Sol-Gel Science
Sol-Gel Science

Author: C. Jeffrey Brinker

Publisher: Academic Press

Published: 2013-10-22

Total Pages: 925

ISBN-13: 0080571034

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Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing presents the physical and chemical principles of the sol-gel process. The book emphasizes the science behind sol-gel processing with a chapter devoted to applications. The first chapter introduces basic terminology, provides a brief historical sketch, and identifies some excellent texts for background reading. Chapters 2 and 3 discuss the mechanisms of hydrolysis and condensation for nonsilicate and silicate systems. Chapter 4 deals with stabilization and gelation of sols. Chapter 5 reviews theories of gelation and examines the predicted and observed changes in the properties of a sol in the vicinity of the gel point. Chapter 6 describes the changes in structure and properties that occur during aging of a gel in its pore liquor (or some other liquid). The discussion of drying is divided into two parts, with the theory concentrated in Chapter 7 and the phenomenology in Chapter 8. The structure of dried gels is explored in Chapter 9. Chapter 10 shows the possibility of using the gel as a substrate for chemical reactions or of modifying the bulk composition of the resulting ceramic by performing a surface reaction (such as nitridation) on the gel. Chapter 11 reviews the theory and practice of sintering, describing the mechanisms that govern densification of amorphous and crystalline materials, and showing the advantages of avoiding crystallization before sintering is complete. The properties of gel-derived and conventional ceramics are discussed in Chapter 12. The preparation of films is such an important aspect of sol-gel technology that the fundamentals of film formation are treated at length in Chapter 13. Films and other applications are briefly reviewed in Chapter 14. Materials scientists and researchers in the field of sol-gel processing will find the book invaluable.

Sol-Gel Technologies for Glass Producers and Users
Sol-Gel Technologies for Glass Producers and Users

Author: Michel Andre Aegerter

Publisher: Springer Science & Business Media

Published: 2013-03-19

Total Pages: 474

ISBN-13: 0387889531

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Sol-Gel Techniques for Glass Producers and Users provides technological information, descriptions and characterizations of prototypes, or products already on the market, and illustrates advantages and disadvantages of the sol-gel process in comparison to other methods. The first chapter entitled "Wet Chemical Technology" gives a summary of the basic principles of the sol-gel chemistry. The most promising applications are related to coatings. Chapter 2 describes the various "Wet Chemical Coating Technologies" from glass cleaning to many deposition and post-coating treatment techniques. These include patterning of coatings through direct or indirect techniques which have became very important and for which the sol-gel processing is particularly well adapted. Chapter 3 entitled "Bulk Glass Technologies" reports on the preparation of special glasses for different applications. Chapter 4 entitled "Coatings and Materials Properties" describes the properties of the different coatings and the sol-gel materials, fibers and powders. The chapter also includes a section dedicated to the characterization techniques especially applied to sol-gel coatings and products.

Transformation of Organometallics into Common and Exotic Materials: Design and Activation
Transformation of Organometallics into Common and Exotic Materials: Design and Activation

Author: R.M. Laine

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 297

ISBN-13: 9400913931

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The design, -synthesis, and selective pyrolytic conversion of organo metallic precursdrs to materials of high purity or specific morphology (for electronic or optical applications), high strength and/or high-temperature stability (for structural or refractory applications) represents a poten tial area of extreme growth at the overlap of chemistry and materials science (materials chemistry). Research in this area is likely to have considerable impact at both the academic and societal levels because it will require development of scientific expertise in areas currently not well understood. Examples include: (1) The thermodynamics of molecular rearrangements in organometallic molecules at temperatures above 200°C; (2) The electronic properties of amorphous ceramic materials; (3) The phys icochemical properties of ceramic molecular composites; and (4) The optical properties of multicomponent glasses made by sol-gel processing. The opportunity to establish the scientific principles needed to pursue useful research goals in "materials chemistry" requires communica tion between chemists, ceramists, metallurgists, and physicists. To date, there have been few opportunities to create an environment where such communication might occur. The objective of this NATO Advanced Research Workshop was to promote discussions between experts in the varibus disci plines aligned with "materials chemistry. " These discussions were intended to identify the scope and potential rewards of research efforts in the development of: Custom-designed precursors to common and exotic materials, methods of selectively transforming these precursors in high yield to the desired material, and methods of characterizing the final products.

Handbook of Zeolite Science and Technology
Handbook of Zeolite Science and Technology

Author: Scott M. Auerbach

Publisher: CRC Press

Published: 2003-07-31

Total Pages: 1526

ISBN-13: 0824756126

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The Handbook of Zeolite Science and Technology offers effective analyses ofsalient cases selected expressly for their relevance to current and prospective research. Presenting the principal theoretical and experimental underpinnings of zeolites, this international effort is at once complete and forward-looking, combining fundamental concepts with the most sophisticated data for each scientific subtopic and budding technology. Supplying over 750 figures, and 350 display equations, this impressive achievement in zeolite science observes synthesis through the lens of MFI (ZSM-5 and silicalite). Chapters progress from conceptual building blocks to complex research presentations.

Engineering Ceramics ’96: Higher Reliability through Processing
Engineering Ceramics ’96: Higher Reliability through Processing

Author: G.N. Babini

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 418

ISBN-13: 9401157987

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Despite the significant progress, which has been made in developing of ceramic materials desired for engineering applications, their mass production is still not on expected level. Among the key factors hindering higher exploitation of these materials the problems in processing were identified. The processing comprises powder production, mixing techniques, forming, and sintering. All of them are equally important and all of them can introduce defects into the material. Besides improvement in processing, the properties of ceramic materials can be considerably improved by the creation of composites. Composites formed at micro or macro level are able to form more flaw-tolerant material. Considerable research activities, working on above mentioned phenomena are in progress at industrial laboratories as well as other research centres. This volume presents the contributions to the Advanced Research Workshop "Engineering Ceramics '96" with 65 participants from 21 countries held on 12th - 15th May 1996 at Smolenice Castle, Slovakia, the conference site of Slovak Academy of Sciences. The book covers research activities on engineering ceramic materials and gives an overview with respect to recent developments.

Optical Fiber Sensor Technology
Optical Fiber Sensor Technology

Author: L.S. Grattan

Publisher: Springer Science & Business Media

Published: 2013-03-09

Total Pages: 340

ISBN-13: 9401724849

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Environmental and chemical sensors in optical fiber sensor technology The nature of the environment in which we live and work, and the precarious state of many aspects of the natural environment, has been a major lesson for scientists over the last few decades. Public awareness of the issues involved is high, and often coupled with a scepticism of the ability of the scientist and engineer to provide an adequate, or even rapid solution to the preservation of the environment before further damage is done, and to achieve this with a mini mum of expenditure. Monitoring of the various aspects of the environment, whether it be external or internal to ourselves and involving chemical, physical or biomedical parameters is an essential process for the well-being of mankind and of the individual. Legis lative requirements set new standards for measurement and control all around us, which must be met by the most appropriate of the technologies available, commensurate with the costs involved. Optical fiber sensor technology has a major part to play in this process, both to complement existing technologies and to promote new solutions to difficult measurement issues. The developments in new sources and detectors covering wider ranges of the electromagnetic spectrum, with higher sensitivity, allow the use of techniques that some time ago would have been considered inappropriate or lacking in sufficient sensitivity.