Heteroepitaxial Thick GaN Layers and Vertical High-Power Devices by Selective Area MOCVD Growth

Heteroepitaxial Thick GaN Layers and Vertical High-Power Devices by Selective Area MOCVD Growth

Author: Atsunori Tanaka

Publisher:

Published: 2019

Total Pages: 133

ISBN-13:

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Gallium nitride (GaN) is now widely used in commercial white Light Emitting Diodes (LEDs) thanks to the emergence of high-brightness GaN blue LEDs in 1990s. In addition to its application in solid-state lighting, GaN has been also vowed as a strong contender for next-generation high power and frequency devices due to its high critical electric field (3.3 MV/cm) and high mobility of the 2-dimensional electron gas (2DEG) at the aluminum gallium nitride (AlGaN)/GaN interface. Lateral AlGaN/GaN high-electron-mobility-transistors (HEMTs) have been available as commercial off-the-shelf devices since 2005. However, with the demand for even higher power at reduced chip area and cost and with better thermal management at high currents, vertical device architectures have emerged as the chosen structure to meet these demands. But vertical devices that can hold high power require thick and high quality GaN layers. Recent developments of bulk GaN substrate growth technologies allowed vertical GaN device with thick drift layer to be more feasible. However, GaN substrate technology is challenged with cost, reliability and uniformity issues even at the currently commercially available 2" (diameter) substrates. Therefore, GaN vertical power devices on cheap substrates without compromising the GaN material quality remains to be of great interest. Si substrates with their fab-scale integrated circuit technology can propel the development of commercial vertical high power GaN devices. The biggest challenge for realizing thick GaN layers on Si to hold high voltage in the vertical direction is the large thermal and lattice mismatch between GaN and Si that leads to cracking of the GaN layers beyond only a few micrometers. In major part of this dissertation, we will focus on the epitaxy techniques of thick crack-free GaN layers on Si by selective area growth (SAG) and the fabrication of vertical GaN switches. The epitaxy technique developed in this work resulted in crack-free thick GaN layers on Si that are of high quality with low dislocation densities and low background doping in order to sustain high breakdown voltages. The developed processes hold the potential to significantly advance the fundamental electronic materials research in power devices and their efficient system level integration.


Selective Area Doping of GaN by Epitaxial Layer Overgrowth and Its Power Electronic Applications

Selective Area Doping of GaN by Epitaxial Layer Overgrowth and Its Power Electronic Applications

Author: Jia Wang

Publisher:

Published: 2021

Total Pages: 200

ISBN-13:

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GaN has wide bandgap, high critical electric field, and high electron saturation velocity, making it an ideal candidate for power switching electronics. However, the development of GaN-based power electronics is still hampered by the high cost of GaN substrate and selective area doping capabilities (especially for p-type) to produce laterally patterned p-n junctions. Epitaxial lateral overgrowth (ELO) is known to render low-dislocation-density GaN in the overgrown regions (wings) on inexpensive foreign substrates. Furthermore, the combination of ELO (prior to the coalescence stage) and in-situ doping process produces the half-core-shell doping profile which has been used in the optoelectronics such as microrod LEDs. However, the application of ELO-GaN has not been explored in the power applications mostly because such doping profile is not configured to withstand high reverse blocking voltage unless the modified structures and methods could be adopted. In this dissertation, a holistic approach was employed to study the innovative measures either in the material growth or device processing stage to tailor the half-core-shell doping profile produced by the ELO of GaN into the desired selective-area doping profiles for power switching electronics featuring the building block of laterally patterned p-n junctions. For the device processing innovation, the concept of true-lateral device architecture was proposed which consists of fully lateral aligned p-n junctions. The general advantages of such device architecture were comprehensively discussed from various aspects. In addition, the low-dislocation density GaN in the wing regions of ELO was fully utilized as an ideal drift layer of a power device. As a result, both power diodes (Schottky barrier diode and p-n junction diode) and power bipolar transistors (gated lateral power bipolar junction transistor and insulated gate bipolar transistor) with the true-lateral device architecture were experimentally demonstrated either with superior performance or for the first time, highlighted by the record high critical electric field in a GaN p-n junction and the record high current gain of a power bipolar transistor. Alternatively, for the material growth innovation, the hybrid epitaxy-enabled substrate transfer approach was demonstrated to produce the GaN substrate with repeating laterally patterned p-n junctions suitable for a number of advanced electronic devices such as a planar-gate vertical MOSFET. In addition, the selective area doping profiles of the GaN substrate product also rendered a number of state-of-the-art characterization techniques which provided valuable information to study the incorporation and diffusion of dopants (especially for acceptors) in GaN. With these innovative measures and a deeper understanding of selective area doping of GaN, the potential of epitaxial lateral overgrowth to simultaneously realize the low threading dislocation density and the selective-area doping profile (lateral patterned p-n junctions) was initially and finally unleashed to yield unprecedented opportunities in the power electronic applications. This may spawn a revival of interest into ELO-GaN for power electronic applications.


Two-dimensional Materials

Two-dimensional Materials

Author: Pramoda Kumar Nayak

Publisher: BoD – Books on Demand

Published: 2016-08-31

Total Pages: 282

ISBN-13: 9535125540

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There are only a few discoveries and new technologies in materials science that have the potential to dramatically alter and revolutionize our material world. Discovery of two-dimensional (2D) materials, the thinnest form of materials to ever occur in nature, is one of them. After isolation of graphene from graphite in 2004, a whole other class of atomically thin materials, dominated by surface effects and showing completely unexpected and extraordinary properties, has been created. This book provides a comprehensive view and state-of-the-art knowledge about 2D materials such as graphene, hexagonal boron nitride (h-BN), transition metal dichalcogenides (TMD) and so on. It consists of 11 chapters contributed by a team of experts in this exciting field and provides latest synthesis techniques of 2D materials, characterization and their potential applications in energy conservation, electronics, optoelectronics and biotechnology.


Technology of Gallium Nitride Crystal Growth

Technology of Gallium Nitride Crystal Growth

Author: Dirk Ehrentraut

Publisher: Springer Science & Business Media

Published: 2010-06-14

Total Pages: 337

ISBN-13: 3642048307

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This book discusses the important technological aspects of the growth of GaN single crystals by HVPE, MOCVD, ammonothermal and flux methods for the purpose of free-standing GaN wafer production.


Handbook of Thin Films, Five-Volume Set

Handbook of Thin Films, Five-Volume Set

Author: Hari Singh Nalwa

Publisher: Elsevier

Published: 2001-11-17

Total Pages: 3451

ISBN-13: 0080533248

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This five-volume handbook focuses on processing techniques, characterization methods, and physical properties of thin films (thin layers of insulating, conducting, or semiconductor material). The editor has composed five separate, thematic volumes on thin films of metals, semimetals, glasses, ceramics, alloys, organics, diamonds, graphites, porous materials, noncrystalline solids, supramolecules, polymers, copolymers, biopolymers, composites, blends, activated carbons, intermetallics, chalcogenides, dyes, pigments, nanostructured materials, biomaterials, inorganic/polymer composites, organoceramics, metallocenes, disordered systems, liquid crystals, quasicrystals, and layered structures. Thin films is a field of the utmost importance in today's materials science, electrical engineering and applied solid state physics; with both research and industrial applications in microelectronics, computer manufacturing, and physical devices. Advanced, high-performance computers, high-definition TV, digital camcorders, sensitive broadband imaging systems, flat-panel displays, robotic systems, and medical electronics and diagnostics are but a few examples of miniaturized device technologies that depend the utilization of thin film materials. The Handbook of Thin Films Materials is a comprehensive reference focusing on processing techniques, characterization methods, and physical properties of these thin film materials.


Springer Handbook of Electronic and Photonic Materials

Springer Handbook of Electronic and Photonic Materials

Author: Safa Kasap

Publisher: Springer

Published: 2017-10-04

Total Pages: 1536

ISBN-13: 331948933X

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The second, updated edition of this essential reference book provides a wealth of detail on a wide range of electronic and photonic materials, starting from fundamentals and building up to advanced topics and applications. Its extensive coverage, with clear illustrations and applications, carefully selected chapter sequencing and logical flow, makes it very different from other electronic materials handbooks. It has been written by professionals in the field and instructors who teach the subject at a university or in corporate laboratories. The Springer Handbook of Electronic and Photonic Materials, second edition, includes practical applications used as examples, details of experimental techniques, useful tables that summarize equations, and, most importantly, properties of various materials, as well as an extensive glossary. Along with significant updates to the content and the references, the second edition includes a number of new chapters such as those covering novel materials and selected applications. This handbook is a valuable resource for graduate students, researchers and practicing professionals working in the area of electronic, optoelectronic and photonic materials.