Metal contamination in the environment is a persisting global issue. The metal reservoirs in the earth have declined due to society’s needs and due to uncontrolled mining activities. Therefore, the idea to recover metals from waste streams has emerged. In this thesis, cost competitive technologies such as adsorption using agro-wastes and precipitation using an inverse fluidized bed (IFB) reactor were investigated, with special emphasis on the recovery of base metals. Groundnut shell showed good potential for metal (Cu, Pb and Zn) removal. From artificial neural network modeling, the performance of the sulfate reducing bacteria (SRB) was found to be strongly pH dependent; the removal efficiency of Cu and Zn in the IFB at pH 5.0 was >97%. Electronic waste is a good candidate as secondary metal resource. The recovery of Cu from computer printed circuited boards (PCBs) using biogenic sulfide precipitation was investigated as well. Using this technology, Cu could be recovered at ~0.48 g Cu/g PCBs.
Waste electrical and electronic equipment (WEEE) generation is a global problem. Despite the growing awareness and deterring legislation, most of the WEEE is disposed improperly, i.e. landfilled or otherwise shipped overseas, and treated in sub-standard conditions. Informal recycling of WEEE has catastrophic effects on humans and the environment. WEEE contains considerable quantities of valuable metals such as base metals, precious metals and rare earth elements (REE). Metal recovery from WEEE is conventionally carried out by pyrometallurgical and hydrometallurgical methods. In this PhD research, novel metal recovery technologies from WEEE are investigated. Using acidophilic and cyanide-generating bacteria, copper and gold were removed from crushed electronic waste with removal efficiencies of 98.4 and 44.0%, respectively. The leached metals in solution were recovered using sulfidic precipitation and electrowinning separation techniques. Finally, a techno-economic assessment of the technology was studied. This research addresses the knowledge gap on two metal extraction approaches, namely chemical and biological, from a secondary source of metals. The essential parameters of the selective metal recovery processes, scale-up potential, techno-economic and sustainability assessment have been studied.
Fundamental Modelling of Membrane Systems: Membrane and Process Performance summarizes the state-of-the-art modeling approaches for all significant membrane processes, from molecular transport, to process level, helping researchers and students who carry out experimental research save time and accurately interpret experimental data. The book provides an overview of the different membrane technologies, handling micro-, ultra-, and nanofiltration, reverse and forward osmosis, pervaporation, gas permeation, supported liquid membranes, membrane contactors, membrane bioreactors and ion-exchange membrane systems. Examples of hybrid membrane systems are also included. - Presents an accessible reference on how to model membranes and membrane processes - Provides a clear, mathematical description of mass transfer in membrane systems - Written by well-known, prominent authors in the field of membrane science
This book discusses the bioremediation of both solid and liquid waste, including regional solutions for India as well as globally relevant applications. The topics covered include pollutant reduction through composting, solutions for petroleum refinery waste, use of microorganisms in the bioremediation of industrial waste and toxicity reduction, microbial fuel cells, and microbial depolymerisation. The book also explores the biosorption of metals and the bioremediation of leachates, especially with regard to soil and groundwater remediation. It is a valuable resource for researchers, professionals, and policy makers alike.
The first-ever book on this subject establishes a rigid, transparent and useful methodology for investigating the material metabolism of anthropogenic systems. Using Material Flow Analysis (MFA), the main sources, flows, stocks, and emissions of man-made and natural materials can be determined. By demonstrating the application of MFA, this book reveals how resources can be conserved and the environment protected within complex systems. The fourteen case studies presented exemplify the potential for MFA to contribute to sustainable materials management. Exercises throughout the book deepen comprehension and expertise. The authors have had success in applying MFA to various fields, and now promote the use of MFA so that future engineers and planners have a common method for solving resource-oriented problems.
In the context of wastewater treatment, Bioelectrochemical Systems (BESs) have gained considerable interest in the past few years, and several BES processes are on the brink of application to this area. This book, written by a large number of world experts in the different sub-topics, describes the different aspects and processes relevant to their development. Bioelectrochemical Systems (BESs) use micro-organisms to catalyze an oxidation and/or reduction reaction at an anodic and cathodic electrode respectively. Briefly, at an anode oxidation of organic and inorganic electron donors can occur. Prime examples of such electron donors are waste organics and sulfides. At the cathode, an electron acceptor such as oxygen or nitrate can be reduced. The anode and the cathode are connected through an electrical circuit. If electrical power is harvested from this circuit, the system is called a Microbial Fuel Cell; if electrical power is invested, the system is called a Microbial Electrolysis Cell. The overall framework of bio-energy and bio-fuels is discussed. A number of chapters discuss the basics – microbiology, microbial ecology, electrochemistry, technology and materials development. The book continues by highlighting the plurality of processes based on BES technology already in existence, going from wastewater based reactors to sediment based bio-batteries. The integration of BESs into existing water or process lines is discussed. Finally, an outlook is provided of how BES will fit within the emerging biorefinery area.
This document presents key messages and the state-of-the-art of soil pollution, its implications on food safety and human health. It aims to set the basis for further discussion during the forthcoming Global Symposium on Soil Pollution (GSOP18), to be held at FAO HQ from May 2nd to 4th 2018. The publication has been reviewed by the Intergovernmental Technical Panel on Soil (ITPS) and contributing authors. It addresses scientific evidences on soil pollution and highlights the need to assess the extent of soil pollution globally in order to achieve food safety and sustainable development. This is linked to FAO’s strategic objectives, especially SO1, SO2, SO4 and SO5 because of the crucial role of soils to ensure effective nutrient cycling to produce nutritious and safe food, reduce atmospheric CO2 and N2O concentrations and thus mitigate climate change, develop sustainable soil management practices that enhance agricultural resilience to extreme climate events by reducing soil degradation processes. This document will be a reference material for those interested in learning more about sources and effects of soil pollution.
This book covers the principles, underlying mechanisms, thermodynamic functions, kinetics and modeling aspects of sustainable technologies, particularly from the standpoint of applying physical, chemical and biological processes for the treatment of wastewater polluted with heavy metals. Particular emphasis has been given to technologies that are based on adsorption, electro-coagulation, bio-precipitation, bio-solubilization, phytoremediation and microbial electrolysis. Metal contamination in the environment is one of the persisting global issues. The adverse health effects of heavy metals on human beings and its impact on the environment has been well-documented. Several physico-chemical and biological technologies have been successfully implemented to prevent and control the discharge of industrial heavy metal emissions. On the contrary, metal resource depletion has also accelerated dramatically during the 20th century due to rapid advances in industrial engineering and medical sciences, which requires large amount of raw materials. To meet the global metal demand, in recent years, novel research lines have started to focus on the recovery of metals from metal contaminated waste streams. In order to conflate both metal removal and recovery, new technologies have been successfully tested, both at the lab and pilot-scale. The target audience of this book primarily comprises of research experts, practicing engineers in the field of environmental/chemical technology and graduate students.
Part of Groundwater Set - Buy all six books and save over 30% on buying separately! Biffaward Winner 2002 The Clean Rivers Trust has fought off stiff competition to become the Research and Development - Technology Category winner at the Biffaward Awards 2002, with its project "Technology Analysis of Acid Mine Drainage Treatment Methods". Minewater Treatment - Technology, Application and Policy, was produced based on the findings of the research to aid in the selection, design and implementation of the most appropriate treatment techniques for particular minewater discharges. Much work has been carried out in recent decades concerning minewater treatment, both in the UK and worldwide. Many different bodies and organizations are involved in developing minewater treatment processes and schemes. Minewater Treatment addresses the need for a single source of state-of-the-art information that draws all the latest research material together. Key features of the book include: a full literature review of minewater treatment throughout the world an overview of relevant legislation and policy in a global context a review of currently available methods for treating minewater worldwide a site specific inventory of minewater treatment schemes within the UK, including compilation of available monitoring data and assessment of performance a review of emerging and innovative minewater treatment technologies and consideration of related academic research within the UK a comprehensive list of active and innovative minewater treatment technologies that are not currently compiled in a book or other review publication a detailed summary and recommendations section assessing the applicability, efficiency and cost-effectiveness of minewater treatment schemes Relevant scientific subject matter is presented in a concise, easily accessible manner to assist with the objective assessment of the progress made to date. Heavily illustrated with many colour photographs, the book allows best use to be made of the collective experience of minewater treatment practitioners throughout the UK, whilst at the same time placing the UK experience within a global context. An invaluable reference work for mining companies, consultants, planning officers, environmental research scientists, environmental agencies, water utilities and regulatory bodies, Minewater Treatment is a definitive source of information on minewater treatment technologies and will help facilitate the selection of the most appropriate technique required to tackle particular minewater discharge problems. Contents The minewater problem Treatment options Existing sites in the UK: Case studies Existing sites in the UK: Site summaries Summary & conclusions
