon Dioxide

Dense Phase Carbon Dioxide

Author: Murat O. Balaban

Publisher: John Wiley & Sons

Published: 2012-04-05

Total Pages: 337

ISBN-13: 1118243323

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Dense phase carbon dioxide (DPCD) is a non-thermal method for food and pharmaceutical processing that can ensure safe products with minimal nutrient loss and better preserved quality attributes. Its application is quite different than, for example, supercritical extraction with CO 2 where the typical solubility of materials in CO 2 is in the order of 1% and therefore requires large volumes of CO 2. In contrast, processing with DPCD requires much less CO 2 (between 5 to 8% CO 2 by weight) and the pressures used are at least one order of magnitude less than those typically used in ultra high pressure (UHP) processing. There is no noticeable temperature increase due to pressurization, and typical process temperatures are around 40°C. DPCD temporarily reduces the pH of liquid foods and because oxygen is removed from the environment, and because the temperature is not high during the short process time (typically about five minutes in continuous systems), nutrients, antioxidant activity, and vitamins are much better preserved than with thermal treatments. In pharmaceutical applications, DPCD facilitates the production of micronized powders of controlled particle size and distribution. Although the capital and operating costs are higher than that of thermal treatments, they are much lower than other non-thermal technology operations. This book is the first to bring together the significant amount of research into DPCD and highlight its effectiveness against microorganisms and enzymes as well as its potential in particle engineering. It is directed at food and pharmaceutical industry scientists and technologists working with DPCD and other traditional or non-thermal technologies that can potentially be used in conjunction with DPCD. It will also be of interest to packaging specialists and regulatory agencies.


Dense Phase Carbon Dioxide

Dense Phase Carbon Dioxide

Author: Murat O. Balaban

Publisher: John Wiley & Sons

Published: 2012-06-19

Total Pages: 337

ISBN-13: 0813806496

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Dense phase carbon dioxide (DPCD) is a non-thermal method for food and pharmaceutical processing that can ensure safe products with minimal nutrient loss and better preserved quality attributes. Its application is quite different than, for example, supercritical extraction with CO 2 where the typical solubility of materials in CO 2 is in the order of 1% and therefore requires large volumes of CO 2. In contrast, processing with DPCD requires much less CO 2 (between 5 to 8% CO 2 by weight) and the pressures used are at least one order of magnitude less than those typically used in ultra high pressure (UHP) processing. There is no noticeable temperature increase due to pressurization, and typical process temperatures are around 40°C. DPCD temporarily reduces the pH of liquid foods and because oxygen is removed from the environment, and because the temperature is not high during the short process time (typically about five minutes in continuous systems), nutrients, antioxidant activity, and vitamins are much better preserved than with thermal treatments. In pharmaceutical applications, DPCD facilitates the production of micronized powders of controlled particle size and distribution. Although the capital and operating costs are higher than that of thermal treatments, they are much lower than other non-thermal technology operations. This book is the first to bring together the significant amount of research into DPCD and highlight its effectiveness against microorganisms and enzymes as well as its potential in particle engineering. It is directed at food and pharmaceutical industry scientists and technologists working with DPCD and other traditional or non-thermal technologies that can potentially be used in conjunction with DPCD. It will also be of interest to packaging specialists and regulatory agencies.


Geochemistry of Geologic CO2 Sequestration

Geochemistry of Geologic CO2 Sequestration

Author: Donald J. DePaolo

Publisher: Walter de Gruyter GmbH & Co KG

Published: 2018-12-17

Total Pages: 556

ISBN-13: 1501508075

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Volume 77 of Reviews in Mineralogy and Geochemistry focuses on important aspects of the geochemistry of geological CO2 sequestration. It is in large part an outgrowth of research conducted by members of the U.S. Department of Energy funded Energy Frontier Research Center (EFRC) known as the Center for Nanoscale Control of Geologic CO2 (NCGC). Eight out of the 15 chapters have been led by team members from the NCGC representing six of the eight partner institutions making up this center - Lawrence Berkeley National Laboratory (lead institution, D. DePaolo - PI), Oak Ridge National Laboratory, The Ohio State University, the University of California Davis, Pacific Northwest National Laboratory, and Washington University, St. Louis.


Handbook of Aqueous Electrolyte Thermodynamics

Handbook of Aqueous Electrolyte Thermodynamics

Author: Joseph F. Zemaitis, Jr.

Publisher: John Wiley & Sons

Published: 2010-09-16

Total Pages: 876

ISBN-13: 0470938404

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Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.


Thermodynamics Of Fluids: Measurement And Correlation

Thermodynamics Of Fluids: Measurement And Correlation

Author: A Anderko

Publisher: World Scientific

Published: 1990-03-01

Total Pages: 526

ISBN-13: 9814611778

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This volume is a collection of papers, mostly state-of-the-art reviews, describing main topics of current research in Applied Thermodynamics. The papers deal with measurements of thermodynamic properties which are important for process design in chemical and related industries as well as for theoretical investigations of pure fluids and mixtures. Besides measuring techniques, methods are reviewed for the processing and correlation of experimental data.


Geological Sequestration of Carbon Dioxide

Geological Sequestration of Carbon Dioxide

Author: Luigi Marini

Publisher: Elsevier

Published: 2006-10-12

Total Pages: 471

ISBN-13: 0080466885

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The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates. Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises. Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer.* Provides applications for investigating and predicting geological carbon dioxide sequestration* Reviews the geochemical literature in the field* Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration


Electrochemical and Electrocatalytic Reactions of Carbon Dioxide

Electrochemical and Electrocatalytic Reactions of Carbon Dioxide

Author: B.P. Sullivan

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 314

ISBN-13: 0444596615

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The recycling of atmospheric molecules for use as fuels and chemicals is a goal which can only be achieved through a deeper understanding of catalytic processes, particularly electrocatalysis whereby redox transformations can be interfaced with solar or nuclear energy input. Carbon dioxide is a prototypical small molecule in many regards since it is chemically inert. In addition, because of the likely role of carbon dioxide in global temperature cycles, it will be imperative in the future to regulate the output from industrial processes. The purpose of this book is to present a unified discussion of the carbon dioxide chemistry which is necessary for the understanding and design of electrochemically-driven processes for the reduction of carbon dioxide and to provide an impetus for the further development of electrocatalytic carbon dioxide chemistry.