Calixarenes was the first book to be published in the `Monographs in Supramolecular Chemistry' series and is also the first complete survey available of this rapidly developing field. It provides a fascinating and lively account of the history, development and applications of calixarenes, which are probably the world's most readily available synthetic molecular baskets. These basket shaped compounds possess the ability to hold metal ions, as well as molecules, in their interior and as a result of their extraordinarily easy synthesis from phenols and aldehydes are receiving increasingly wide attention. This book is a must for advanced undergraduates and post-graduates studying bio-organic and supramolecular chemistry.
"Calixarenes: An introduction 2nd Edition provides a concise overview of the field with particular attention to the historical development of calixarenes. Topics covered include: how to synthesize and functionalize calixarenes, examination of calixarenes properties, and applied uses of calixarenes." "This book contains extensive references to recent literature, offering the reader a valid presentation of information, and will be of immediate value to researchers, as well as graduates and professionals, who require a comprehensive introduction to the subject."--P. 4 of cover.
Contributions featuring the chemistry and applications of a family of macrocyclic compounds collectively known as 'calixarenes' are presented in this edited volume. The arsenal of structures based on calixarenes provides tools which are effective in numerous areas of supramolecular chemistry. The Editors have compiled a timely volume which contains up to date, high calibre contributions from a large number of international authors. A broad perspective on the progress and future of calixarene chemistry is presented. Aimed at students and researchers active in Supramolecular Chemistry.
This book provides a timely review of both the current state of knowledge and the exciting prospects offered by calixarenes in nanotechnology. The book incorporates several review articles defining the importance of calixarenes as reagents in nanochemistry. Calixarenes in the Nanoworld is designed for a broad audience of professionals in universities, research institutions, and industries engaged in the production of high-tech materials.
Calixarenes in Action is unique among books devoted to this interesting class of synthetic macrocycles. Rather than emphasizing the molecular properties of calixarenes, it covers in depth their supramolecular functions, enlightening the reader as to the peculiar features of calixarenes as hosts and as platforms for the synthesis of more complex receptors and catalysts. Topics covered in detail include the use of calixarenes in:molecular modeling of calixarenesnon-covalent interactionscrystal engineeringcation recognitionanion recognitionsupramolecular devicesnew materialsself-assembly processessupramolecular catalysisThe interest in calixarenes has grown tremendously in the last few years and this book reports, for each topic, the most recent literature critically evaluated by active researchers in the field. Calixarenes in Action is a valuable reference book for researchers in organic, inorganic, analytical and environmental chemistry and can serve as a graduate-level text for students of supramolecular science and technology.
In recent years there has been an explosive growth in the field of calixarene chemistry. Calixarenes Revisited, a sequel to the 1989 publication Calixarenes, brings researchers right up to date with current developments in this increasingly competitive area. Covering in depth the synthesis, characterization and properties, as well as conformation, reactions and complex formations of these 'baskets', Calixarenes Revisited is the most complete treatment of the subject available for researchers employing calixarenes in their work. It builds on the framework of the first volume, and can be used by readers already familiar with the field. For those with a less detailed background, it can be used in tandem with Calixarenes to provide a complete picture. Spanning the period 1989 to 1996, items are fully referenced and an extensive bibliography is included.
Calixarene chemistry, at the turn of the millennium, is a field approaching true maturity. In many areas, applications are real and important, and the arsenal of structures based on calixarenes provides tools effective in numerous areas of supramolecular chemistry. In this book, chapters contributed by a broad spectrum of international authors provide a variety of perspectives upon the progress and future of calixarene chemistry. Issues covered in depth include: Calixarene synthesis, with all its subtleties and sophistication. Forces at play in the inclusion of neutral and charged molecules by calixarenes. Theoretical analyses of calixarene properties. Dynamics and thermodynamics of calixarenes and their complexes. Nanocomposite construction based on calixarene aggregates. Calixarenes on surfaces. Analytical applications of calixarenes. Catalysis by calixarenes and their complexes. Resource recovery and waste treatment with calixarenes. New directions in calixarene chemistry. Hetero- and homo-calixarenes. Bioactive calixarenes. Coordination chemistry of calixarenes. Calixarenes in the solid state.
Macrocyclic molecules contain rings made up of seven or more atoms. They are interesting because they provide building blocks for synthesizing precise two or three dimensional structures – an important goal in nanotechnology. For example, they can be used to develop nanosized reaction vessels, cages, switches and shuttles, and have potential as components in molecular computers. They also have applications as catalysts and sensors. Macrocycles: Construction, Chemistry and Nanotechnology Applications is an essential introduction this important class of molecules and describes how to synthesise them, their chemistry, how they can be used as nanotechnology building blocks, and their applications. A wide range of structures synthesised over the past few decades are covered, from the simpler cyclophanes and multi-ring aromatic structures to vases, bowls, cages and more complex multi-ring systems and 3D architectures such as “pumpkins”, interlocking chains and knots. Topics covered include: principles of macrocycle synthesis simple ring compounds multi-ring aromatic structures porphyrins and phthalocanines cyclophanes crown ethers, cryptands and spherands calixarenes, resorcinarenes, cavitands, carcerands, and heterocalixarenes cyclodextrins cucurbiturils cyclotriveratylenes rotaxanes catenanes complex 3D architectures, including trefoils and knots Macrocycles: Construction, Chemistry and Nanotechnology Applications distills the essence of this important topic for undergraduate and postgraduate students, and for researchers in other fields interested in getting a general insight into this increasingly important class of molecules.
Comprehensive Supramolecular Chemistry II, Second Edition, Nine Volume Set is a ‘one-stop shop’ that covers supramolecular chemistry, a field that originated from the work of researchers in organic, inorganic and physical chemistry, with some biological influence. The original edition was structured to reflect, in part, the origin of the field. However, in the past two decades, the field has changed a great deal as reflected in this new work that covers the general principles of supramolecular chemistry and molecular recognition, experimental and computational methods in supramolecular chemistry, supramolecular receptors, dynamic supramolecular chemistry, supramolecular engineering, crystallographic (engineered) assemblies, sensors, imaging agents, devices and the latest in nanotechnology. Each section begins with an introduction by an expert in the field, who offers an initial perspective on the development of the field. Each article begins with outlining basic concepts before moving on to more advanced material. Contains content that begins with the basics before moving on to more complex concepts, making it suitable for advanced undergraduates as well as academic researchers Focuses on application of the theory in practice, with particular focus on areas that have gained increasing importance in the 21st century, including nanomedicine, nanotechnology and medicinal chemistry Fully rewritten to make a completely up-to-date reference work that covers all the major advances that have taken place since the First Edition published in 1996
Iptycenes Chemistry: From Synthesis to Applications provides a comprehensive overview of the development of iptycene chemistry in the past seventy years. This book covers: (1) the basic nomenclature and general properties of iptycenes and their derivatives; (2) the synthesis and functionalization reactions of triptycenes, pentiptycenes, higher iptycenes, heterotriptycenes, and homotriptycenes; (3) the methods for the preparation of iptycene-based polymers with different types; and (4) the applications of iptycenes and their derivatives in molecular machines, materials science, host-guest chemistry, self-assembly, coordination chemistry, physical organic chemistry, medicinal chemistry, and so on. Consequently, such a book is not only helpful to researchers working in iptycene chemistry, but can also facilitate future research in wide areas.
