Molten Salt Chemistry

Molten Salt Chemistry

Author: Gleb Mamantov

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 538

ISBN-13: 9400938632

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Molten salts are of considerable significance to chemical technology. Applications range from the established ones, such as the production of aluminum, magnesium, sodium and fluorine, to those as yet to be fully exploited, such as molten salt batteries and fuel cells, catalysis, and solar energy. Molten salts are investigated for different purposes by many diverse techniques. There is a need to keep investigators working in different areas, such as metal production, power sources, and glass industry, aware of progress in various specialties, as well as to familiarize new research workers with the fundamental aspects of the broad field of molten salt _ chemistry. This volume constitutes the plenary lectures presented at the NATO Advanced Study Institute on Molten Salt Chemistry, Camerino, Italy, August 3-15, 1986. The fundamentals and several selected applications of molten salt chemistry were addressed. The major fundamental topics covered at this ASI were the structure of melts, thermodynamics of molten salt mixtures, theoretical and experimental studies of transport processes, metal-metal salt solutions, solvent properties of melt systems, acid-base effects in molten salt chemistry, electronic absorption, vibrational, and nuclear magnetic resonance spectroscopy of melt systems, electrochemistry and electroanalytical chemistry in molten salts, and organic chemistry in molten salts. The applied aspects of molten salt chemistry included the chemistry of aluminum production, electrodeposition using molten salts, and molten salt batteries and fuel cells.


Molten Salts Chemistry and Technology

Molten Salts Chemistry and Technology

Author: Marcelle Gaune-Escard

Publisher: John Wiley & Sons

Published: 2014-05-12

Total Pages: 902

ISBN-13: 1118448820

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Written to record and report on recent research progresses in the field of molten salts, Molten Salts Chemistry and Technology focuses on molten salts and ionic liquids for sustainable supply and application of materials. Including coverage of molten salt reactors, electrodeposition, aluminium electrolysis, electrochemistry, and electrowinning, the text provides researchers and postgraduate students with applications include energy conversion (solar cells and fuel cells), heat storage, green solvents, metallurgy, nuclear industry, pharmaceutics and biotechnology.


Advances in Chemical Physics, Volume 48

Advances in Chemical Physics, Volume 48

Author: Ilya Prigogine

Publisher: John Wiley & Sons

Published: 2009-09-08

Total Pages: 562

ISBN-13: 0470143142

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The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.


Molten Salts Chemistry

Molten Salts Chemistry

Author: FREDERIC Lantelme

Publisher: Elsevier

Published: 2013-08-30

Total Pages: 0

ISBN-13: 9780123985385

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Molten salts and fused media provide the key properties and the theory of molten salts, as well as aspects of fused salts chemistry, helping you generate new ideas and applications for fused salts. Molten Salts Chemistry: From Lab to Applications examines how the electrical and thermal properties of molten salts, and generally low vapour pressure are well adapted to high temperature chemistry, enabling fast reaction rates. It also explains how their ability to dissolve many inorganic compounds such as oxides, nitrides, carbides and other salts make molten salts ideal as solvents in electrometallurgy, metal coating, treatment of by-products and energy conversion. This book also reviews newer applications of molten salts including materials for energy storage such as carbon nano-particles for efficient super capacitors, high capacity molten salt batteries and for heat transport and storage in solar plants. In addition, owing to their high thermal stability, they are considered as ideal candidates for the development of safer nuclear reactors and for the treatment of nuclear waste, especially to separate actinides from lanthanides by electrorefining.


Modern Aspects of Electrochemistry 45

Modern Aspects of Electrochemistry 45

Author: Ralph E. White

Publisher: Springer Science & Business Media

Published: 2009-08-12

Total Pages: 351

ISBN-13: 144190655X

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This volume maintains the series’ high standards, containing chapters covering topics such as the cathodic reduction of nitrate, and including discussion of product selectivity, current efficiency, and the thermodynamics and kinetics for the reactions studied.


Molten Salts and Ionic Liquids

Molten Salts and Ionic Liquids

Author: Marcelle Gaune-Escard

Publisher: John Wiley & Sons

Published: 2012-07-06

Total Pages: 466

ISBN-13: 0470947764

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For many years, the related fields of molten salts and ionic liquids have drifted apart, to their mutual detriment. Both molten salts and ionic liquids are liquid salts containing only ions - all that is different is the temperature! Both fields involve the study of Coulombic fluids for academic and industrial purposes; both employ the same principles; both require skilled practitioners; both speak the same language; all then that is truly different is their semantics, and how superficial is that? The editors of this book, recognising that there was so much knowledge, both empirical and theoretical, which can be passed from the molten salt community to the ionic liquid community, and vice versa, organised a landmark meeting in Tunisia, designed to bridge the gap and heal the rift. Leaders from both communities met for a week for a mutual exchange, with a high tutorial content intermixed with cutting edge findings. This volume is a condensate of the principal offerings of that week, and emphasises the success which was achieved. Indeed, four future biannual meetings, under the title of “EUCHEM Conferences on Molten Salts and Ionic Liquids”, have now been planned as a direct result of this meeting of minds. Topics discussed in this volume include structure, dynamics, electrochemistry, interfacial and thermodynamic properties, spectroscopy, synthesis, and theoretical studies. Experimental and theoretical methods for investigating these data are elaborated, as are techniques for data collection and analysis. This book represents the first serious discussion on the transfer of these methods and techniques between the differing temperature regimes, and is a major contribution to the future of both fields.


Advances in Molten Slags, Fluxes, and Salts

Advances in Molten Slags, Fluxes, and Salts

Author: Ramana Reddy

Publisher: Springer

Published: 2017-01-10

Total Pages: 1373

ISBN-13: 3319487698

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This collection focuses on ferrous and non-ferrous metallurgy where ionic melts, slags, fluxes, or salts play important roles in industrial growth and economy worldwide. Technical topics included are: thermodynamic properties and phase diagrams and kinetics of slags, fluxes, and salts; physical properties of slags, fluxes, and salts; structural studies of slags; interfacial and process phenomena involving foaming, bubble formation, and drainage; slag recycling, refractory erosion/corrosion, and freeze linings; and recycling and utilization of metallurgical slags and models and their applications in process improvement and optimization. These topics are of interest to not only traditional ferrous and non-ferrous metal industrial processes but also new and upcoming technologies.


Corrosion of Metals and Hydrogen-Related Phenomena

Corrosion of Metals and Hydrogen-Related Phenomena

Author: J. Flis

Publisher: Elsevier

Published: 2016-01-11

Total Pages: 409

ISBN-13: 1483291723

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It is estimated that about 40% of the annual production of metals is used to repair or replace materials damaged by corrosion. Corrosion causes waste of the natural material and energy resources, it creates serious materials problems for many technologies and adversely affects almost every area of engineering. The use of metals in various aggressive environments has resulted in an extremely wide diversity of corrosion problems. This book presents a collection of concise reviews written by experts in the field on selected topics of metallic corrosion and on some aspects of interaction of hydrogen with metals. A comprehensive range of problems is examined including localized corrosion, high temperature corrosion in liquid metals and molten salts, transport control in corrosion processes, entry of hydrogen into metals, hydrogen embrittlement, and hydrogen reactions with metals. The variety of topics covered in the book will provide corrosion scientists, engineers, university lecturers and students alike with an interdisciplinary approach to solving problems of materials degradation and surface processes in metal corrosion.