This book covers all research fields in high Tc Superconductivity. Breakthrougs in the single crystal growth of a monolithic device leads to a new technology.
More than seven years have passed since the dramatic breakthrough in the critical temperature for superconductors. During this period, a host of new materials have been discovered, and efforts have been stepped up in a variety of domains including device and systems applications, commercialization, and basic research on the properties of superconductive materials. Recent progress in areas such as bulk single crystal production, long-scale wire and tape produc tion, flywheel and bearing applications, and electronic device applications for thin films indicate that science and technology have been working hand in hand in this field, as has been the case in the research and development of semi conductors. This interdisciplinary "resonance" will be certain to lead to further outstanding advances in the years to come. It goes without saying that worldwide information exchange is the key to accelerating progress in superconductivity science and technology. As in previous years, the ISS '93 served as a venue where visions of future develop ments were shared in addition to presentations and extensive discussions on the most up-to-date research results. I hope that the Proceedings contained in this volume will be consulted not only as a summary of the current "state of the art" in high-Tc superconductivity but also as a stimulating source of ideas regarding future applications of superconductivity research.
Intense recent activity in the field of high-temperature superconductivity both in Japan and in the rest of the world was discussed at the First International Symposium on Superconductivity held in Nagoya in August 1988. Current research and development efforts by major Japanese companies in the field of high-temperature superconductivity are reported by leading company scientists, to give an overview of the high level of activity in the area. Progress in the development of new materials and recent theoretical work is reported both from Japanese and international researchers. Contributions are organized by topic, with such topics as crystal chemistry and electronic structure, processing and microstructure, tapes and thick films, wires and coils, and thin film processing and properties. Future applications of superconductivity including magnetic levitation vehicles, electronics based on Josephson junctions, power delivery, energy storage, ship propulsion and magnetic resonance imaging are particularly stressed.
The 11th International Symposium on Superconductivity was held November 16-19, 1998, in Fukuoka, Japan. Convened annually since 1988, the symposium covers the whole field of superconductivity from fundamental physics and chemistry to new applications. At the 11th Symposium, there was increased interest reported in the development of trial devices using bismuth wires and yttrium-based bulk materials. Among the presentations were those that clearly defined the development targets for next-generation yttrium-based wires and bulk materials and single-flux quantum (SFQ) circuits. Other popular topics were high-temperature superconductivity applications such as SQUIDs, microwave filters, and cryocooler-cooled magnets. With more than 600 participants from 18 countries, the symposium provided an excellent forum for exchanges of the most recent information in the field of superconductivity.
The field of high-temperature superconductivity has encouraged an inter disciplinary approach to research. It has required significant cooperation and collaboration among researchers, each of whom has brought to it a rich variety of experience from many other fields. Recently, great improvements have been made in the quality of research. The subject has matured and been launched into the next stage through the resonance between science and technology. The current progress of materials processing and engineering in this field is analogous to that previously seen in the development of semiconductors. These include the appearance of materials taking the place of YBa2Cu307 owing to their improved properties (higher critical temperatures and stronger flux pin ning) in which rare earth ions with large radii (La, Nd, Sm) substitute for Y; the development of technology enabling growth control on the nanometer scale; and precise and reproducible measurements that can be used as rigorous tests of theoretical models, which in turn are expected to lead to the develop ment of new devices. For further progress in high-T research, academics and c technologists must pool their knowledge and experience. I hope that this volume will promote that goal by providing the reader with the latest results of high-temperature superconductor research and will stimulate further discussion and collaboration.
Since the discovery of superconductivity with trans1tton temperatures above 77 K, concentrated research activities toward the exploration of practical applica tions of these materials have been carried out. Currently, a remarkable improve ment in superconducting properties has been achieved due to the fine optimization of fabrication processes, and this has attracted industrial interest for future applications. In the case of NdBa Cu 0 materials, a new pinning mecha 2 3 7 nism was found which enhances the critical current under applied magnetic fields. In single crystals of these materials, oxygen control results in an increase in the growth rate. The metalorganic chemical vapor deposition (MOCVD) film quality has been improved by using a new liquid raw material. Simultaneously, real demands from the viewpoint of the market start to be a motivation force, es pecially in electronics application where some products are already being sold. At the same time, interesting physical properlies have been obtained from a new superconducting single crystal which has a layered perovskite structure without copper. In addition, various precision measurement techniques have confirmed the d-wave mechanism and the existence of intrinsicJosephson junctions in single crystals. These new phenomena challenge the existing theoretical models but also open the way for new applications. These significant areas of progress in materials science have led high-Tc super conductivity research into the next phase of activity, while fundamental research continues to be very important. I sincerely hope that this volume will give further impetus to this development.
Five years have passed since the breakthrough in the critical temperature for superconductors. During this period, many superconducting materials have been discovered and developed, and our knowledge of the physical and other properties of oxide superconductors has deepened through extensive and intensive research. This knowledge has advanced superconductivity science and technology from the initial questioning stage to a more developed but still uncertain second stage where research activity in superconductivity now overlaps with fields of application. Generally speaking, science resonates with technology. Science not only complements but also competes with or stimulates technology. New scientific knowledge has triggered the second technological research stage. Much progress has been made in the development of practical devices, encouraging the application of superconductors in areas such as human levitation, a high speed levitated bearing, large current transforming leads, and high frequency devices. This technological progress has increased our understanding of the science involved, such as flux pinning and dynamics, and anomalous long-range superconducting interactions. At this important stage, international cooperation and collaborative projects can effectively sustain aggressive research and development in order to advance superconductivity to the next stages. The ISS Symposium is expected to serve as a venue for increasing our knowledge of superconductivity and for exchanging visions for future research and applications, through the presentation and discus of the latest research results. These proceedings also aim to summarize sion annual progress in high-Tc superconductivity in all fields.
The authors of this book present current research in the study of superconductivity. Topics discussed in this compilation include the effects of non-magnetic defects in hole doped cuprates; deep cryogenic refrigeration by photons based on the phonon deficit effect in superconductors; superconductivity driven by an anti-polar electric phase in high temperature superconducting materials; superconductive graphite intercalation compounds; a superconducting magnetic field concentrator with nanodimensional branches and slits; magnetic mechanisms of pairing in a strongly correlated electron system of copper oxides; two non-linear mechanisms of correlations between copper carriers in superconductivity and their microscopical descriptions; three dimensionality of the critical state and variational methods for magnetically anisotropic superconductors; theory of multi-band superconductivity; conserving approximation for the self-energy of the t-U-V-J model beyond the Hartree-Fock approximation; and superconductivity as a consequence of an ordering of zero-point oscillations in electron gas.
C axis Current I ~ . The (11 0) thick homoepitaxial film of 320 nm -------~ ~-=-=--==---==--==--==--- shows a very good surface flatness, which --------·· sJ;1 0] suggests the unique (110) atomic plane helps 2- A [1 1 OJ dimensional epitaxial growth of YBCO films, and shows excellent high Tc. The resultant 1. 0 surface morphology of YBCO is quite different Q ,. -- R(270)=1. 60 m 0 from the (110) heteroepitaxial films of similar 0 0. 0 " thickness [11). In the case of heteroepitaxy ~ . ,,_. 1. 0 irrespective of c-axis [ 12] or a-axis oriented ~ ~. . ,. R(270)=3. 71 m 0 films [5), only thin films show flat surfaces, g 0. 0 . . Tc=92. 3K "' which, however, give usually a degraded Tc due -~ 1. 0 v v I - to lattice mismatching. In conclusion, we have ::1. ,. . . . . R(270)=31. 9 mO succeeded to grow high-quality (11 0) YBCO ~ YBCO film . . Tc=90. 7 K 0. 0 ·;:: YBCO(IIO) 1 0 ·d·--~ YBCO thinfilms on (11 0) YBCO single crystal § substrate ~Xtt=u 1. 0 substra substrates with very flat surfaces and high Tc's. :£ R(270)=40. 1 m 0 0. 0 LLLLL. J. . . . LL~. t-J' L-Tc=9LWO. L-! L-K LLLLL. . . . L. . I. . . . l. . . . L. L. L. J. . . . . L. L. l. . . J 50 100 150 200 250 300 0 ACKNOWLEDGMENTS Temperature (K) One of the authors (T. U. ) would like to thank Fig.
Superconductivity is the ability of certain materials to conduct electrical current with no resistance and extremely low losses. High temperature superconductors, such as La2-xSrxCuOx (Tc=40K) and YBa2Cu3O7-x (Tc=90K), were discovered in 1987 and have been actively studied since. In spite of an intense, world-wide, research effort during this time, a complete understanding of the copper oxide (cuprate) materials is still lacking. Many fundamental questions are unanswered, particularly the mechanism by which high-Tc superconductivity occurs. More broadly, the cuprates are in a class of solids with strong electron-electron interactions. An understanding of such "strongly correlated" solids is perhaps the major unsolved problem of condensed matter physics with over ten thousand researchers working on this topic. High-Tc superconductors also have significant potential for applications in technologies ranging from electric power generation and transmission to digital electronics. This ability to carry large amounts of current can be applied to electric power devices such as motors and generators, and to electricity transmission in power lines. For example, superconductors can carry as much as 100 times the amount of electricity of ordinary copper or aluminium wires of the same size. Many universities, research institutes and companies are working to develop high-Tc superconductivity applications and considerable progress has been made. This volume brings together new leading-edge research in the field.