Adsorption of Gases on Heterogeneous Surfaces

Adsorption of Gases on Heterogeneous Surfaces

Author: W. Rudzinski

Publisher: Academic Press

Published: 2012-12-02

Total Pages: 619

ISBN-13: 0080984363

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All real solid surfaces are heterogeneous to a greater or lesser extent and this book provides a broad yet detailed survey of the present state of gas adsorption. Coverage is comprehensive and extends from basic principles to computer simulation of adsorption. Underlying concepts are clarified and the strengths and weaknesses of the various methods described are discussed. - Adsorption isotherm equations for various types of heterogeneous solid surfaces - Methods of determining the nature of surface heterogeneity and porosity from experimental data - Studies of phase behavior of gases absorbed on heterogeneous solid surfaces - Computer simulation of adsorption on heterogeneous solid surfaces


Adsorption by Powders and Porous Solids

Adsorption by Powders and Porous Solids

Author: Jean Rouquerol

Publisher: Academic Press

Published: 2013-09-06

Total Pages: 647

ISBN-13: 0080970362

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The declared objective of this book is to provide an introductory review of the various theoretical and practical aspects of adsorption by powders and porous solids with particular reference to materials of technological importance. The primary aim is to meet the needs of students and non-specialists who are new to surface science or who wish to use the advanced techniques now available for the determination of surface area, pore size and surface characterization. In addition, a critical account is given of recent work on the adsorptive properties of activated carbons, oxides, clays and zeolites. - Provides a comprehensive treatment of adsorption at both the gas/solid interface and the liquid/solid interface - Includes chapters dealing with experimental methodology and the interpretation of adsorption data obtained with porous oxides, carbons and zeolites - Techniques capture the importance of heterogeneous catalysis, chemical engineering and the production of pigments, cements, agrochemicals, and pharmaceuticals


Gas Adsorption Equilibria

Gas Adsorption Equilibria

Author: Jürgen U. Keller

Publisher: Springer Science & Business Media

Published: 2006-06-23

Total Pages: 430

ISBN-13: 0387235981

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This book is intended to present for the first time experimental methods to measure equilibria states of pure and mixed gases being adsorbed on the surface of solid materials. It has been written for engineers and scientists from industry and academia who are interested in adsorption based gas separation processes and/or in using gas adsorption for characterization of the porosity of solid materials. This book is the result of a fruitful collaboration of a theoretician (JUK) and an experimentalist (RS) over more than twelve years in the field of gas adsorption systems at the Institute of Fluid- and Thermodynamics (IFT) at the University of Siegen, Siegen, Germany. This collaboration resulted in the development of several new methods to measure not only pure gas adsorption, but gas mixture or coadsorption equilibria on inert porous solids. Also several new theoretical results could be achieved leading to new types of so-called adsorption isotherms based on the concepts of molecular association and – phenomenologically speaking – on that of thermodynamic phases of fractal dimension. Naturally, results of international collaboration of the authors over the years (1980-2000) also are included.


Adsorption Analysis: Equilibria And Kinetics (With Cd Containing Computer Matlab Programs)

Adsorption Analysis: Equilibria And Kinetics (With Cd Containing Computer Matlab Programs)

Author: Duong D Do

Publisher: World Scientific

Published: 1998-09-22

Total Pages: 915

ISBN-13: 1783262249

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This book covers topics of equilibria and kinetics of adsorption in porous media. Fundamental equilibria and kinetics are dealt with for homogeneous as well as heterogeneous particles. Five chapters of the book deal with equilibria and eight chapters deal with kinetics. Single component as well as multicomponent systems are discussed. In kinetics analysis, we deal with the various mass transport processes and their interactions inside a porous particle. Conventional approaches as well as the new approach using Maxwell-Stefan equations are presented. Various methods to measure diffusivity, such as the Differential Adsorption Bed (DAB), the time lag, the diffusion cell, chromatography, and the batch adsorber methods are also covered by the book. It can be used by lecturers and engineers who wish to carry out research in adsorption. A number of programming codes written in MatLab language are included so that readers can use them directly to better understand the behavior of single and multicomponent adsorption systems.


Theoretical Advancement in Chromatography and Related Separation Techniques

Theoretical Advancement in Chromatography and Related Separation Techniques

Author: Francesco Dondi

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 651

ISBN-13: 9401126860

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Chromatography and all the related separation techniques are experimental in their origin and justification. However, the spectacular progress made in this area since World War II has given rise to a theoretical underpinning. The present book covers the current status of the research area and places it in perspective with the general concepts of the fields of physical chemistry involved. The ASI lectures/authors -- well known leaders in their fields -- have written presentations at the graduate level, accessible to all those who have a good general background in the thermodynamics and mass transfer theory of phase equilibria. The book will be useful to young scientists and engineers who wish to access the current frontiers in chromatography and other separation sciences.


Colloid Science

Colloid Science

Author: D. H. Everett

Publisher: Royal Society of Chemistry

Published: 1973

Total Pages: 273

ISBN-13: 0851865089

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This product is not available separately, it is only sold as part of a set. There are 750 products in the set and these are all sold as one entity. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.


Progress in Surface and Membrane Science

Progress in Surface and Membrane Science

Author: D. A. Cadenhead

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 505

ISBN-13: 1483219798

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Progress in Surface and Membrane Science, Volume 14 covers the advances in the study of surface and membrane science. The book discusses statistical thermodynamics of monolayer adsorption from gas and liquid mixtures on homogeneous and heterogeneous solid surfaces; and the structure of the boundary layers of liquids and its influence on the mass transfer in fine pores. The text then describes the coupling of ionic and non-electrolyte fluxes in ion selective membranes; the electrocatalytic properties of matalloporphins at the interface; and the adsorption from binary gas and liquid phases. Phase transitions in two-dimensional amphiphilic systems, as well as the wettability of solids by liquid metals are also considered. Biochemists, physicists, and people in electrochemistry research will find the book invaluable.


Surfaces of Nanoparticles and Porous Materials

Surfaces of Nanoparticles and Porous Materials

Author: James A. Schwarz

Publisher: CRC Press

Published: 1999-01-21

Total Pages: 814

ISBN-13: 9780824746681

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This innovative reference collects state-of-the-art procedures for the construction and design of nanoparticles and porous material while suggesting appropriate areas of application. Presenting both synthesis and characterization protocols, Surfaces of Nanoparticles and Porous Materials contains over 3000 references, tables, equations, drawings, and photographs. It examines the thermodynamics and kinetics of adsorption involving organic and inorganic liquids, solids, and gaseous media.. Topics include characterization, transport processes, diffusion, and the adsorption of heavy metals, ions, proteins, and pharmaceutical organics.