Chemical Thermodynamics: Advanced Applications

Chemical Thermodynamics: Advanced Applications

Author: J. Bevan Ott

Publisher: Elsevier

Published: 2000-06-16

Total Pages: 465

ISBN-13: 0080500994

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This book is an excellent companion to Chemical Thermodynamics: Principles and Applications. Together they make a complete reference set for the practicing scientist. This volume extends the range of topics and applications to ones that are not usually covered in a beginning thermodynamics text. In a sense, the book covers a "middle ground" between the basic principles developed in a beginning thermodynamics textbook, and the very specialized applications that are a part of an ongoing research project. As such, it could prove invaluable to the practicing scientist who needs to apply thermodynamic relationships to aid in the understanding of the chemical process under consideration. The writing style in this volume remains informal, but more technical than in Principles and Applications. It starts with Chapter 11, which summarizes the thermodynamic relationships developed in this earlier volume. For those who want or need more detail, references are given to the sections in Principles and Applications where one could go to learn more about the development, limitations, and conditions where these equations apply. This is the only place where Advanced Applications ties back to the previous volume. Chapter 11 can serve as a review of the fundamental thermodynamic equations that are necessary for the more sophisticated applications described in the remainder of this book. This may be all that is necessary for the practicing scientist who has been away from the field for some time and needs some review. The remainder of this book applies thermodynamics to the description of a variety of problems. The topics covered are those that are probably of the most fundamental and broadest interest. Throughout the book, examples of "real" systems are used as much as possible. This is in contrast to many books where "generic" examples are used almost exclusively. A complete set of references to all sources of data and to supplementary reading sources is included. Problems are given at the end of each chapter. This makes the book ideally suited for use as a textbook in an advanced topics course in chemical thermodynamics. An excellent review of thermodynamic principles and mathematical relationships along with references to the relevant sections in Principles and Applications where these equations are developed Applications of thermodynamics in a wide variety of chemical processes, including phase equilibria, chemical equilibrium, properties of mixtures, and surface chemistry Case-study approach to demonstrate the application of thermodynamics to biochemical, geochemical, and industrial processes Applications at the "cutting edge" of thermodynamics Examples and problems to assist in learning Includes a complete set of references to all literature sources


Fundamentals of Chemical Engineering Thermodynamics

Fundamentals of Chemical Engineering Thermodynamics

Author: Themis Matsoukas

Publisher: Pearson Education

Published: 2013

Total Pages: 719

ISBN-13: 0132693062

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Fundamentals of Chemical Engineering Thermodynamics is the clearest and most well-organized introduction to thermodynamics theory and calculations for all chemical engineering undergraduates. This brand-new text makes thermodynamics far easier to teach and learn. Drawing on his award-winning courses at Penn State, Dr. Themis Matsoukas organizes the text for more effective learning, focuses on "why" as well as "how," offers imagery that helps students conceptualize the equations, and illuminates thermodynamics with relevant examples from within and beyond the chemical engineering discipline. Matsoukas presents solved problems in every chapter, ranging from basic calculations to realistic safety and environmental applications.


Engineering and Chemical Thermodynamics

Engineering and Chemical Thermodynamics

Author: Milo D. Koretsky

Publisher: John Wiley & Sons

Published: 2012-12-17

Total Pages: 724

ISBN-13: 0470259612

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Chemical engineers face the challenge of learning the difficult concept and application of entropy and the 2nd Law of Thermodynamics. By following a visual approach and offering qualitative discussions of the role of molecular interactions, Koretsky helps them understand and visualize thermodynamics. Highlighted examples show how the material is applied in the real world. Expanded coverage includes biological content and examples, the Equation of State approach for both liquid and vapor phases in VLE, and the practical side of the 2nd Law. Engineers will then be able to use this resource as the basis for more advanced concepts.


Fundamentals of Thermodynamics

Fundamentals of Thermodynamics

Author: John H. S. Lee

Publisher: CRC Press

Published: 2022-01-26

Total Pages: 139

ISBN-13: 1000533204

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A concise treatment of the fundamentals of thermodynamics is presented in this book. In particular, emphasis is placed on discussions of the second law, a unique feature of thermodynamics, which states the limitations of converting thermal energy into mechanical energy. The entropy function that permits the loss in the potential of a real thermodynamic process to be assessed, the maximum possible work in a process, and irreversibility and equilibrium are deduced from the law through physical and intuitive considerations. They are applicable in mitigating waste heat and are useful for solving energy, power, propulsion and climate-related issues. The treatment is not restricted to properties and functions of ideal gases. The ideal gas assumption is invoked as a limiting case. Reversible paths between equilibrium states are obtained using reversible heat engines and reversible heat pumps between environment and systems to determine the entropy changes and the maximum work. The conditions of thermodynamic equilibrium comprising mechanical, thermal, chemical and phase equilibrium are addressed and the species formed at equilibrium in a chemical reaction at a given temperature and pressure are obtained. The molecular basis for the laws of thermodynamics, temperature, internal energy changes, entropy, reversibility and equilibrium are briefly discussed. The book serves as a reference for undergraduate and graduate students alongside thermodynamics textbooks.


Chemical Thermodynamics for Industry

Chemical Thermodynamics for Industry

Author: Trevor M Letcher

Publisher: Royal Society of Chemistry

Published: 2007-10-31

Total Pages: 295

ISBN-13: 184755041X

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Chemical Thermodynamics for Industry presents the latest developments in applied thermodynamics and highlights the role of thermodynamics in the chemical industry. Written by leading experts in the field, Chemical Thermodynamics for Industry covers the latest developments in traditional areas such as calorimetry, microcalorimetry, transport properties, crystallization, adsorption, electrolyte systems and transport fuels, It highlights newly established areas such as multiphase modeling, reactive distillation, non-equilibrium thermodynamics and spectro-calorimetry. It also explores new ways of treating old technologies as well as new and potentially important areas such as ionic liquids, new materials, ab-initia quantum chemistry, nano-particles, polymer recycling, clathrates and the economic value of applied thermodynamics. This book is aimed not only at those working in a specific area of chemical thermodynamics but also at the general chemist, the prospective researcher and those involved in funding chemical research.


Elements of Chemical Thermodynamics

Elements of Chemical Thermodynamics

Author: Leonard K. Nash

Publisher: Courier Corporation

Published: 2013-02-20

Total Pages: 271

ISBN-13: 0486151840

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This text addresses the use of purely thermal data in calculating the position of equilibrium in a chemical reaction. Its argument highlights the physical content of thermodynamics, as distinct from purely mathematical aspects. Methods are limited to a very few of the most elementary operations of the calculus, all of which are explained in an appendix. Readers need no more than a sound background in high school mathematics and physics, as well as some familiarity with the leading quantitative concepts of an introductory college chemistry course. An introduction establishes the fundamentals of temperature, heat and work, reversibility, and pressure-volume work. The first principle of thermodynamics is explored in terms of energy, enthalpy, thermochemistry and Hess's Law, heat capacity, Kirchhoff's equations, and adiabatic processes. Considerations of the second principle of thermodynamics encompass the Carnot cycle, the concept of entropy, and evaluation of entropy changes. The consequences of thermodynamic principles are examined in chapters on the free energies, the Clapeyron equation, ideal solutions and colligative properties, and the equilibrium state and equilibrium constant. Numerous problems appear throughout the text, in addition to 30 fully worked illustrative examples.


Thermodynamics: Fundamentals and Applications for Chemical Engineers

Thermodynamics: Fundamentals and Applications for Chemical Engineers

Author: Miguel T. Fleischer

Publisher:

Published: 2017-12-29

Total Pages: 592

ISBN-13: 9781516526680

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Thermodynamics: Fundamentals and Applications for Chemical Engineers explores the concepts and properties of thermodynamics and illustrates how they can be applied to solve practical problems. The book introduces the fundamentals of thermodynamics for multi-phase, multi-component systems, providing a framework for dealing with problems in chemical engineering including mixing, compressing, and distilling fluids. The first eight chapters of Thermodynamics focus on single-component thermodynamics, introducing important concepts that will be referenced throughout subsequent chapters. Later chapters introduce modeling for multi-component systems. Topics covered include: properties as a function of state variables; first and second law of thermodynamics; power cycles, combustion, refrigeration cycles, and heat pumps; equilibrium phase relationships; correlations and calculations of vapor-liquid equilibrium data; elementary theories of solutions; and the efficiency of multicomponent separation and reaction processes. The Second Law of Thermodynamics, availability concepts, and process efficiency receive extensive coverage. The clear, well-organized sequence of the chapters helps students successfully learn and retain information. Each of the fifteen chapters includes updated sample problems that underline key principles and problem-solving steps. The book has numerous appendixes for quick reference on everything from conversion factors to Francis constants, and from properties of pure substances to thermodynamics tables and Diagrams. Thermodynamics can be used by chemical, petroleum, and mechanical engineering departments in introductory and intermediate courses on engineering thermodynamics and thermodynamics fundamentals. Born and raised in Chile, Miguel T. Fleischer earned his M.S. and Ph.D. in chemical engineering from the University of Houston where he is an adjunct professor and the undergraduate program director of the Chemical and Biomolecular Engineering Department. Dr. Fleischer worked at Royal Dutch Shell for more than 26 years in research and development, manufacturing, finance, and management. He began teaching when he was an undergraduate student in Chile where he developed a program sponsored by Universidad CatOlica de Chile to prepare high school students for college. He was the co-owner and CEO of Fleischer International Trading, a private enterprise that imported and distributed wines from all over the world for 13 years. He continued teaching while he was a graduate student at the University of Houston. He has received the Outstanding Lecturer award of the Cullen College of Engineering four times, the University's Teaching Excellence Award, the Cullen College of Engineering's Career Teaching Award, and the Cullen College of Engineering's Distinguished Engineering Alumni Award.


Fundamentals of Thermodynamics and Applications

Fundamentals of Thermodynamics and Applications

Author: Ingo Müller

Publisher: Springer Science & Business Media

Published: 2009-03-12

Total Pages: 404

ISBN-13: 354074648X

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Thermodynamics is the much abused slave of many masters • physicists who love the totally impractical Carnot process, • mechanical engineers who design power stations and refrigerators, • chemists who are successfully synthesizing ammonia and are puzzled by photosynthesis, • meteorologists who calculate cloud bases and predict föhn, boraccia and scirocco, • physico-chemists who vulcanize rubber and build fuel cells, • chemical engineers who rectify natural gas and distil f- mented potato juice, • metallurgists who improve steels and harden surfaces, • - trition counselors who recommend a proper intake of calories, • mechanics who adjust heat exchangers, • architects who construe – and often misconstrue – ch- neys, • biologists who marvel at the height of trees, • air conditioning engineers who design saunas and the ventilation of air plane cabins, • rocket engineers who create supersonic flows, et cetera. Not all of these professional groups need the full depth and breadth of ther- dynamics. For some it is enough to consider a well-stirred tank, for others a s- tionary nozzle flow is essential, and yet others are well-served with the partial d- ferential equation of heat conduction. It is therefore natural that thermodynamics is prone to mutilation; different group-specific meta-thermodynamics’ have emerged which serve the interest of the groups under most circumstances and leave out aspects that are not often needed in their fields.


A TEXTBOOK OF CHEMICAL ENGINEERING THERMODYNAMICS

A TEXTBOOK OF CHEMICAL ENGINEERING THERMODYNAMICS

Author: K. V. NARAYANAN

Publisher: PHI Learning Pvt. Ltd.

Published: 2013-01-11

Total Pages: 528

ISBN-13: 8120347471

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Designed as an undergraduate-level textbook in Chemical Engineering, this student-friendly, thoroughly class-room tested book, now in its second edition, continues to provide an in-depth analysis of chemical engineering thermodynamics. The book has been so organized that it gives comprehensive coverage of basic concepts and applications of the laws of thermodynamics in the initial chapters, while the later chapters focus at length on important areas of study falling under the realm of chemical thermodynamics. The reader is thus introduced to a thorough analysis of the fundamental laws of thermodynamics as well as their applications to practical situations. This is followed by a detailed discussion on relationships among thermodynamic properties and an exhaustive treatment on the thermodynamic properties of solutions. The role of phase equilibrium thermodynamics in design, analysis, and operation of chemical separation methods is also deftly dealt with. Finally, the chemical reaction equilibria are skillfully explained. Besides numerous illustrations, the book contains over 200 worked examples, over 400 exercise problems (all with answers) and several objective-type questions, which enable students to gain an in-depth understanding of the concepts and theory discussed. The book will also be a useful text for students pursuing courses in chemical engineering-related branches such as polymer engineering, petroleum engineering, and safety and environmental engineering. New to This Edition • More Example Problems and Exercise Questions in each chapter • Updated section on Vapour–Liquid Equilibrium in Chapter 8 to highlight the significance of equations of state approach • GATE Questions up to 2012 with answers