Emulsion Polymerization

Emulsion Polymerization

Author: Robert G. Gilbert

Publisher:

Published: 1995

Total Pages: 392

ISBN-13:

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This book provides a modern overview of the principles governing emulsion polymerization, a topic of both academic and industrial importance. The reader is provided with the mathematical, physical and technical tools to understand the mechanisms and physical chemistry of these systems, particularly the major advances of the last 15 years. The book describes the mechanisms that govern the various aspects of an emulsion polymerization, and how from appropriate experimental studies, the dominant mechanisms in a particular system may be deduced. From such deductions, the means are developed whereby the properties of the result of the emulsion polymerization can be quantitatively modelled and trends can be qualitatively understood and predicted. This book opens the way to the intelligent, knowledge-based design that is the future for improvements and innovations in products and processes from this important technology. Provides a thoroughly up-to-date overview of the principles and practices of emulsion polymerization Contains mathematical, physical, and technical tools which enable the reader to understand the mechanisms and physical chemistry used in the field Includes extensive exercises with model answers


Simulation of Particle Size Distribution in Continuous Emulsion Polymerization Through a Modified Population Balance Approach

Simulation of Particle Size Distribution in Continuous Emulsion Polymerization Through a Modified Population Balance Approach

Author: Ying-Yuh Lu

Publisher:

Published: 1984

Total Pages: 174

ISBN-13:

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A detailed mathematical model for particle size distribution in continuous emulsion polymerization of styrene and vinyl acetate is proposed on the basis of the population balance in the presence of several kinetic and mass transfer processes. This study is limited to the Smith-Ewart case II, which assumes instantaneous free radical termination within polymer particles. Radical desorption mechanism from polymer particles is included in the model and the desorption rate is formulated from the diffusion theory which suggests that the rate coefficient should be inversely proportional to the surface area of polymer particles.


Emulsion Polymerization and Its Applications in Industry

Emulsion Polymerization and Its Applications in Industry

Author: V. I. Eliseeva

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 231

ISBN-13: 1468416413

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There is a large body of Soviet work on emulsion polymerization, spanning a period of over three decades, that has been published primarily in the Russian language. Most of this has remained untranslated into English and hence un available to most other scientists. The value of this book lies primarily in the fact that it brings together the most important of these Soviet contributions, along with comment and analysis by the authors, who may be considered among the foremost authorities in this field in the Soviet Union. But the hundreds of literature citations go far beyond the borders of the Soviet Union and serve as an excellent bibliography of the world literature on emulsion polymerization up to the time this book was written. The book covers both fundamental and applied aspects. In the former are included discussions of particle formation mechanisms, a comprehensive theory of emulsion polymerization, copolymerization of polar monomers, and particle morphology and its implications with regard to derived film properties. Among the applied aspects are discussions of continuous emulsion polymerization, both tubular reactors and continuous stirred tank cascades, and various aspects con cerning the manufacture of some of the most important monomers, such as styrene, butadiene, vinyl acetate, methyl methacrylate, acrylonitrile, and chloroprene. This book will be an indispensable reference source for scientists who are entering the field as well as those who are experienced and who have wanted a ready access to this large body of literature.